Silicone modified lubricant

Patent metadata

Field	Value
Publication number	US-11434447-B2
Application number	US-201615155378-A
Country	US
Kind code	B2
Filing date	May 16, 2016
Priority date	Nov 22, 2013
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

A silicone modified lubricant includes a Group I, II, III, IV or V base oil in combination with a minor amount of a silicone oil. Further, the lubricant includes a dispersant such as a dispersant olefin copolymer which maintains the silicone oil dispersed in the base oil. The silicone oil reduces the surface tension of the lubricant thereby reducing power loss. Preferably the lubricant formation has a surface tension less than 28 mN/m, making it particularly suitable for dip lubrication systems.

First claim

What is claimed is:

1. A lubricant formulation comprising:
a base oil selected from a Group consisting of Group I, Group II, Group III, Group IV and Group V base oil and combinations thereof excluding silicone oil;
0.01 to 5% silicone oil which remains dispersed in said base oil, said silicone oil having a viscosity less than 10,000 cSt at 25° C., in an amount effective to decrease the surface tension of said lubricant formulation to less than 28 mN/m;
a dispersant olefin copolymer in an amount effective to maintain said silicone oil dispersed in said base oil, said olefin copolymer having a backbone polymer which is substantially linear and has less than 4 mole percent olefinic unsaturation, wherein said olefin copolymer is soluble in said base oil,
a defoamer in a concentration of from 0.02 to 0.5%, and
wherein said lubricant formulation produces foam test results using ASTM D892 of less than 50 mL foam in each of sequences I, II, and III, and a viscosity improver including a comb polymer.

2. The lubricant formulation claimed in claim 1 wherein said dispersant olefin copolymer is an ethylene propylene copolymer.

3. The lubricant formulation claimed in claim 2 , wherein said dispersant olefin copolymer has an ethylene propylene ratio of 55/45-45/55.

4. The lubricant formulation claimed in claim 1 , wherein said dispersant olefin copolymer is an ethylene propylene diene terpolymer.

5. The lubricant formulation claimed in claim 1 , having 0.02 to 0.5% silicone oil.

6. The lubricant formulation claimed in claim 1 , having 0.1 to 10% olefin copolymer.

7. The lubricant formulation claimed in claim 1 , wherein said base oil is a Group III base oil.

8. The lubricant formulation claimed in claim 1 , comprising 40-95% PAO.

9. The lubricant formulation claimed in claim 1 , comprising 0.01 to 15% nanographite particles.

10. The lubricant formulation claimed in claim 1 , wherein said base oil includes at least 40% of a Group III or Group IV base oil.

11. The lubricant formulation claimed in claim 5 , comprising 40 to 95% by weight of said base oil.

12. The lubricant formulation claimed in claim 5 , having a surface tension less than or equal to 25 mN/m.

13. The lubricant formulation of claim 1 wherein said polymer backbone includes at least 70% repeating Si—O groups.

14. The lubricant formulation of claim 1 wherein said silicone oil is selected from the group consisting of cyclopentasiloxane, dimethylpolysiloxane, and a mixture of dimethyl and methyl phenyl siloxanes.

15. The lubricant formulation of claim 1 wherein said defoamer is a polyalkylmethacrylate.

16. The lubricant formulation of claim 15 wherein said polyalkylmethacrylate is polymethylmethacrylate.

17. The lubricant formulation of claim 1 wherein said comb polymer contains an acrylic copolymer.

Assignees

• Valvoline Licensing & Intellectual Property LLC
• Imperial Innovations Ltd

Inventors

• Kolekar Anant S
• Olver Andrew V
• Sworski Adam E
• Lockwood Frances E
• Wu Gefei
• Cheng Xiurong

Classifications

• C10M2203/1006

  used as base material · CPC title

• C10M2203/1025

  used as base material · CPC title

• C10M155/02

  Monomer containing silicon · CPC title

• C10N2030/54

  Fuel economy · CPC title

• C10N2020/06

  Particles of special shape or size · CPC title