Organic electro-luminescent element and bioinstrumentation device

Patent metadata

Field	Value
Publication number	US-11444248-B2
Application number	US-201715823601-A
Country	US
Kind code	B2
Filing date	Nov 28, 2017
Priority date	Nov 30, 2016
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

An organic electro-luminescent element having a luminescence peak in a near-infrared range, comprising a positive electrode, a negative electrode, and at least one organic layer including a luminescent layer located between the positive electrode and the negative electrode, wherein the luminescent layer comprises a host material, a delayed fluorescent material and a luminescent material, wherein each of the delayed fluorescent material and the luminescent material have a structure with two or three benzene rings bonded to an N atom.

First claim

The invention claimed is:

1. An organic electro-luminescent element having a luminescence peak in a near-infrared range, comprising a positive electrode, a negative electrode, and at least one organic layer including a luminescent layer located between the positive electrode and the negative electrode, wherein the luminescent layer comprises:
a host material;
a delayed fluorescent material as an assistant dopant; and
a luminescent material as a dopant, wherein each of the delayed fluorescent material and the luminescent material has a N-containing structure with two or three benzene rings bonded to an N atom,
wherein the N-containing structure of each of the delayed fluorescent material and the luminescent material comprises a structure selected from formulas (1) to (6):

the structure of the delayed fluorescent material selected from formulas (1) to (6) is also selected as the N-containing structure of the luminescent material, and
each of the delayed fluorescent material and the luminescent material further has a fused ring structure in addition to the N-containing structure, wherein the fused ring structures of the delayed fluorescent material and the luminescent material each comprise an equivalent set of at least two successive rings selected from the following group:

2. An organic electro-luminescent element having a luminescence peak in a near-infrared range, comprising a positive electrode, a negative electrode, and at least one organic layer including a luminescent layer located between the positive electrode and the negative electrode, wherein the luminescent layer comprises:
a host material;
a delayed fluorescent material as an assistant dopant; and
a luminescent material as a dopant, wherein each of the delayed fluorescent material and the luminescent material has a N-containing structure with two or three benzene rings bonded to an N atom,
wherein the N-containing structure of each of the delayed fluorescent material and the luminescent material is selected from formulas (1) to (6):

and
each of the delayed fluorescent material and the luminescent material further has a fused ring structure in addition to the N-containing structure, wherein the fused ring structures of the delayed fluorescent material and the luminescent material each having an equivalent set of at least two successive rings selected from the following group:

3. The organic electro-luminescent element according to claim 1 , wherein the N-containing structure comprises a structure represented by formula (7):

4. A bioinstrumentation device comprising:
a photo detector; and
an organic electro-luminescent element having a luminescence peak in a near-infrared range, comprising a positive electrode, a negative electrode, and at least one organic layer including a luminescent layer located between the positive electrode and the negative electrode, wherein the luminescent layer comprises:
a host material;
a delayed fluorescent material as an assistant dopant; and
a luminescent material as a dopant, wherein each of the delayed fluorescent material and the luminescent material has a N-containing structure with two or three benzene rings bonded to an N atom,
wherein the N-containing structure of each of the delayed fluorescent material and the luminescent material is selected from formulas (1) to (6):

and
each of the delayed fluorescent material and the luminescent material further has a fused ring structure in addition to the N-containing structure, wherein the fused ring structures of the delayed fluorescent material and the luminescent material each having an equivalent set of at least two successive rings selected from the following group:

5. The bioinstrumentation device according to claim 4 , wherein the structure of the delayed fluorescent material selected from formulas (1) to (6) is the same as the N-containing structure of the luminescent material.

6. The bioinstrumentation device according to claim 4 , wherein the N-containing structure of at least one of the delayed fluorescent material and the luminescent material comprises a structure represented by formula (7):

7. The bioinstrumentation device according to claim 6 , wherein each of the delayed fluorescent material and the luminescent material has the N-containing structure represented by formula (7).

8. The organic electro-luminescent element according to claim 1 , wherein a content of the host material is 50 wt % to 90 wt %, a content of the delayed fluorescent material is 5.0 wt % to 45 wt %, and a content of the luminescent material is 0.3 wt % to 4.0 wt % based on a total content of the host material, the delayed fluorescent material, and the luminescent material.

9. The organic electro-luminescent element according to claim 2 , wherein a content of the host material is 50 wt % to 90 wt %, a content of the delayed fluorescent material is 5.0 wt % to 45 wt %, a content of the luminescent material is 0.3 wt % to 4.0 wt % based on a total content of the host material, the delayed fluorescent material, and the luminescent material.

10. The bioinstrumentation device according to claim 4 , wherein a content of the host material is 50 wt % to 90 wt %, a content of the delayed fluorescent material is 5.0 wt % to 45 wt %, a content of the luminescent material is 0.3 wt % to 4.0 wt % based on a total content of the host material, the delayed fluorescent material, and the luminescent material.

Assignees

• Univ Kyushu Nat Univ Corp
• Hamamatsu Photonics Kk

Inventors

• Adachi Chihaya
• Nakanotani Hajime
• Yamanaka Takahiko
• Hara Shigeo
• Hirohata Toru

Classifications

• C07D265/38

  [b, e]-condensed with two six-membered rings · CPC title

• C07D279/18

  [b, e]-condensed with two six-membered rings · CPC title

• A61B5/0059

  using light, e.g. diagnosis by transillumination, diascopy, fluorescence (photoacoustic A61B5/0093; optical measurement of heart rate A61B5/02416; optical measurement of blood flow A61B5/0261; optical measurement of analytes A61B5/1455) · CPC title

• G01N21/6486

  Measuring fluorescence of biological material, e.g. DNA, RNA, cells (G01N21/6428 takes precedence) · CPC title

• C07D209/82

  Carbazoles; Hydrogenated carbazoles · CPC title