Transparent multilayer structure for thermal management

Patent metadata

Field	Value
Publication number	US-11440382-B2
Application number	US-201716461417-A
Country	US
Kind code	B2
Filing date	Nov 16, 2017
Priority date	Nov 17, 2016
Publication date	Sep 13, 2022
Grant date	Sep 13, 2022

Abstract

The invention relates to transparent multilayer structures and glazings or glazing elements comprising said multilayer structures, which are suitable for screening an indoor space from a radiation source, comprising, in this order a) optionally a protective layer a, b) a substrate layer based on a thermoplastic polymer, especially an aromatic polycarbonate, having a luminous transmittance in the range of 380 to 780 nm of at least 0.3%, determined at a layer thickness of 4 mm according to DIN ISO 13468-2:2006 (D65, 10°), and a TDS value of less than 40%, determined according to ISO 13837:2008 at a layer thickness of 4 mm, the substrate layer containing at least 0.001 wt. % of an IR absorber different from carbon black, c) if necessary, another layer c based on a thermoplastic polymer with a maximum thickness of 600 μm, d) at least one metal layer d, containing at least one element selected from the group including Ag, Al, Au, Pt, Fe, Cr, Sn, In, Ti, Pd, Nb, Cu, V or their alloys, the sum of thicknesses of all metal layers being 1 nm to not more than 30 nm, and e) optionally a protective layer e, at least 60% of the substrate layer b being covered by metal layer d, the layers following layer d, including the protective layer e, when added up, having a thickness of not more than 100 nm and the metal layer being applied to the side of the substrate layer b designed to be on the face of the multilayer structure facing away from the radiation source.

First claim

The invention claimed is:

1. A transparent multilayer article suitable for shielding a three-dimensional volume from a radiation source, comprising, in this sequence,
a) optionally a protective layer a,
b) a substrate layer b based on a thermoplastic polymer having light transmittance in the range from 380 to 780 nm of at least 3.0% determined at a layer thickness of 4 mm according to DIN ISO 13468-2:2006 (D65, 10°) and
a direct solar transmittance T DS value of less than 40%, determined according to ISO 13837:2008 at a layer thickness of 4 mm, where the substrate layer contains at least 0.001% by weight of an IR absorber other than carbon black,
c) optionally a further layer c based on a thermoplastic polymer having a maximum thickness of 600 μm,
d) at least one metal layer d comprising at least one element selected from Ag, Al, Au, Pt, Fe, Cr, Sn, In, Ti, Pd, Nb, Cu, V or alloys thereof where the sum total of the thicknesses of all metal layers is 1 nm to a maximum of 30 nm, and
e) optionally a protective layer e,
wherein at least 60% of the substrate layer b is covered by metal layer d,
the layers that follow on from layer d, including protective layer e, have a total thickness of not more than 100 nm
and the metal layer is disposed on the side of the substrate layer b intended to lie on the side of the multilayer article facing away from the radiation source.

2. The multilayer article as claimed in claim 1 , wherein the T DS value of the substrate layer b is less than 30%, determined according to ISO 13837:2008 at a layer thickness of 4 mm.

3. The multilayer article as claimed in claim 1 , wherein the IR absorber is selected from borides and/or tungstates.

4. The multilayer article as claimed in claim 1 , wherein the substrate layer b contains 0.003% to 0.009% by weight of IR absorbers other than carbon black.

5. The multilayer article as claimed in claim 1 , wherein the substrate layer b contains 0.004% to 0.008% by weight of lanthanum hexaboride as IR absorber.

6. The multilayer article as claimed in claim 1 , wherein the thermoplastic polymer in the substrate layer b is aromatic polycarbonate.

7. The multilayer article as claimed in claim 1 , wherein the substrate layer contains up to 0.003% by weight of carbon black.

8. The multilayer article as claimed in claim 1 , wherein the multilayer article has a three-dimensionally shaped surface.

9. The multilayer article as claimed in claim 1 , wherein the multilayer article, apart from adhesive layers including any carrier films, does not comprise any further layers between layers b to d for bonding of the individual layers and/or any (semi)metal nitride layers and/or (semi)metal oxide layers.

10. The multilayer article as claimed in claim 1 , wherein the three-dimensional volume to be shielded is a motor vehicle interior, the multilayer article is a bodywork part or part of a bodywork part and the radiation source is the sun.

11. The multilayer article as claimed in claim 1 , wherein the multilayer article comprises the following layers:
Layer a) a scratch-resistant coating based on polysiloxane, and optionally a primer layer which is disposed atop the substrate layer b and acts as an adhesion promoter between the scratch-resistant coating based on polysiloxane and the substrate layer b, and
Layer b) a substrate layer b based on aromatic polycarbonate, having light transmittance in the range from 380 to 780 nm of at least 3.0% determined at a layer thickness of 4 mm according to DIN ISO 13468-2:2006 (D65, 10°) and
a T DS value of less than 40%, determined according to ISO 13837:2008 at a layer thickness of 4 mm,
where the substrate layer contains at least 0.001% by weight of an IR absorber other than carbon black, and
Layer d′) at least one metal layer d comprising at least one element selected from Ag, Al, Au, Cu or alloys thereof where the sum total of the thicknesses of all metal layers is 5 nm to 20 nm, or
Layer d″) a metal layer system consisting of
i) one or more metal layers, selected from the group of the Ag, Au and Cu layers and mixtures thereof, where the sum total of the thicknesses of the metal layers is 5 to 20 nm, and
ii) optically active antireflection layers of metal oxide applied to either side of the metal layer(s), the thickness of each of which is 5 to 80 nm.

12. The multilayer article as claimed in claim 11 , wherein the multilayer article comprises an adhesive layer between layer band layer d′/d″ and
Layer c) a layer c based on a thermoplastic polymer, having a maximum thickness of 600 μm.

13. The multilayer article as claimed in claim 11 , wherein the multilayer article does not comprise any further layers.

14. A glazing or a glazing element comprising a multilayer article as claimed in claim 1 .

15. The glazing as claimed in claim 14 , wherein the glazing is a roof module having a black edge alongside the multilayer article.

Assignees

• Covestro Deutschland Ag

Inventors

• Meyer Alexander
• Oser Rafael
• Hinzmann Dirk
• Kuhlmann Timo

Classifications

• B32B1/00 Primary

  Layered products having a non-planar shape · CPC title

• B32B2255/26

  Polymeric coating · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B15/085

  comprising polyolefins · CPC title

• B32B27/18

  characterised by the use of special additives · CPC title