Methods of fabricating oxide/metal composites and components produced thereby

Patent metadata

Field	Value
Publication number	US-11434173-B2
Application number	US-202016783793-A
Country	US
Kind code	B2
Filing date	Feb 6, 2020
Priority date	Feb 7, 2019
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Methods for producing oxide/metal composite components for use in high temperature systems, and components produced thereby. The methods use a fluid reactant and a porous preform that contains a solid oxide reactant. The fluid reactant contains yttrium as a displacing metal and the solid oxide reactant of the preform contains niobium oxide, of which niobium cations are displaceable species. The preform is infiltrated with the fluid reactant to react its yttrium with the niobium oxide of the solid oxide reactant and produce an yttria/niobium composite component, during which yttrium at least partially replaces the niobium cations of the solid oxide reactant to produce yttria and niobium metal, which together define a reaction product. The pore volume of the preform is at least partially filled by the reaction product, whose volume is greater than the volume lost by the solid oxide reactant as a result of reacting yttrium and niobium oxide.

First claim

The invention claimed is:

1. A method for producing an oxide/metal composite component for use in a system in which the oxide/metal composite component is subjected to elevated temperatures exceeding 500° C. and up to at least 2000° C., the method comprising:
providing a fluid reactant and a porous preform that has a pore volume and contains a solid oxide reactant that defines a solid volume of the porous preform, the fluid reactant comprising at least yttrium as a displacing metal and the solid oxide reactant of the preform comprising at least niobium oxide in which niobium cations in the niobium oxide are displaceable species, the yttrium of the fluid reactant being capable of displacing the niobium cations in the solid oxide reactant to produce at least yttria as a solid oxide reaction product and niobium metal as a solid metal reaction product; and
infiltrating the porous preform with the fluid reactant by means of a pressureless reactive infiltration process to react the yttrium of the fluid reactant with the niobium oxide of the solid oxide reactant to produce the oxide/metal composite component, during which the yttrium of the fluid reactant at least partially replaces the niobium cations of the solid oxide reactant to produce the yttria and the niobium metal that together define a reaction product volume, the pore volume is at least partially filled by the reaction product volume, and the reaction product volume is greater than the solid volume lost by the solid oxide reactant as a result of the reaction of the yttrium and the niobium oxide, wherein the oxide/metal composite component comprises an yttria/niobium composite containing at least yttria and niobium metal.

2. The method of claim 1 , wherein the fluid reactant further comprises copper and the yttrium of the fluid reactant reacts with the niobium oxide at a temperature that is lower the melting point of yttrium.

3. The method of claim 2 , wherein the fluid reactant is a Cu-Y liquid.

4. The method of claim 1 , further comprising exposing the oxide/metal composite component to temperatures greater than 500° C. in the system, wherein the yttria and the niobium metal exhibit linear thermal expansion values within 10% of one another throughout a temperature range of 250° C. to at least 2000° C.

5. The method of claim 4 , wherein the system is in an application in which the oxide/metal composite component is subjected to velocities of Mach 5 and above.

6. The method of claim 5 , wherein the application is chosen from the group consisting of aircraft, spacecraft, missiles, and energy conversion devices.

7. The method of claim 1 , wherein the oxide/metal composite component is at an edge of an aircraft, spacecraft, missile, or energy conversion device and is subjected to velocities of Mach 5 and above.

8. The method of claim 1 , further comprising adjusting amounts of the yttria and the niobium metal in the oxide/metal composite component by adding additional niobium metal to the porous preform prior to the infiltrating step.

9. The method of claim 1 , further comprising forming an yttria coating on the oxide/metal composite component.

10. The method of claim 9 , wherein the yttria coating is generated by one or more of physical vapor deposition, chemical vapor deposition, and air plasma spraying.

11. The method of claim 9 , wherein the yttria coating is generated by one or more of: a sol-gel dip coating and firing process, a powder slurry dip coating and firing process, a slip casting process, a laser deposition process, a plasma spraying process, a flame spraying process, an electrophoretic deposition process, and a hot isostatic pressing process.

12. A method for producing an oxide/metal composite component for use in a system in which the oxide/metal composite component is subjected to elevated temperatures exceeding 500° C. and up to at least 2000° C., the method comprising:
providing a fluid reactant and a porous preform that has a pore volume and contains a solid oxide reactant that defines a solid volume of the porous preform, the fluid reactant comprising a Cu-Y liquid that contains yttrium as a displacing metal and the solid oxide reactant of the preform consisting of niobium oxide in which niobium cations in the niobium oxide are displaceable species, the yttrium of the fluid reactant being capable of displacing the niobium cations in the solid oxide reactant to produce yttria as a solid oxide reaction product and niobium metal as a solid metal reaction product;
infiltrating the porous preform with the fluid reactant by means of a pressureless reactive infiltration process to react the yttrium of the fluid reactant with the niobium oxide of the solid oxide reactant at a temperature that is lower the melting point of yttrium to produce the oxide/metal composite component, during which the yttrium of the fluid reactant replaces the niobium cations of the solid oxide reactant to produce the yttria and the niobium metal that together define a reaction product volume, the pore volume is filled by the reaction product volume, and the reaction product volume is greater than the solid volume lost by the solid oxide reactant as a result of the reaction of the yttrium and the niobium oxide, wherein the oxide/metal composite component comprises an yttria/niobium composite containing yttria and niobium metal; and
forming an yttria coating on the oxide/metal composite component.

13. The method of claim 12 , further comprising exposing the oxide/metal composite component to temperatures greater than 500° C. in the system, wherein the yttria and the niobium metal exhibit linear thermal expansion values within 10% of one another throughout a temperature range of 250° C. to at least 2000° C.

14. The method of claim 13 , wherein the system is in an application in which the oxide/metal composite component is subjected to velocities of Mach 5 and above.

15. The method of claim 14 , wherein the application is chosen from the group consisting of aircraft, spacecraft, missiles, and energy conversion devices.

16. The method of claim 12 , wherein the oxide/metal composite component is at an edge of an aircraft, spacecraft, missile, or energy conversion device and is subjected to velocities of Mach 5 and above.

17. The method of claim 12 , further comprising adjusting amounts of the yttria and the niobium metal in the oxide/metal composite component by adding additional niobium metal to the porous preform prior to the infiltrating step.

18. A method for producing an oxide/metal composite component for use in a system in which the oxide/metal composite component is subjected to elevated temperatures exceeding 500° C. and up to at least 2000° C., the method comprising:
providing a fluid reactant and a porous preform that has a pore volume and contains a solid oxide reactant that defines a solid volume of the porous preform, the fluid reactant comprising at least yttrium as a displacing metal and the solid oxide reactant of the preform comprising at least one oxide in which cations of the oxide are displaceable cation species, the displacing metal of the fluid reactant being capable of displacing the cations in the solid oxide reactant to produce at least a solid oxide reaction product and a solid metal reaction product; and
infiltrating the porous preform with the fluid reactant by means of a pressureless reactive infiltration process to react the displacing metal of the fluid reactant with the displaceable cation species of the solid oxide reactant to produce the oxide/metal composite component, during which the displacing metal

Assignees

• Purdue Research Foundation

Inventors

• Sandhage Kenneth H

Classifications

• C22C1/1057

  Reactive infiltration · CPC title

• C22C1/1068

  Making hard metals based on borides, carbides, nitrides, oxides or silicides · CPC title

• C22C29/005 Primary

  comprising a particular metallic binder · CPC title

• B64G99/00

  Subject matter not provided for in other groups of this subclass · CPC title

• C04B2235/616

  Liquid infiltration of green bodies or pre-forms · CPC title