Low-reflection coated glass sheet, method for producing low-reflection coated substrate, and coating liquid for forming low-reflection coating of low-reflection coated substrate

Patent metadata

Field	Value
Publication number	US-11442200-B2
Application number	US-201716320901-A
Country	US
Kind code	B2
Filing date	Jul 7, 2017
Priority date	Jul 28, 2016
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

A low-reflection coated glass sheet of the present invention includes a glass sheet and a low-reflection coating. The low-reflection coating is formed on at least a portion of one principal surface of the glass sheet and contains a binder containing silica as a main component, fine silica particles bound by the binder, and fine titania particles bound by the binder. The low-reflection coating satisfies the following relationships: 30 mass %<CSP<68 mass %; 12 mass %≤CTP<50 mass %; 20 mass %<CBinder<43.75 mass %; CTP/CBinder≥0.6; CBinder<25 mass % in the case of CSP≥55 mass %; and CTP>20 mass % in the case of CSP<55 mass %. The low-reflection coated glass sheet has a transmittance gain of 2.0% or more.

First claim

The invention claimed is:

1. A low-reflection coated glass sheet comprising:
a glass sheet; and
a low-reflection coating formed on at least a portion of one principal surface of the glass sheet, the low-reflection coating comprising a binder containing silica as a main component, fine silica particles bound by the binder, and fine titania particles bound by the binder, wherein
the low-reflection coating satisfies the following relationships when the content of the fine silica particles in the low-reflection coating, the content of the fine titania particles in the low-reflection coating, and the content of the silica of the binder in the low-reflection coating are defined as C SP mass %, C TP mass %, and C Binder mass %, respectively:
30 mass %<C SP <68 mass %;
12 mass %≤C TP <50 mass %;
20 mass %<C Binder <43.75 mass %;
C TP /C Binder ≥0.6;
C Binder <25 mass % in the case of C SP ≥55 mass %; and
C TP >20 mass % in the case of C SP <55 mass %, and
the low-reflection coated glass sheet has a transmittance gain of 2.0% or more, the transmittance gain being determined by subtracting an average light transmittance of the glass sheet unprovided with the low-reflection coating in the wavelength range of 380 nm to 850 nm from an average light transmittance of the low-reflection coated glass sheet in the wavelength range of 380 nm to 850 nm.

2. The low-reflection coated glass sheet according to claim 1 , wherein the low-reflection coating further satisfies the relationship C TP /C Binder >0.8.

3. The low-reflection coated glass sheet according to claim 1 , wherein the low-reflection coating further satisfies the following relationships:
30 mass %<C SP ≤65 mass %;
15 mass %≤C TP ≤40 mass %; and
20 mass %<C Binder ≤30 mass %.

4. The low-reflection coated glass sheet according to claim 1 , wherein the low-reflection coating further satisfies the following relationships:
35 mass %≤C SP ≤60 mass %;
15 mass %≤C TP ≤40 mass %; and
20 mass %<C Binder <25 mass %.

5. The low-reflection coated glass sheet according to claim 1 , wherein a critical contact angle of water on the low-reflection coating, as defined in Japanese Industrial Standard (JIS) R 1703-1:2007, is 5° or less.

6. The low-reflection coated glass sheet according to claim 1 , wherein when, according to JIS R 1703-1:2007, oleic acid is applied to the low-reflection coating and subsequently the low-reflection coating is irradiated with ultraviolet light at an intensity of 1.0 mW/cm 2 , a period of time from start of the ultraviolet irradiation to a point at which a contact angle of water on the low-reflection coating reaches 5° is 40 hours or less.

7. A method for producing a low-reflection coated glass sheet according to claim 1 ,
the method comprising: forming a coating film by applying a coating liquid to the glass sheet; and forming the low-reflection coating by drying and curing the coating film, wherein a maximum temperature reached by a surface of the glass sheet during the drying and curing of the coating film is 120° C. or higher and 350° C. or lower.

8. The method according to claim 7 , wherein in the drying and curing of the coating film, a period of time during which the surface of the glass sheet has a temperature of 200° C. or higher is 5 minutes or less.

9. The method according to claim 7 , wherein in the drying and curing of the coating film, a period of time during which the surface of the glass sheet has a temperature of 120° C. or higher is 3 minutes or less.

10. The method according to claim 7 , wherein
the coating liquid comprises fine silica particles, fine titania particles, a source material for the binder, and a solvent,
the source material for the binder comprises a silicon alkoxide, and
the solvent comprises an organic solvent as a main component, the organic solvent being miscible with water and having a boiling point of 150° C. or lower.

11. A coating liquid for forming a low-reflection coating of a low-reflection coated glass sheet according to claim 1 ,
the low-reflection coating being formed on at least a portion of one principal surface of the glass sheet, the low-reflection coating including a binder containing silica as a main component, fine silica particles bound by the binder, and fine titania particles bound by the binder, wherein
the coating liquid comprising fine silica particles, fine titania particles, a source material for the binder, and a solvent, wherein
the source material for the binder comprises a silicon alkoxide, and
the solvent comprises an organic solvent as a main component, the organic solvent being miscible with water and having a boiling point of 150° C. or lower.

12. The coating liquid according to claim 11 , further comprising an acid having an acid dissociation constant pKa of 2.5 or less as a hydrolysis catalyst for hydrolysis of the silicon alkoxide.

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Koyo Mizuho
• Nakazawa Tatsuhiro
• Kawazu Mitsuhiro

Classifications

• B05D3/00

  Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials (successively applying liquids or other fluent materials B05D1/36; drying ovens F26B) · CPC title

• C09D183/00

  Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers · CPC title

• B05D2518/10

  Silicon-containing polymers · CPC title

• C03C17/006

  with materials of composite character · CPC title

• C09D7/68

  Particle size between 100-1000 nm · CPC title