Bearing material, bearing element and method

Patent metadata

Field	Value
Publication number	US-11441609-B2
Application number	US-201816212666-A
Country	US
Kind code	B2
Filing date	Dec 6, 2018
Priority date	Dec 7, 2017
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

A bearing material may include a polymeric matrix of polyamide-imide (PAI) polymer material and a plurality of melamine cyanurate particles dispersed within the polymeric matrix.

First claim

The invention claimed is:

1. A bearing material, comprising:
a polymeric matrix of polyamide-imide (PAI) polymer material;
a plurality of metal flakes composed of aluminum; and
a solid lubricant consisting of melamine cyanurate, the melamine cyanurate comprising a plurality of melamine cyanurate particles dispersed within and distributed evenly throughout the polymeric matrix;
wherein the plurality of melamine cyanurate particles have an average particle size of 0.5 μm to 3 μm; and
wherein about 8 wt % to about 12 wt % of the bearing material is melamine cyanurate.

2. The bearing material according to claim 1 , further comprising at least one of a dispersant, an adhesion agent, and a leveller.

3. A bearing element, comprising:
a bearing material including a polymeric matrix of polyamide-imide (PAI) polymer material;
a plurality of melamine cyanurate particles dispersed within and distributed evenly throughout the polymeric matrix such that the bearing material has a uniform composition;
wherein the plurality of melamine cyanurate particles have an average particle size of 0.5 μm to 3 μm;
wherein the plurality of melamine cyanurate particles have a bulk density of 0.24 g/ml, a D 10 of 0.5 μm, a D 50 of 1.3 μm, and a D 90 of 4.7 μm; and
wherein about 8 wt % to about 12 wt % of the bearing material is melamine cyanurate.

4. A method of forming a bearing material, comprising mixing a polyamide-imide (PAI) polymer material with a plurality of particles of melamine cyanurate to define a dispersion, wherein:
mixing the polyamide-imide (PAI) polymer material with the plurality of particles of melamine cyanurate includes evenly distributing the plurality of particles of melamine cyanurate throughout the dispersion; and
the plurality of melamine cyanurate particles have a bulk density of 0.24 g/ml, a D 10 of 0.5 μm, a D 50 of 1.3 μm, and a D 90 of 4.7 μm.

5. The method according to claim 4 , wherein mixing the polyamide-imide (PAI) polymer material with the plurality of particles of melamine cyanurate includes adding a quantity of the plurality of particles of melamine cyanurate to the polyamide-imide (PAI) polymer material such that the plurality of particles of melamine cyanurate form about 2 wt % to about 30 wt % of the dispersion.

6. A method of forming a bearing element, comprising:
depositing onto a bearing element substrate a bearing material including a polymeric matrix of polyamide-imide (PAI) polymer material and a plurality of melamine cyanurate particles dispersed within and distributed evenly throughout the polymeric matrix such that the bearing material has a uniform composition; and
mixing a plurality of aluminum flakes, a leveller, and an adhesion agent with the polyamide-imide (PAI) polymer material and the plurality of particles of melamine cyanurate such that:
the plurality of particles of melamine cyanurate form about 8 wt % to about 12 wt % of the bearing material;
the plurality of melamine cyanurate particles have a D 10 of 0.5 μm, a D 50 of 1.3 μm, and a D 90 of 4.7 μm;
the plurality of aluminum flakes form about 26 wt % of the bearing material; and
the leveller forms less than 0.5 wt % of the bearing material.

7. The bearing element according to claim 3 , further comprising a bearing element substrate and an overlay layer disposed on the bearing element substrate, wherein the overlay layer is composed of the bearing material.

8. The bearing element according to claim 7 , wherein the plurality of melamine cyanurate particles have an average particle size smaller than a thickness of the overlay layer.

9. The bearing element according to claim 7 , wherein the overlay layer has a thickness of 3 μm to 25 μm.

10. The bearing element according to claim 3 , further comprising a bearing element substrate and a plurality of overlay layers disposed on the bearing element substrate one on top of another, wherein each of the plurality of overlay layers is composed of the bearing material.

11. The bearing material according to claim 1 , wherein the plurality of melamine cyanurate particles is the only solid lubricant material dispersed within the polymeric matrix.

12. The bearing material according to claim 1 , wherein the plurality of melamine cyanurate particles have a bulk density of 0.24 g/ml, a D 10 of 0.5 μm, a D 50 of 1.3 μm, and a D 90 of 4.7 μm.

13. The method according to claim 6 , further comprising:
mixing the polyamide-imide (PAI) polymer material with the plurality of particles of melamine cyanurate to define the bearing material; and
maintaining suspension of the plurality of particles of melamine cyanurate within the polyamide-imide (PAI) polymer material prior to depositing the bearing material onto the bearing element via agitating the bearing material.

14. The method according to claim 6 , wherein:
depositing the bearing material onto the bearing element substrate includes depositing a plurality of sub-layers of the bearing material on top of one another; and
the method further comprises removing solvent from each of the plurality of sub-layers via performing a flash-off process between each successive deposition of a sub-layer of the plurality of sub-layers.

15. The bearing material according to claim 1 , further comprising a leveller distributed throughout the polymeric matrix, wherein:
the plurality of aluminum metal flakes form about 26 wt % of the bearing material; and
the leveller forms less than 0.5 wt % of the bearing material.

16. The bearing material according to claim 15 , wherein the plurality of melamine cyanurate particles have a D 10 of 0.5 μm, a D 50 of 1.3 μm, and a D 90 of 4.7 μm.

17. The bearing material according to claim 1 , wherein the plurality of melamine cyanurate particles have a bulk density of 0.24 g/ml and the average particle size of the plurality of melamine cyanurate particles is 1 μm to 2 μm.

18. The bearing material according to claim 1 , wherein the bearing material does not contain graphite, MoS 2 , nor polytetrafluoroethylene (PTFE).

19. The bearing element according to claim 3 , wherein the bearing element is structured as a crankshaft bearing shell for an internal combustion engine.

Assignees

• Mahle Int Gmbh
• Mahle Engine Systems Uk Ltd

Inventors

• Mcewan Kayleigh
• Harvey Jennifer

Classifications

• F16C2360/22

  Internal combustion engines · CPC title

• C08L79/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08K5/34928

  Salts · CPC title

• F16C2223/30

  Coating surfaces · CPC title

• C09D7/63

  organic · CPC title