Separation of ozone oxidation in liquid media into three unit operations for process optimization

Patent metadata

Field	Value
Publication number	US-11434153-B2
Application number	US-201815938786-A
Country	US
Kind code	B2
Filing date	Mar 28, 2018
Priority date	Mar 28, 2018
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Disclosed are decoupled systems and methods for producing an oxidized liquid. The method comprises the steps of generating an ozone strong water in a mass transfer unit, mixing the ozone strong water with a process liquid in a mixing unit to form a homogeneous and gas-free mixture of the ozone strong water and the process liquid, forwarding the homogeneous and gas-free mixture to a reaction unit, and producing the oxidized liquid in the reaction unit. The method utilizes the acidic feed liquid to generate ozone dissolved in water having a higher concentration at a saturated or nearly saturated concentration compared to prior art processes at atmospheric pressure and neutral or alkaline pH.

First claim

What is claimed is:

1. A method for producing an oxidized liquid, the method comprising the steps of:
generating an ozone strong water in a pressurized reactor comprising a step of bubbling gaseous ozone through a volume of water in the pressurized reactor, wherein the ozone strong water is a pressurized gas-free high concentrated or saturated or close to saturated ozonated water, which under atmospheric conditions is supersaturated, wherein a steady state concentration of ozone in the ozone strong water is greater than approximately 150 mg/L;
making a quick dilution of the ozone strong water in a process liquid to avoid degassing, wherein a pressure of the ozone strong water is higher than a pressure of the process liquid;
mixing the diluted ozone strong water with the process liquid in a mixer to form a homogeneous and gas-free mixture of the ozone strong water and the process liquid;
forwarding the homogeneous and gas-free mixture to a reactor; and
producing the oxidized liquid in the reactor.

2. The method of claim 1 , further comprising the steps of:
injecting CO 2 gas or a mineral acid into a pressurized feed water configured and adapted to form an acidic feed water;
feeding the pressurized acidic feed water into the pressurized reactor configured and adapted to form a body of pressurized acidic water for generating the ozone strong water therein.

3. The method of claim 2 , wherein the feed liquid includes fresh water, tap water, process water, effluent water, municipal and industrial wastewater, wastewater already treated by secondary treatment process.

4. The method of claim 2 , wherein the feed liquid and the process liquid are from the same source.

5. The method of claim 2 , further comprising the step of:
recycling ozone gas from a pressurized off-gas stream from the pressurized reactor for use as ozone feed to the pressurized reactor; and/or
recycling oxygen gas from the pressurized off-gas stream from the pressurized reactor for use as oxygen feed to a secondary wastewater treatment process.

6. The method of claim 1 , wherein a pH value of the ozone strong water is in a range of 3<pH>7.

7. The method of claim 1 , wherein a pH value of the ozone strong water is about 5.

8. The method of claim 1 , wherein a pH value of the ozone strong water is about 4.

9. The method of claim 1 , wherein a pressure of the ozone strong water ranges from 2 barg to 7 barg.

10. The method of claim 1 , wherein the process liquid includes fresh water, tap water, process water, effluent water, municipal and industrial wastewater, wastewater already treated by secondary treatment process.

11. The method of claim 1 , wherein the steady state concentration of ozone in the ozone strong water ranges from approximately 150 mg/L to approximately 300 mg/L.

12. A liquid oxidation system for producing an oxidized liquid, the system comprising:
a pressurized reactor, configured and adapted to generate an ozone strong water by bubbling gaseous ozone through a volume of water in the pressurized reactor, wherein the ozone strong water is a pressurized gas-free high concentrated or saturated or close to saturated ozonated water, which under atmospheric conditions is supersaturated, wherein a steady state concentration of ozone in the ozone strong water is greater than approximately 150 mg/L;
a liquid pump, fluidly connected to the pressurized reactor and integrating with a pipe through which a process liquid flows, configured and adapted to create a flow of the ozone strong water into a mixer, wherein a pressure of the ozone strong water is higher than a pressure of the process liquid;
the mixer, fluidly connected to the pipe and the liquid pump, configured and adapted to mix the ozone strong water with the process liquid to form a homogeneous and gas-free mixture of the ozone strong water and the process liquid; and
a reactor, fluidly connected to the mixer, configured and adapted to receive the homogeneous and gas-free mixture and produce an oxidized liquid therein.

13. The system of claim 12 , wherein the liquid pump is connected to an acidic source and configured and adapted to form a pressurized acidic feed liquid and further configured and adapted to feed to the pressurized reactor to generate the ozone strong water under acidic conditions.

14. The system of claim 13 , wherein CO 2 gas or a mineral acid is injected into a pressurized feed liquid that flows through the liquid pump connected to the acidic source configured and adapted to form the pressurized acidic feed liquid.

15. The system of claim 12 , wherein a pH of the ozone strong water is below 7.

16. The system of claim 12 , wherein a pH of the ozone strong water is about 5.

17. The system of claim 12 , wherein a pH of the ozone strong water is about 4.

18. The system of claim 12 , wherein the pressure inside the first reactor ranges from 2 to 7 barg.

19. The system of claim 12 , wherein the quick dilution of the ozone strong water in the process liquid takes within approximately 1 second or less than 1 seconds.

20. A method for liquid oxidation process using liquid oxidants, the method comprising the steps of:
generating the liquid oxidant in a pressurized reactor comprising a step of bubbling gaseous oxidant through a volume of water in the pressurized reactor;
making a quick dilution of the liquid oxidant in a process liquid to avoid degassing, wherein the liquid oxidant is a pressurized gas-free high concentrated or saturated or close to saturated gaseous oxidant dissolved water, which under atmospheric conditions is supersaturated, wherein a pressure of the liquid oxidant is higher than a pressure of the process liquid, wherein a steady state concentration of gaseous oxidant in the liquid oxidant is greater than approximately 150 mg/L;
mixing the diluted liquid oxidant with the process liquid in a mixer to form a homogeneous and gas-free mixture of the liquid oxidant and the process liquid;
forwarding the homogeneous and gas-free mixture to a reactor; and
producing an oxidized liquid in the reactor.

21. The method of claim 20 , wherein the gaseous oxidant is ozone or oxygen.

Assignees

• Air Liquide
• Air Liquide American
• Lair Liquide Sa Pour Letude Et Lexploitation Des Procedes George Claude

Inventors

• Mante Jan
• Schwerdt Joerg
• Rasanayagam Vasuhi
• Mahmudov Rovshan
• Isazadeh Siavash

Classifications

• C02F1/78 Primary

  with ozone {(C02F1/4672 takes precedence)} · CPC title

• C02F1/66

  by neutralisation; pH adjustment (for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58) · CPC title

• C02F2101/103

  Arsenic compounds · CPC title

• C02F2209/06

  pH · CPC title

• C02F2101/203

  Iron or iron compound · CPC title