System and process for production of synthesis gas

Patent metadata

Field	Value
Publication number	US-11447389-B2
Application number	US-201816753501-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Dec 8, 2017
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

A system for production of a synthesis gas, including: a synthesis gas generation reactor arranged for producing a first synthesis gas from a hydrocarbon feed stream; a post converter including a catalyst active for catalyzing steam methane reforming, methanation and reverse water gas shift reactions; the post converter including a conduit for supplying a CO2 rich gas stream into a mixing zone of the post converter, where the CO2 rich gas stream in the conduit upstream the mixing zone is in heat exchange relationship with gas flowing over the catalyst downstream the mixing zone; a pipe combining the at least part of the first synthesis gas and the CO2 rich gas stream to a mixed gas, in a mixing zone being upstream the catalyst; wherein the post converter further includes an outlet for outletting a product synthesis gas from the post converter. Also, a corresponding process.

First claim

The invention claimed is:

1. A system for production of a synthesis gas, comprising:
a synthesis gas generation reactor arranged for producing a first synthesis gas from a hydrocarbon feed stream; and
a post converter comprising a shell housing a catalyst, said catalyst being active for catalyzing steam methane reforming, methanation and reverse water gas shift reactions; said post converter comprising a conduit for supplying a CO 2 rich gas stream into a mixing zone of said post converter, said mixing zone being upstream said catalyst, where said CO 2 rich gas stream in said conduit upstream said mixing zone is in heat exchange relationship with gas flowing over said catalyst downstream the mixing zone;
where said system further comprises a pipe for supplying at least a part of said first synthesis gas from said synthesis gas generation reactor into said mixing zone of said post converter, thereby combining said at least part of the first synthesis gas and said CO 2 rich gas stream to a mixed gas,
wherein said post converter further comprises an outlet for outletting a product synthesis gas from said post converter.

2. A system according to claim 1 , wherein said synthesis gas generation reactor is an autothermal reforming reactor, a thermal partial oxidation reactor, a catalytic partial oxidation reactor or a steam methane reforming reactor.

3. A system according to claim 1 , wherein said conduit comprises a first part arranged for conducting said CO 2 rich gas stream in heat exchange relationship with said product synthesis gas.

4. A system according to claim 1 , wherein said conduit comprises a second part arranged for conducting said CO 2 rich gas stream in heat exchange relationship with the mixed gas in said mixing zone.

5. A system according to claim 1 , wherein said CO 2 rich gas stream is heated in a fired heater, in an electrically heated heater, by heat exchange with at least part of the product synthesis gas exiting the post converter, and/or by heat exchange with superheated steam prior to being inlet into the post converter.

6. A system according to claim 1 , wherein the catalyst is a steam reforming catalyst.

7. A process for production of a synthesis gas, comprising:
in a synthesis gas generation reactor producing a first synthesis gas from a hydrocarbon feed stream;
supplying a CO 2 rich gas stream into a mixing zone of a post converter via a conduit, where said post converter comprises a shell housing a catalyst, where said CO 2 rich gas stream in said conduit upstream said mixing zone is in heat exchange relationship with gas flowing over catalyst prior to mixing said CO 2 rich gas stream with at least part of the first synthesis gas in said mixing zone,
supplying said at least a part of the first synthesis gas from said synthesis gas generation reactor into a mixing zone of said post converter via a pipe, thereby combining said at least part of the first synthesis gas and said CO 2 rich gas stream to a mixed gas, where said post converter, said catalyst being active for catalyzing steam methane reforming, methanation and reverse water gas shift reactions, and where said mixing zone is upstream said catalyst,
producing a product synthesis gas from said mixed gas by carrying out steam methane reforming, methanation and reverse water gas shift reactions over said catalyst, and
outletting said product synthesis gas from said post converter.

8. A process according to claim 7 , wherein said synthesis gas generation reactor is an autothermal reforming reactor, a partial oxidation reactor, a catalytic partial oxidation reactor or a steam methane reforming reactor.

9. A process according to claim 7 , wherein said CO 2 rich gas stream is conducted in heat exchange relationship with said product synthesis gas upstream said catalyst.

10. A process according to claim 7 , wherein said CO 2 rich gas stream is conducted in heat exchange relationship with the mixed gas in said mixing zone downstream said catalyst.

11. A process according to claim 7 , wherein said CO 2 rich gas stream is heated in a fired heater, in an electrically heated heater, by heat exchange with at least part of the product synthesis gas exiting the post converter, and/or by heat exchange with superheated steam prior to being inlet into the post converter.

12. A process according to claim 7 , wherein the catalyst is a steam reforming catalyst.

Assignees

• Haldor Topsoe As

Inventors

• Mortensen Peter Mølgaard
• Aasberg-Petersen Kim

Classifications

• C01B2203/0405

  Purification by membrane separation · CPC title

• C01B2203/046

  Purification by cryogenic separation · CPC title

• C01B2203/0255

  containing a non-catalytic partial oxidation step · CPC title

• C01B2203/0244

  the reforming step being an autothermal reforming step, e.g. secondary reforming processes · CPC title

• C01B3/382 Primary

  Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation · CPC title