Iron sulfide scale control agent for geothermal wells

Patent metadata

Field	Value
Publication number	US-11447410-B2
Application number	US-201815976977-A
Country	US
Kind code	B2
Filing date	May 11, 2018
Priority date	May 15, 2017
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

The disclosure relates to improved methods for inhibiting the formation and deposition of sulfide and silica scale in aqueous systems. In particular, the methods include injecting a composition into an aqueous system or wellbore. The composition includes a sulfide scale inhibitor and a silica scale inhibitor. The sulfide scale inhibitor may be a copolymer of acrylic acid or methacrylic acid and an anionic monomer. The silica scale inhibitor may be a copolymer of acrylic acid or methacrylic acid and an alkoxylated monomer.

First claim

What is claimed is:

1. A method for sulfide and silica scale inhibition or reduction in an aqueous system, comprising:
injecting a composition into the aqueous system, wherein the aqueous system comprises a temperature of about 185° C. to about 370° C., wherein the composition comprises a sulfide scale inhibitor and a silica scale inhibitor, wherein the sulfide scale inhibitor is added in the aqueous system in an amount ranging from about 1 ppm to about 500 ppm and the silica scale inhibitor is added in the aqueous system in an amount ranging from about 1 ppm to about 100 ppm, and wherein the sulfide scale inhibitor disperses iron.

2. The method of claim 1 , wherein the sulfide scale inhibitor comprises a copolymer of acrylic acid or methacrylic acid and an anionic monomer.

3. The method of claim 1 , wherein the silica scale inhibitor comprises a copolymer of acrylic acid or methacrylic acid and an alkoxylated monomer.

4. The method of claim 2 , wherein the anionic monomer is selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid (AMPS), styrene sulfonic acid, 2-methyacrylimido-2-methylpropylsulfonic acid, vinyl sulfonic acid, sulfoalkyl acrylate, sulfoalkyl methacrylate, allyl sulfonic acid, 3-methacrylamido-2-hydroxypropylsulfonic acid, any salt thereof, and any combination thereof.

5. The method of claim 3 , wherein the alkoxylated monomer is selected from the group consisting of hydroxypolyethoxy allyl ether (AAE), 3-allyloxy-1,2-propanediol, diethylene glycol monoallyl ether, tetraethylene glycol methyl vinyl ether, ethylene glycol vinyl ether, polyethoxy methacrylate, 1-allyloxy-2-hydroxypropane sulfonic acid, any salt thereof, and any combination thereof.

6. The method of claim 2 , wherein the anionic monomer is AMPS.

7. The method of claim 3 , wherein the alkoxylated monomer is hydroxypolyethoxy (10) allyl ether (AAE-10).

8. The method of claim 1 , wherein the sulfide scale inhibitor comprises a copolymer, wherein the copolymer comprises from about 40% to about 80% by weight of acrylic acid and from about 20% to about 60% by weight of AMPS.

9. The method of claim 1 , wherein the silica scale inhibitor comprises a copolymer, wherein the copolymer comprises from about 30% to about 70% by weight of acrylic acid and from about 30% to about 70% by weight of AAE-10.

10. The method of claim 1 , wherein the composition is injected into a condenser in the aqueous system, wherein the condenser contains water or wherein the composition is injected into a separator in the aqueous system, wherein the separator contains water, or wherein the aqueous system comprises brine with a salinity from less than about 1,000 ppm to 300,000 ppm.

11. The method of claim 1 , wherein the aqueous system is a geothermal system, wherein the geothermal system is a geothermal power plant selected from the group consisting of a dry steam station, a flash steam station, and a binary cycle station.

12. The method of claim 1 , wherein the sulfide scale inhibitor comprises a copolymer with a weight average molecular weight ranging from about 1,000 Da to about 100,000 Da, wherein the silica scale inhibitor comprises a copolymer with a weight average molecular weight ranging from about 1,000 Da to about 100,000 Da, wherein the weight average molecular weight is determined using size exclusion chromatography.

13. The method of claim 1 , wherein the sulfide scale is selected from the group consisting of iron sulfide, antimony sulfide, lead sulfide, zinc sulfide, and any combination thereof.

14. The method of claim 1 , wherein the composition further comprises an additive selected from the group consisting of a hydrogen sulfide scavenger, a corrosion inhibitor, a dispersant, a gas hydrate inhibitor, a biocide, a surfactant, a solvent, an inert tracer, and any combination thereof.

15. The method of claim 1 , wherein the composition is injected at a location in a wellbore that is from about 200 to about 400 feet below a lowest encountered scale formation site.

16. The method of claim 1 , wherein inhibition of mixed deposits of iron silicate and iron sulfide by the composition was more than a sum of inhibition of mixed deposits of iron silicate and iron sulfide by the sulfide scale inhibitor and the silica scale inhibitor separately.

17. A method for sulfide and silica scale inhibition or reduction in a wellbore, comprising:
injecting a composition into the wellbore, wherein the wellbore comprises a temperature of about 185° C. to about 370° C., wherein the composition comprises a sulfide scale inhibitor and a silica scale inhibitor, wherein the sulfide scale inhibitor is added to the wellbore in an amount ranging from about 1 ppm to about 500 ppm and the silica scale inhibitor is added to the wellbore in an amount ranging from about 1 ppm to about 100 ppm, and wherein the sulfide scale inhibitor disperses iron.

18. The method of claim 17 , wherein the sulfide scale inhibitor comprises a copolymer, wherein the copolymer comprises from about 40% to about 80% by weight of acrylic acid and from about 20% to about 60% by weight of AMPS.

19. The method of claim 17 , wherein the silica scale inhibitor comprises a copolymer, wherein the copolymer comprises from about 30% to about 70% by weight of acrylic acid and from about 30% to about 70% by weight of AAE-10.

20. The method of claim 17 , wherein inhibition of mixed deposits of iron silicate and iron sulfide by the composition was more than a sum of inhibition of mixed deposits of iron silicate and iron sulfide by the sulfide scale inhibitor and the silica scale inhibitor separately.

Assignees

• Ecolab Usa Inc

Inventors

• Mantri Dinesh
• Gill Jasbir S

Classifications

• Y02E10/10

  Geothermal energy · CPC title

• C02F5/12 Primary

  containing nitrogen (C02F5/14 takes precedence) · CPC title

• F24T10/20

  using underground water as working fluid; using working fluid injected directly into the ground, e.g. using injection wells and recovery wells · CPC title

• C02F2101/10

  Inorganic compounds · CPC title

• C02F2101/101

  Sulfur compounds · CPC title