Method for making a PEG phase change composite

Patent metadata

Field	Value
Publication number	US-11434339-B2
Application number	US-202016794713-A
Country	US
Kind code	B2
Filing date	Feb 19, 2020
Priority date	Jul 27, 2018
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

A heat energy storage system may have a shape-stabilized composite prepared using an easy impregnation method involving a porous Ca2+-doped MgCO3 matrix and PEG as the functional phase. The heat storage capability, microstructures, and interactions with the PEG/CaMgCO3 composite can be characterized by DSC, SEM imaging, FT-IR spectroscopy, and TGA. Likely because of the synergistic phase change effect of CaMgCO3 and PEG, the PEG/CaMgCO3 composites can have high thermal enthalpies, and their enthalpy efficiencies are substantially higher than those of traditional shape stabilized PCMs. The functional material PEG can permeate porous CaMgCO3 matrices under capillary action. Liquid PEG can be stabilized within the porous matrix, and/or the CaMgCO3 matrix can improve the thermal stability of the PEG. The high heat energy storage properties and good thermal stability of such organic-inorganic composites offers utility in a range of applications, including thermal energy storage.

First claim

The invention claimed is:

1. A method of preparing a phase change composite of polyethylene glycol (PEG) encapsulated in a porous matrix, the method comprising:
dissolving magnesium nitrate, calcium nitrate, and ammonium carbonate in water to form a solution;
stirring the solution at constant pH in the range of 7.5 to 9.5 for 6 to 18 hours;
heating the solution at a temperature in the range of 150 to 250° C. for 12 to 48 hours to produce mesoporous calcium ion doped magnesium carbonate comprising 5-15 mol % calcium ions on MgCO 3 ;
mixing the mesoporous calcium ion doped magnesium carbonate with an alcoholic solution comprising a polyethylene glycol having a number-average molecular weight of from 4,000 to 8,000 and an alcohol, and stirring for a time in the range of 2 to 8 hours; and
evaporating the alcohol to produce the composite of the polyethylene glycol encapsulated in a mesoporous calcium ion doped magnesium carbonate.

2. The method of claim 1 , wherein the mesoporous calcium ion doped magnesium carbonate comprises at least 90 wt % calcium ion doped magnesium carbonate.

3. The method of claim 1 , wherein the composite has an apparent melting enthalpy in a range of from 400 to 600 J/g.

4. The method of claim 1 , wherein the mesoporous calcium ion doped magnesium carbonate has a BET specific surface area in a range of from 10 to 20 m 2 /g.

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Zahir Md Hasan
• Rahman Mohammad Mizanur

Classifications

• C08J2300/22

  Thermoplastic resins · CPC title

• C08K2003/267

  Magnesium carbonate · CPC title

• C08L71/02

  Polyalkylene oxides · CPC title

• C08K7/24

  inorganic · CPC title

• C08K3/26 Primary

  Carbonates; Bicarbonates · CPC title