Crystal fiber manufacturing method

Patent metadata

Field	Value
Publication number	US-11447888-B2
Application number	US-201917057479-A
Country	US
Kind code	B2
Filing date	Mar 15, 2019
Priority date	May 22, 2018
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

Provided is a method for producing a crystal fiber which can suppress the occurrence of stress birefringence even while distributing a light emission center so as to concentrate on a cross-sectional middle portion. The method for producing a crystal fiber comprises the steps of: using, as a preform, the crystal fiber comprising a light emission center that volatilizes from a melted portion upon the melting of a crystal, and heating a portion or a plurality of portions of the side of the preform, whereby the portion or the plurality of portions of the preform are melted such that only a given amount of the inside of the portion or the plurality of portions of the preform is not melted, to form the melted portion; and sequentially transferring the melted portion in the longitudinal direction of the preform, and cooling the melted portion, whereby the melted portion is continuously recrystallized to form a recrystallized region.

First claim

The invention claimed is:

1. A method for producing a crystal fiber of cross-sectional light emission center distribution type which concentrates a light emission center on or near the middle in a cross section of the crystal fiber, the method comprising the steps of:
using, as a preform, the crystal fiber comprising a light emission center that volatilizes from a melted portion upon the melting of a crystal, and heating a portion of the side of the preform or a plurality of portions of the side of the preform positionally equal in the longitudinal direction of the preform, whereby the portion or the plurality of portions of the preform are melted such that only a given amount of the inside of the portion or the plurality of portions of the preform is not melted, to form the melted portion; and
sequentially transferring the melted portion in the longitudinal direction of the preform, and cooling the melted portion, whereby the melted portion is continuously recrystallized to form a recrystallized region.

2. A method for producing a crystal fiber of cross-sectional light emission center distribution type which concentrates a light emission center on or near the middle in a cross section of the crystal fiber, the method comprising the steps of:
using, as a preform, the crystal fiber comprising a light emission center that volatilizes from a melted portion upon the melting of a crystal, and heating a portion of the side of the preform or a plurality of portions of the side of the preform positionally equal in the longitudinal direction of the preform, whereby the portion or the plurality of portions of the preform are melted such that only a given amount of the inside of the portion or the plurality of portions of the preform is not melted, to form the melted portion;
sequentially transferring the melted portion in the longitudinal direction of the preform, and cooling the melted portion, whereby the melted portion is continuously recrystallized to form a first recrystallized region;
a) heating a site that is the portion of the side of the preform or the plurality of portions of the side of the preform positionally equal in the longitudinal direction of the preform, and is a portion other than the first to n−1th (wherein n represents a positive integer with 2 as an initial value) recrystallized regions thus formed, whereby the portion or the plurality of portions of the preform are melted such that only a given amount of the inside of the portion or the plurality of portions of the preform is not melted, to form the melted portion;
b) sequentially transferring the melted portion in the longitudinal direction of the preform, and cooling the melted portion, whereby the melted portion is continuously recrystallized to form a nth recrystallized region; and
c) when the maximum value of the n is defined as M (wherein M represents a positive integer of 2 or larger), repeating the steps a) and b) predetermined times by increasing the n one by one until the n becomes predetermined M.

3. The method for producing a crystal fiber according to claim 2 , wherein
the step of forming the first to Mth recrystallized regions is a step that is performed while cooling the portion or the plurality of portions of the preform opposed to the melted portion via an axis along the longitudinal direction of the preform.

4. The method for producing a crystal fiber according to claim 3 , wherein
the step of forming the first to Mth recrystallized regions comprises contacting the portion or the plurality of portions of the preform with a cooling block when the portion or the plurality of portions of the preform are cooled.

5. The method for producing a crystal fiber according to claim 4 , wherein
a material for the cooling block is a block using diamond, sapphire or a metal, or a heat pipe-incorporated block.

6. The method for producing a crystal fiber according to claim 1 , wherein the cooling employs helium in an atmosphere.

7. The method for producing a crystal fiber according to claim 1 , wherein the light emission center is any of period 4 transition metal elements titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), or copper (Cu), or zinc (Zn).

8. The method for producing a crystal fiber according to claim 1 , wherein the preform is crystalline and is any of yttrium-aluminum-garnet supplemented with tetravalent chromium (Cr 4+ :YAG), Ti:sapphire or Cr:forsterite.

9. The method for producing a crystal fiber according to claim 1 , wherein the preform is a fiber consisting of a single crystal or a fiber with a plurality of single crystals joined.

10. The method for producing a crystal fiber according to claim 1 , further comprising, after the completion of the step of forming the recrystallized region, the step of forming a thin film for use as a clad on the entire circumference of the side of the crystal fiber.

11. The method for producing a crystal fiber according to claim 1 , further comprising, after the completion of the step of forming the recrystallized region,
an annealing step of elevating the temperature of the crystal fiber to a predetermined temperature equal to or lower than the melting point of the preform, maintaining the predetermined temperature for a predetermined time, and then slowly cooling the crystal fiber over a predetermined time.

12. The method for producing a crystal fiber according to claim 11 , further comprising, after the annealing step, the step of forming a thin film for use as a clad on the entire circumference of the side of the crystal fiber.

13. The method for producing a crystal fiber according to claim 10 , wherein a material for the clad is silicon dioxide (SiO 2 ), aluminum oxide (Ai 2 O 3 ), or magnesium oxide (MgO).

14. The method for producing a crystal fiber according to claim 1 , wherein a heat source for heating the preform is any of a laser, a lamp or other radiation sources.

Assignees

• Nippon Telegraph & Telephone

Inventors

• Ishibashi Shigeo

Classifications

• C30B13/22

  by irradiation or electric discharge · CPC title

• H01S3/1625

  titanium · CPC title

• C30B29/28

  with formula A3Me5O12 wherein A is a rare earth metal and Me is Fe, Ga, Sc, Cr, Co or Al, e.g. garnets · CPC title

• C30B13/30 Primary

  Stabilisation or shape controlling of the molten zone, e.g. by concentrators, by electromagnetic fields; Controlling the section of the crystal · CPC title

• C30B29/60 Primary

  characterised by shape · CPC title