Method for the production of polyether polyols

Patent metadata

Field	Value
Publication number	US-11434328-B2
Application number	US-201816477048-A
Country	US
Kind code	B2
Filing date	Jan 18, 2018
Priority date	Jan 25, 2017
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

The invention is related to a method for preparing polyether polyols, wherein the method comprises the steps of: a) providing a crude polyether polyols and a base catalyst; b) mixing the crude polyether polyols mixture with an acid thereby providing a neutralized polyether polyols mixture; c) removing water from the neutralized polyether polyols mixture, thereby providing a dehydrated neutralized polyether polyols mixture comprising polyether polyols and a suspension of the crystallized salts suspended in the polyether polyols; d) separating the polyether polyols from the crystallized salt by filtration resulting in a filtration cake comprising crystallized salts and remaining polyether polyols around the crystals; e) removing polyether polyols from the filter, leaving a filtration cake; f) redissolving the filtration cake obtaining a mixture of a salt solution and the remaining polyether polyols; and separating and removing the remaining polyether polyols from the salt solution.

First claim

The invention claimed is:

1. A method for preparing polyether polyols, wherein the method comprises the steps of:
a) providing a crude polyether polyols mixture comprising polyether polyols and a base catalyst;
b) mixing the crude polyether polyols mixture with an aqueous solution of an acid thereby neutralizing said base catalyst and providing a neutralized polyether polyols mixture;
c) removing at least part of the water from the neutralized polyether polyols mixture, thereby providing a dehydrated neutralized polyether polyols mixture comprising polyether polyols and a suspension of the crystallized salts suspended in the polyether polyols, which salts result from the neutralization of the base catalyst by the acid;
d) separating the polyether polyols from the crystallized salt by filtration resulting in a filtration cake comprising crystallized salts and remaining polyether polyols around the crystals;
e) removing at least part of the polyether polyols from the filter, leaving a filtration cake;
f) redissolving the filtration cake obtaining a mixture of a salt solution and the remaining polyether polyols;
g) separating the remaining polyether polyols from the salt solution; and
h) removing at least part of the remaining separated polyether polyols from the salt solution.

2. The method according to claim 1 , wherein the separation of the mixture of remaining polyether polyols from the salts solution in step g) is based on density difference between the remaining polyether polyols and the salt solution, forming at least two layers, the salt solution layer and the polyether polyols layer, wherein the salt solution layer comprises a salt concentration that is sufficient to provide phase separation.

3. The method according to claim 1 , wherein the separation of the mixture of remaining polyether polyols from the salts solution in step g) is facilitated by:
adding salt to or removing water from the mixture in case the density difference is not enough to facilitate the separation, wherein the salt is preferably a salt of the base catalyst and the acid; or
adding water to the mixture in case the salt concentration is too high.

4. The method according to claim 2 , wherein the salt concentration is measured using a conductivity meter.

5. The method according to claim 2 , wherein the salt concentration that is sufficient to provide phase separation is between 5 wt % and 60 wt % based on the weight of the salt solution.

6. The method according to claim 2 , wherein the polyether polyols layer comprises at least two layers, a gummy layer and a pure polyether polyols layer.

7. The method according to claim 6 , wherein the removing of at least part of the remaining separated polyether polyols from the salt solution in step h), comprises removing at least part of the pure polyether polyols layer and leaving the gummy layer and the salt solution.

8. The method according to claim 6 , wherein the gummy layer is removed from the salt solution.

9. The method according to claim 2 , wherein step (g) comprises the steps of:
removing all the remaining polyether polyols and a part of the salt solution from a first separation vessel; and
separating the part of the salt solution and the remaining polyether polyols based on density difference between the remaining polyether polyols and the salt solution in a second separation vessel, forming at least two layers, the salt solution layer and the polyether polyols layer.

10. The method according to claim 1 , wherein at least part of the separated salt solution obtained in step h) is used to redissolve the cake in step f).

11. The method according to claim 1 , wherein the separation of the polyether polyols from the cake in step d) is provided by the means of a filter.

12. The method according to claim 11 , wherein the filter is an inside-out filter candle where the cake remains on the inside of the filter candle and the polyether polyols are on the outside of the filter.

13. The method according to claim 11 , wherein the separation of the polyether polyols from the cake further comprises the step of adding an inert gas to the filter.

14. The method according to claim 13 , wherein the step of adding an inert gas to the filter is under pressure.

Assignees

• Huntsman Int Llc

Inventors

• Termorshuizen Paul Anton
• Cantero Hector

Classifications

• C08G65/30 Primary

  Post-polymerisation treatment, e.g. recovery, purification, drying · CPC title

• C08G65/10

  characterised by the catalysts used · CPC title