Process and plant for the production of argon by cryogenic distillation of air

Patent metadata

Field	Value
Publication number	US-11441840-B2
Application number	US-201916527467-A
Country	US
Kind code	B2
Filing date	Jul 31, 2019
Priority date	Aug 1, 2018
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

Plant for the production of argon by cryogenic distillation, comprising an argon separation column, means for sending a gas containing argon and oxygen to the argon separation column, means for extracting a fluid enriched in argon at the top of the argon separation column, means for extracting a liquid enriched in oxygen at the bottom of the argon separation column and at least two storage tanks, positioned one above the other, each storage tank being connected to two different intermediate levels of the argon separation column by two pipes, the two storage tanks being contiguous.

First claim

The invention claimed is:

1. A process for the production of argon by cryogenic distillation, the process comprising the steps of:
sending a gas enriched in argon that was produced by air separation in a system of columns to an argon separation column;
withdrawing a flow rich in argon at a top of the argon separation column; and
withdrawing a liquid enriched in oxygen at a bottom of the argon separation column; returning the liquid enriched in oxygen to the system of columns;
determining, using a controller, whether a load of the argon separation column is below a first threshold;
determining, using the controller, whether the load of the argon separation column is above a second threshold, wherein the second threshold is greater than the first threshold;
whereupon a determination that the load of the argon separation column is below a first threshold, the process further comprises a first mode of operation,
whereupon a determination that the load of the argon separation column is above a second threshold, the process further comprises a second mode of operation,
whereupon a determination that the load of the argon separation column is between the first threshold and the second threshold, the process further comprises a third operation,
i) wherein during the first mode of operation the process comprises the steps of:
withdrawing a first liquid from a first intermediate location of the argon separation column and storing the first liquid in a first storage tank;
preventing, using a first valve, the first liquid stored within the first storage tank from flowing to a second intermediate location of the argon separation column;
withdrawing a third liquid from the argon separation column at a third intermediate location of the argon separation column and storing the third liquid in a second storage tank;
preventing, using a second valve, the third liquid stored within the second storage tank from flowing to a fourth intermediate location of the argon separation column,

ii) wherein during the second mode of operation, the process comprises the steps of:
preventing, using a third valve, the first liquid from the first intermediate location of the argon separation column from flowing to the first storage tank;
sending liquid argon from the first storage tank to the second intermediate location of the argon separation column, wherein the second intermediate location is separated from the first intermediate location by at least one layer of structured packing that is configured for the exchange of mass and of heat, the second intermediate location being located below the first intermediate location;
preventing, using a fourth valve, the third liquid from the third intermediate location of the argon separation column from flowing to the second storage tank; and
sending the third liquid from the second storage tank to the argon separation column at a fourth intermediate location of the argon separation column, wherein the fourth intermediate location is separated from the third intermediate location by at least one layer of structured packing that is configured for the exchange of mass and of heat, the fourth intermediate location being located below the third intermediate location and the third intermediate location not being located above the second intermediate location.

2. The process according to claim 1 , wherein no structured packing is positioned between the second and third intermediate locations.

3. The process according to claim 1 , wherein the argon separation column comprises a top condenser, wherein the process further comprises:
feeding the top condenser with an oxygen rich liquid received from a lower portion of the system of columns; and
sending a vaporized liquid from the top condenser to the system of columns.

4. The process according to claim 3 , wherein the step of determining, using the controller, whether the load of the argon separation column is below the first threshold further comprises measuring a flow rate of the vaporized liquid sent from the condenser C to the system of columns.

5. The process according to claim 1 , wherein during the third mode of operation, the process comprises the steps of:
preventing, using a fifth valve, flow of the first liquid from the first intermediate location of the argon separation column to the first storage tank, and
preventing, using a sixth valve, a flow of the third liquid from the third intermediate location of the argon separation column to the second storage tank;
preventing, using the first valve, the first liquid stored within the first storage tank from flowing to the second intermediate location of the argon separation column from the first storage tank;
preventing, using the second valve, the third liquid stored within the second storage tank from flowing to the fourth intermediate location of the argon separation column.

6. A plant for the production of argon by cryogenic distillation of air in a system of columns for the implementation of a process according to claim 1 , the plant comprising the argon separation column, a first pipe configured to send a gas containing argon and oxygen to the argon separation column, a second pipe configured to extract a fluid enriched in argon at a top of the argon separation column, a third pipe configured to extract a liquid enriched in oxygen at a bottom of the argon separation column and the first storage tank and the second storage tank, wherein the second storage tank is positioned above the first storage tank, and each of the first and second storage tank is connected to the second and fourth intermediate locations, respectively, by a fourth pipe and a fifth pipe, wherein the first and second storage tanks are contiguous.

7. The plant according to claim 6 , in which the first and second storage tanks are formed by two tanks in a common shell.

8. The plant according to claim 6 , comprising an absence of a pump or compressor configured to pressurize the liquid to be sent from the first intermediate location of the argon separation column to the first storage tank and an absence of a pump or compressor configured to pressurize the first liquid to be sent from the first storage tank to the second intermediate location of the argon separation column, the elevation of the first storage tank being chosen as a function of a point of withdrawal of the first liquid from the first intermediate location of the argon column and of a point of return to the second intermediate location of the argon separation column of the first liquid argon.

9. The plant according to claim 6 , in which the first and second storage tanks are connected to one another in order to form a structure positioned on the ground.

10. The plant according to claim 6 , in which the first and second storage tanks form an elongated body, a length of which is equal to at least half of a total length of the argon separation column.

11. The plant according to claim 6 , in which at least one of the first and second storage tanks and at least one pipe of the two pipes, or both of the two pips, connected to the respective storage tank is/are positioned so that the liquid passes from the argon separation column to the storage tank and/or vice versa, without using a pump.

12. The plant according to claim 6 , wherein a floor of the first storage tank is positioned at a height that is higher than the second intermediate location.

13. The plant according to claim 6 , in which the first and second storage tanks are positioned in a dedicated cold box.

14. The plant according to claim 6 , in which the first and second storage tanks are positioned in a cold box with the ar

Assignees

• Air Liquide

Inventors

• Briglia Alain
• Staine Frederic
• Leaute Mathieu
• Berthaume Ingrid
• Dos Santos Benedicte

Classifications

• F25J3/04721

  Producing pure argon, e.g. recovered from a crude argon column · CPC title

• F25J3/04866

  Construction and layout of air fractionation equipments, e.g. valves, machines (F25J5/00 takes precedence) · CPC title

• F25J3/04878

  Side by side arrangement of multiple vessels in a main column system, wherein the vessels are normally mounted one upon the other or forming different sections of the same column (multiple vessels of a crude argon column F25J3/04703) · CPC title

• F25J3/044

  using a single pressure main column system only (F25J3/0446, F25J3/04624, F25J3/04636 take precedence) · CPC title

• F25J2290/62

  Details of storing a fluid in a tank · CPC title