Process for capturing a heavy metal contained in a moist gas, integrating a heat pump to cool the gas before eliminating water

Patent metadata

Field	Value
Publication number	US-11446607-B2
Application number	US-201414909326-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jul 31, 2013
Publication date	Sep 20, 2022
Grant date	Sep 20, 2022

Abstract

Capturing mercury or arsenic heavy metal from a moist gas containing water vapour, by:a) cooling the moist gas by heat exchange with a heat transfer fluid produced ine) in order to obtain a gas cooled to a temperature Tf, vaporizing the heat transfer fluid;b) separating condensed water and condensates contained in the cooled gas obtained in a) obtaining a gas depleted in water and a liquid stream containing water;c) compressing vaporized heat transfer fluid obtained from a) obtaining compressed heat transfer fluid;d) heating water-depleted gas by heat exchange with compressed heat transfer fluid obtained in c) obtaining a cooled heat transfer fluid and a gas reheated to a temperature Tc;e) decompressing cooled heat transfer fluid obtained in d), recycling heat transfer fluid to a);f) contacting reheated gas obtained in d) with a capture mass for said heavy metal.

First claim

The invention claimed is:

1. A process for capturing at least one mercury or arsenic heavy metal, contained in a gaseous hydrocarbon effluent comprising water vapor, comprising:
a) cooling ( 1000 ) the gaseous hydrocarbon effluent by heat exchange with a heat transfer fluid produced in e) in order to obtain a gas cooled 2 to 10° C. to a temperature Tf, the heat transfer fluid being vaporized during a);
b) separating ( 2000 ) at least a portion of condensed water contained in the cooled gas obtained in a) in a manner such as to obtain a gas which is depleted in water and a liquid stream containing water;
c) compressing ( 4000 ) the vaporized heat transfer fluid obtained from a) in a manner such as to obtain a compressed heat transfer fluid;
d) heating ( 1002 ) the water-depleted gas by heat exchange with the compressed heat transfer fluid obtained in c) in order to obtain a cooled heat transfer fluid and a gas reheated 2 to 10° C. to a temperature Tc, the temperature Tc being determined in a manner such that the reheated moist gas obtained in d) has a relative humidity of less than 75%;
e) decompressing ( 5000 ) the cooled heat transfer fluid obtained in d), the decompressed heat transfer fluid being recycled to a);
f) bringing the reheated gas obtained in d) into contact ( 3000 ) with a capture mass for said heavy metal in order to obtain a gas depleted in heavy metal.

2. The process according to claim 1 , in which the temperature Tc is determined in a manner such that the reheated moist gas obtained in d) has a relative humidity of less than 50%.

3. The process according to claim 1 , in which the capture mass comprises an active phase comprising at least one metallic sulphide of a copper (Cu), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co) or nickel (Ni).

4. The process according to claim 1 , in which the capture mass comprises an active phase of elemental sulfur.

5. The process according to claim 1 , in which, when the moist gas contains H 2 S, the capture mass comprises an active phase of at least one metallic oxide of copper (Cu), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co) or nickel (Ni).

6. The process according to claim 1 , in which the capture mass comprises an active phase of at least one metallic oxide of copper (Cu) or lead (Pb).

7. The process according to claim 3 , in which the active phase is distributed over a porous support, the porous support being an alumina, a phosphorus-containing alumina, a silica-alumina, a silica, a clay, an activated carbon, a zeolite, a titanium oxide, a zirconium oxide or a mixture thereof.

8. The process according to claim 1 , in which the heat transfer fluid is a hydrocarbon containing 1 to 7 carbon atoms and optionally one or more heteroatomic ligands.

9. The process according to claim 1 , in which at least one of the following operations is carried out:
before carrying out b), carrying out a supplemental cooling of the cooled gas obtained in a);
before carrying out c), carrying out a supplemental heating of the vaporized heat transfer fluid obtained in a);
before carrying out f), carrying out a supplemental heating of the reheated gas obtained in d);
before carrying out e), carrying out a supplemental cooling of the cooled heat transfer fluid obtained in d).

10. The process according to claim 9 , further comprising exchanging of heat from the vaporized heat transfer fluid obtained in a) to the cooled heat transfer fluid obtained in d).

11. The process according to claim 1 , in which in b), a coalescer is used in order to separate the condensed water contained in the cooled gas obtained in a).

12. The process according to claim 1 , in which mercury contained in the aqueous liquid stream obtained from b) is captured.

13. The process according to claim 1 , in which the moist gas is a natural gas.

14. The process according to claim 1 , in which the moist gas is a natural gas and in which before carrying out a), the following are carried out:
extracting a natural gas from an underground deposit; then
introducing the natural gas into a sludge elimination device; then
introducing the natural gas into a gas-liquid separation device then sending the natural gas to a);
then, after f), the following are carried out:
eliminating at least a portion of H 2 S and CO 2 contained in the gas depleted in heavy metal; then
eliminating at least a portion of water vapor contained in the gas depleted in heavy metal.

15. The process according to claim 1 , wherein the moist gas to be treated is at a pressure of 2-10 MPa.

16. The process according to claim 1 , wherein the moist gas to be treated is at a pressure of 5-9 MPa.

17. The process according to claim 1 , wherein the moist gas is at a temperature of 20 to 80° C.

18. A process for capturing at least one mercury or arsenic heavy metal, contained in a moist gas that is a natural gas, a shale gas, a coal gas, a synthesis gas, combustion fumes, a gaseous hydrocarbon effluent, or rare earth production exhaust gas, comprising water vapor, consisting of:
a) introducing the moist gas into a primary gas-liquid separator ( 6 ) separating a liquid stream comprising water and hydrocarbon from the moist gas to produce an effluent moist gas,
b) cooling ( 1000 ) the effluent moist gas by heat exchange with a heat transfer fluid produced in e) in order to obtain a gas cooled to a temperature Tf, the heat transfer fluid being vaporized during b);
c) separating ( 2000 ) at least a portion of condensed water contained in the cooled gas obtained in b in a manner such as to obtain a gas which is depleted in water and a liquid stream containing water;
d) compressing ( 4000 ) the vaporized heat transfer fluid obtained from b) in a manner such as to obtain a compressed heat transfer fluid;
e) heating ( 1002 ) the water-depleted gas by heat exchange with the compressed heat transfer fluid obtained in d) in order to obtain a cooled heat transfer fluid and a gas reheated to a temperature Tc, the temperature Tc being determined in a manner such that the reheated moist gas obtained in e) has a relative humidity of less than 75% in which the difference between Tc and Tf is less than 20° C.;
f) decompressing ( 5000 ) the cooled heat transfer fluid obtained in e, the decompressed heat transfer fluid being recycled to b);
g) bringing the reheated gas obtained in e into contact ( 3000 ) with a capture mass for said heavy metal in order to obtain a gas depleted in heavy metal.

19. The process according to claim 1 , wherein the temperature Tc is determined in a manner such that the reheated moist gas obtained in d) has a relative humidity of 50% to less than 75%.

Assignees

• Ifp Energies Now

Inventors

• Guillou Florent
• Porcheron Fabien
• Barthelet Karin
• Baudot Arnaud
• Lepine Yann
• Jubin Clotilde

Classifications

• C10L2290/06

  Heat exchange, direct or indirect · CPC title

• B01D2251/602

  Oxides · CPC title

• C10L2290/54

  Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• B01D2257/602

  Mercury or mercury compounds · CPC title