Method of preparing porous silicone article and use of the silicone article

Patent metadata

Field	Value
Publication number	US-11446859-B2
Application number	US-201816498985-A
Country	US
Kind code	B2
Filing date	Mar 30, 2018
Priority date	Mar 30, 2017
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

A method of forming a porous three-dimensional (3D) silicone article is disclosed. The method comprises I) printing a first composition with a 3D printer to form a first layer from the first composition. The method further comprises II) printing a second composition on the first layer with the 3D printer to form a second layer from the second composition on the first layer. At least one of the first and second compositions comprises a silicone composition. In the method, step II) may optionally be repeated with independently selected composition(s) for any additional layer(s). At least one of the first and second layers does not consist of linear filaments. Finally, the method comprises III) exposing the layers to a solidification condition. The porous three-dimensional (3D) silicone article defines a plurality of voids.

First claim

What is claimed is:

1. A method of forming a porous three-dimensional (3D) silicone article, said method comprising:
I) printing a first composition with a 3D printer to form a first layer from the first composition;
II) printing a second composition on the first layer with the 3D printer to form a second layer from the second composition on the first layer;
optionally, repeating step II) with independently selected composition(s) for any additional layer(s); and
III) exposing the layers to a solidification condition;
wherein at least one of the first and second compositions comprises a silicone composition selected from (a) hydrosilylation-curable silicone compositions; (b) condensation-curable silicone compositions; (c) thiol-ene reaction-curable silicone compositions; (d) free-radical-curable silicone compositions; and (e) ring-opening reaction-curable silicone compositions;
wherein at least one of the first and second layers does not consist of linear filaments;
wherein the porous three-dimensional (3D) silicone article defines a plurality of voids;
wherein the first layer comprises a first non-linear filament and the second layer comprises a second non-linear filament, and wherein the plurality of voids are defined by at least the first and second non-linear filaments; or
wherein: (i) the first layer comprises fused droplets formed from the first composition, the second layer comprises fused droplets formed from the second composition, and wherein the plurality of voids are defined by at least deposition patterns of the fused droplets of the first and second layers, respectively; (ii) the first layer comprises fused powders formed from the first composition, the second layer comprises fused powders formed form the second composition, and wherein the plurality of voids are defined by at least fusion patterns of the fused powders of the first and second layers, respectively; (iii) the first layer comprises a selectively solidified pattern, the second layer comprises a selectively solidified pattern, and wherein the plurality of voids are defined at least by solidification patterns of the selectively solidified patterns of the first and second layers, respectively; or (iv) a combination of (i) to (iii); or
wherein the method prepares a 3D silicone article, and the method further comprises forming voids in the 3D silicone article to provide the porous 3D silicone article by (i) selectively etching portions of the 3D silicone article to form the plurality of voids and give the porous 3D silicone article; (ii) exposing the layers to the solidification condition to selectively solidify portions of the 3D silicone article to form the plurality of voids, thereby forming the porous 3D silicone article; or (iii) both (i) and (ii).

2. The method of claim 1 , wherein: (i) the plurality of voids are open-celled; (ii) the plurality of voids are closed-celled; or (iii) a combination of (i) and (ii).

3. The method of claim 1 , wherein after I) the first layer is exposed to a solidification condition to give an at least partially solidified first layer such that II) is further defined as II) printing a second composition on the at least partially solidified first layer with the 3D printer to form a second layer on the at least partially solidified first layer.

4. The method of claim 1 , wherein the solidification condition is selected from: (i) exposure to moisture; (ii) exposure to heat; (iii) exposure to irradiation; (iv) reduced ambient temperature; (v) exposure to solvent; (vi) exposure to mechanical vibration; or (vii) any combination of (i) to (vi).

5. The method of claim 1 , wherein the first and second compositions are the same as one another.

6. The method according to claim 1 , wherein the 3D printer is selected from a fused filament fabrication printer, a fused deposition modeling printer, a direct ink deposition printer, a selective laser sintering printer, a selective laser melting printer, a stereolithography printer, a powder bed (binder jet) printer, a material jet printer, a direct metal laser sintering printer, an electron beam melting printer, a laminated object manufacturing deposition printer, a directed energy deposition printer, a laser powder forming printer, a polyjet printer, an ink-jetting printer, a material jetting printer, and a syringe extrusion printer.

Assignees

• Dow Silicones Corp

Inventors

• Reese Herschel Henry
• Zhu Bizhong

Classifications

• B33Y80/00

  Products made by additive manufacturing · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• C08G77/00

  Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule · CPC title

• B29C64/118 Primary

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title

• B29C44/34

  Auxiliary operations · CPC title