Solid electrolyte composition, sheet for all-solid state secondary battery, all-solid state secondary battery, and methods for manufacturing sheet for all-solid state secondary battery and all-solid state secondary battery

Patent metadata

Field	Value
Publication number	US-11444315-B2
Application number	US-201916255948-A
Country	US
Kind code	B2
Filing date	Jan 24, 2019
Priority date	Jul 28, 2016
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

Provided are a solid electrolyte composition including a sulfide-based inorganic solid electrolyte, a salt of a metal belonging to Group I or II of the periodic table, and a multibranched polymer, in which the multibranched polymer has a core portion and at least three arm portions that bond to the core portion, and the arm portion dissolves a metal ion of the salt of the metal belonging to Group I or II of the periodic table, a sheet for an all-solid state secondary battery, an all-solid state secondary battery, and methods for manufacturing a sheet for an all-solid state secondary battery and an all-solid state secondary battery.

First claim

What is claimed is:

1. A solid electrolyte composition comprising:
a sulfide-based inorganic solid electrolyte having a conductivity of an ion of a metal belonging to Group I or II of the periodic table;
a salt of a metal belonging to Group I or II of the periodic table; and
a multibranched polymer,
wherein the multibranched polymer has a core portion and at least three arm portions that bond to the core portion, and the arm portion dissolves a metal ion of the salt of the metal belonging to Group I or II of the periodic table,
wherein the arm portion includes a polymer structure containing at least one repeating unit having an alkylene oxide group, a carbonate group, an ester group, an amide group, or a silicone group, and
wherein the repeating unit is a repeating unit represented by Formula (A),

in the formula, R 1 represents a hydrogen atom, a halogen atom, a cyano group, an alkyl group, an alkoxy group, or an aryl group, R 2 represents a hydrogen atom, a halogen atom, a cyano group, an alkyl group, an alkoxy group, or an aryl group, and L 1 represents a divalent linking group including at least one of an alkylene oxide group, a carbonate group, an ester group, an amide group, or a silicone group.

2. The solid electrolyte composition according to claim 1 ,
wherein a main chain of the polymer structure constituting the arm portion is constituted by including an alkylene oxide group, a carbonate group, and/or an ester group.

3. The solid electrolyte composition according to claim 1 ,
wherein a mass-average molecular weight of the arm portion is 500 or more and 1,000,000 or less.

4. The solid electrolyte composition according to claim 1 ,
wherein the multibranched polymer is represented by Formula (B),
L X—P 1 ) n   Formula (B)

in the formula, L represents an n-valent linking group, P 1 represents a polymer chain, n represents an integer of 3 or more, nP 1 's may be identical to or different from each other, L—(X) n , forms the core portion, (P 1 ) n forms the arm portion, X represents an oxygen atom, a sulfur atom, or —N(R 3 )—, and R 3 represents a hydrogen atom, an alkyl group, or an aryl group.

5. The solid electrolyte composition according to claim 1 ,
wherein the core portion has a partial structure represented by any of the following formulae,

in the formulae, Rx represents a divalent substituent including an oxygen atom, a nitrogen atom, a sulfur atom, or a phosphorus atom, and * represents a bonding site in the multibranched polymer.

6. The solid electrolyte composition according to claim 1 ,
wherein the core portion is a group of atoms having a molecular weight of 200 or more.

7. The solid electrolyte composition according to claim 5 ,
wherein the core portion has a partial structure represented by any of the following formulae,

in the formulae, * represents a bonding site in the multibranched polymer.

8. The solid electrolyte composition according to claim 1 ,
wherein a content of the salt of the metal belonging to Group I or II of the periodic table is 5% by mass to 60% by mass with respect to a total of 100% by mass of the multibranched polymer and the salt of the metal belonging to Group I or II of the periodic table.

9. The solid electrolyte composition according to claim 1 ,
wherein the salt of the metal belonging to Group I or II of the periodic table is lithium bis(trifluoromethanesulfonyl)imide, lithium bis(fluorosulfonyl)imide and/or lithium bisoxalatoborate.

10. The solid electrolyte composition according to claim 1 , further comprising:
an active material capable of intercalating and deintercalating an ion of a metal belonging to Group I or II of the periodic table.

11. The solid electrolyte composition according to claim 1 ,
wherein a content of the multibranched polymer is 0.1 parts by mass or more and 10 parts by mass or less with respect to 100 parts by mass of the sulfide-based inorganic solid electrolyte having a conductivity of an ion of a metal belonging to Group I or II of the periodic table.

12. A sheet for an all-solid state secondary battery comprising:
a layer of the solid electrolyte composition according to claim 1 on a base material.

13. An all-solid state secondary battery comprising:
a positive electrode active material layer;
a negative electrode active material layer; and
an inorganic solid electrolyte layer,
wherein at least one layer of the positive electrode active material layer, the negative electrode active material layer, or the inorganic solid electrolyte layer is a layer of the solid electrolyte composition according to claim 1 .

14. A method for manufacturing a sheet for an all-solid state secondary battery, the method comprising: a step of applying the solid electrolyte composition according to claim 1 onto a base material.

15. A method for manufacturing an all-solid state secondary battery, the method comprising:
a step of applying the solid electrolyte composition according to claim 1 onto a base material.

Assignees

• Fujifilm Corp

Inventors

• Makino Masaomi
• Mochizuki Hiroaki
• Yawata Toshihiko

Classifications

• H01M10/056 Primary

  characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M2300/0068

  inorganic · CPC title

• H01B1/06

  mainly consisting of other non-metallic substances · CPC title

• H01M10/0562

  Solid materials · CPC title