Nanofibers decorated with nanoparticles and methods of their manufacture

Patent metadata

Field	Value
Publication number	US-11450860-B2
Application number	US-201715623220-A
Country	US
Kind code	B2
Filing date	Jun 14, 2017
Priority date	Jun 14, 2016
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

Nanostructured materials, and methods and apparatus for their production are provided. Nanostructured materials comprise nanofibers having nanoparticles deposited along the outer surface thereof. The size of the nanofibers and nanoparticles, and the spacing of such nanoparticles along the nanofibers may be controlled over a wide range. Nanostructured materials may comprise a plurality of such nanofibers interwoven together to form fiber cloth-like materials. Many materials may be used to form the nanofibers including polymer nanofiber materials (e.g., polyvinyl alcohol (PVA) polyvinylpyrrolidone (PVP), etc.) along with compatible nanoparticle materials (e.g., salts or other crystallizable materials).

First claim

What is claimed is:

1. A method of preparing a nanostructured material comprising solid electrolyte nanoparticles disposed along the surface of polymeric nanofibers, the method comprising:
preparing a single-phase solution comprising a polymer material, a solute for forming the solid electrolyte nanoparticles, and at least one solvent;
extracting polymeric nanofibers from the solution, wherein the polymeric nanofibers have solute disposed at least one of the surface or interior of the nanofiber;
solidifying the extracted polymeric nanofibers; and
curing the solidified polymeric nanofibers having solute disposed on at least one of the surface or interior thereof such that the solute is nucleated into a plurality of crystalline solid electrolyte nanoparticles disposed along the surface of the solidified polymeric nanofibers,
wherein the curing is either a passive process, wherein the nucleation occurs via natural drying; or an active process, wherein the nucleation occurs in a condition selected from the group consisting of stir drying, heating, applying humidified air, and any combinations thereof; and
wherein the method does not convert the polymeric nanofibers to carbon fibers.

2. The method of claim 1 , wherein the solute is a salt.

3. The method of claim 2 , wherein the salt is CDP.

4. The method of claim 3 , wherein the concentration of solute in the solution varies from 30-50 mg/mL.

5. The method of claim 1 , wherein the polymeric material is selected from the group consisting of PMMA, PEG, PVP and PVA.

6. The method of claim 5 , wherein the polymeric material is PVP and the concentration of polymeric material in the solution varies from 25-45 mg/mL.

7. The method of claim 5 , wherein the polymeric material is PVA and the concentration of polymeric material in the solution varies from 15-30 mg/mL.

8. The method of claim 1 , further comprising varying the concentration of polymeric material in the solution to control the nanoparticle size and the density of nanoparticles disposed on the nanofiber.

9. The method of claim 1 , wherein the polymeric material is PVP, the solute is CDP, and the concentration of the solute in solution is around 50 mg/mL.

10. The method of claim 1 , wherein the polymeric material is PVA, the solute is CDP, and the concentration of the solute in solution is around 30 mg/mL.

11. The method of claim 1 , wherein the nanofibers are solidified on a substrate heated between about 110 to 140° C.

12. The method of claim 1 , wherein the polymeric nanofibers are extracted using a process selected from the group consisting of electrospinning and meltblowing.

13. The method of claim 1 , further comprising interweaving a plurality of solidified nanofibers together.

Assignees

• California Inst Of Techn

Inventors

• Radacsi Norbert
• Giapis Konstantinos P

Classifications

• D01D5/003 Primary

  the material being a polymer solution or dispersion (D01D5/0053 takes precedence) · CPC title

• D01D5/0076

  characterised by the collecting device, e.g. drum, wheel, endless belt, plate or grid (D01D5/0046 takes precedence) · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• D06M11/00

  Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising (D06M10/00 takes precedence) · CPC title