Refrigerant compositions

Patent metadata

Field	Value
Publication number	US-11447674-B2
Application number	US-201816614151-A
Country	US
Kind code	B2
Filing date	May 17, 2018
Priority date	May 17, 2017
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

A composition comprising: (i) 1,1-difluoroethene (vinylidene fluoride, R-1132a); (ii) carbon dioxide (CO2, R-744); (iii) pentafluoroethane (R-125); and (iv) one or more of trifluoromethane (R-23) and hexafluoroethane (R-116).

First claim

The invention claimed is:

1. A composition comprising:
(i) 1,1-difluoroethene (vinylidene fluoride, R-1132a);
(ii) carbon dioxide (CO 2 , R-744);
(iii) from about 10 to 25% by weight pentafluoroethane (R-125); and
(iv) trifluoromethane (R-23).

2. The composition according to claim 1 comprising from 1 to 90% by weight R-1132a.

3. The composition according to claim 2 comprising from 1 to 50% by weight R-1132a.

4. The composition according to claim 1 comprising from 1 to 90% by weight carbon dioxide.

5. The composition according to claim 4 comprising from 5 to 70% by weight carbon dioxide.

6. The composition according to claim 1 comprising from 1 to 90% by weight of trifluoromethane.

7. The composition according to claim 6 comprising from 1 to 50% by weight of trifluoromethane.

8. The composition according to claim 1 comprising from 20 to 40% by weight R-1132a, from 30 to 60% by weight carbon dioxide, and from 1 to 20% by weight R-23.

9. The composition according to claim 8 comprising from 25 to 35% by weight R-1132a, from 35 to 50% by weight carbon dioxide, and from 5 to 15% by weight R-23.

10. The composition according to claim 1 comprising from 25 to 30% by weight R-1132a, from 35 to 50% by weight carbon dioxide, and from 5 to 20% by weight R-23.

11. The composition according to claim 1 further comprising hexafluoroethane (R-116).

12. The composition according to claim 11 comprising from 30 to 60% by weight carbon dioxide, from 10 to 40% by weight R-1132a, from about 10 to 25% by weight R-125, and from 1 to 20% by weight R-116.

13. The composition according to claim 1 , wherein the R-1132a is present in an amount of less than 50% by mol.

14. The composition according to claim 13 , wherein R-1132a is present in an amount of less than 30% by mol.

15. The composition according to claim 1 consisting essentially of:
(i) 1,1-difluoroethene (vinylidene fluoride, R-1132a);
(ii) carbon dioxide (CO 2 , R-744);
(iii) from about 10 to 25% by weight pentafluoroethane (R-125); and
(iv) trifluoromethane (R-23).

16. The composition according to claim 1 which is azeotropic or near azeotropic.

17. The composition according to claim 1 , wherein the composition is less flammable than R-1132a alone.

18. The composition according to claim 17 wherein the composition has
a. a higher flammable limit;
b. a higher ignition energy; and/or
c. a lower flame velocity
compared to R-1132a alone.

19. The composition according to claim 1 which is non-flammable.

20. The composition according to claim 1 which has a temperature glide in an evaporator or condenser of less than about 10 K.

21. The composition according to claim 20 which has a temperature glide in an evaporator or a condenser of less than 7K.

22. The composition according to claim 1 which has a critical temperature of greater than about 0° C.

23. The composition according to claim 22 which has a critical temperature of greater than 10° C.

24. The composition according to claim 1 whose volumetric refrigeration capacity is at least 90% of that of R-23 at comparable cycle conditions.

25. The composition according to claim 24 which has a volumetric refrigeration capacity of at least 95% of that of R-23 at comparable conditions.

26. The composition according to claim 1 whose cycle efficiency (Coefficient of Performance, COP) is at least 95% and/or within about 5% of the existing refrigerant fluid that the composition is replacing.

27. The composition according to claim 1 whose compressor discharge temperature is within 15 K of that of R-23 at comparable cycle conditions.

28. A composition comprising a lubricant and the composition according to claim 1 .

29. The composition according to claim 28 , wherein the lubricant is selected from the group consisting of mineral oil, silicone oil, polyalkyl benzenes (PABs), polyol esters (POEs), polyalkylene glycols (PAGs), polyalkylene glycol esters (PAG esters), polyvinyl ethers (PVEs), poly (alpha-olefins) and combinations thereof.

30. The composition according to claim 29 , wherein the composition further comprises pentane.

31. The composition according to claim 30 , wherein the lubricant is selected from the group consisting of PAGs and POEs.

32. A composition comprising a stabilizer and the composition according to claim 1 .

33. The composition according to claim 32 , wherein the stabilizer is selected from the group consisting of diene-based compounds, phosphates, phenol compounds and epoxides, and mixtures thereof.

34. A composition comprising a flame retardant and the composition according to claim 1 .

35. The composition according to claim 34 , wherein the flame retardant is selected from the group consisting of tri-(2-chloroethyl)-phosphate, (chloropropyl) phosphate, tri-(2,3-dibromopropyl)-phosphate, tri-(1,3-chloropropyl)-phosphate, diammonium phosphate, various halogenated aromatic compounds, antimony oxide, aluminum trihydrate, polyvinyl chloride, a fluorinated iodocarbon, a fluorinated bromocarbon, trifluoro iodomethane, perfluoroalkyl amines, bromo-fluoroalkyl amines and mixtures thereof.

36. A heat transfer device comprising the composition according to claim 1 .

37. The heat transfer device according to claim 36 wherein the heat transfer device is a refrigeration device.

38. The heat transfer device according to claim 36 wherein the heat transfer device comprises an ultra-low temperature refrigeration system.

39. The heat transfer device according to claim 38 wherein the heat transfer device is a blast freezer.

40. The heat transfer device according to claim 36 wherein the heat transfer device comprises a cascade system.

41. A method for cooling an article which comprises condensing the composition according to claim 1 and thereafter evaporating the composition in the vicinity of the article to be cooled.

42. A method for heating an article which comprises condensing the composition according to claim 1 in the vicinity of the article to be heated and thereafter evaporating the composition.

43. A method for extracting a substance from biomass comprising contacting biomass with a solvent comprising the composition according to claim 1 , and separating the substance from the solvent.

44. A method of cleaning an article comprising contacting the article with a solvent comprising the composition according to claim 1 .

45. A method of extracting a material from an aqueous solution or from a particulate solid matrix comprising contacting the aqueous solution or the particulate solid matrix with a solvent comprising the composition according to claim 1 , and separating the material from the solvent.

46. A method of retrofitting a heat transfer device comprising removing an existing heat transfer composition, and introducing the composition according to claim 1 .

47. The method according to claim 46 wherein the heat transfer composition is a refrigerant selected from the group consisting of R-508A, R-508B, R-23 and R-13B1.

48. The method accor

Assignees

• Mexichem Fluor Sa De Cv

Inventors

• Low Robert

Classifications

• C09K5/041

  for compression-type refrigeration systems · CPC title

• C09K2205/106

  Carbon dioxide · CPC title

• G06Q50/26

  Government or public services (business processes related to the transportation industry G06Q50/40) · CPC title

• C09K2205/32

  The mixture being azeotropic · CPC title

• C09K2205/126

  Unsaturated fluorinated hydrocarbons · CPC title