Method for producing metal oxides by means of spray pyrolysis

Patent metadata

Field	Value
Publication number	US-11434146-B2
Application number	US-201716476274-A
Country	US
Kind code	B2
Filing date	Dec 20, 2017
Priority date	Jan 9, 2017
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

A process for producing a metal oxide powder by flame spray pyrolysis wherea) a stream of a solution containing at least one oxidizable or hydrolysable metal compound is atomized to afford an aerosol by means of an atomizer gas,b) this aerosol is brought to reaction in the reaction space of the reactor with a flame obtained by ignition of a mixture of fuel gas and air,c) the reaction stream is cooled andd) the solid product is subsequently removed from the reaction stream, whereine) the reaction space comprises one or more successive double-walled internals, wherein the wall of the double-walled internal facing the flame-conducting region of the reaction space comprises at least one slot through which a gas or vapour is introduced into the reaction space in which the flame is burning andf) the slot is arranged such that this gas or vapour brings about a rotation of the flame.

First claim

The invention claimed is:

1. A process for producing a metal oxide powder by flame spray pyrolysis, comprising the steps of:
a) using an atomizer gas to atomize a stream of a solution and thereby produce an aerosol, wherein the solution comprises at least one oxidizable or hydrolysable metal compound;
b) reacting the aerosol of step a) in a reaction space of a reactor with a flame obtained by ignition of a mixture of fuel gas and air to produce a reaction stream;
c) cooling the reaction stream;
d) removing a solid product from the cooled reaction stream of step c);
wherein:
i) the reaction space comprises one or more successive double-walled internals, wherein the wall of the double-walled internal facing a flame-conducting region of the reaction space comprises at least one slot through which a gas or vapour is introduced into the reaction space in which the flame is burning; and
ii) the slot is arranged such that this gas or vapour brings about a rotation of the flame.

2. The process of claim 1 , wherein the internal comprises at least two slots.

3. The process of claim 1 , wherein slot length/slot width is 10:1-200:1.

4. The process of claim 1 , wherein reaction space diameter/total slot area is 15:1-200:1.

5. The process of claim 1 , wherein, when viewed in longitudinal section of an internal, an angle α of a slot to vertical is 15°≤α≤60°.

6. The process of claim 1 , wherein angle β, which describes an angle between a section axis of the slot to a circle perpendicular of centre, is 30°≤β≤60°.

7. The process of claim 1 , wherein the gas is a fuel gas.

8. The process of claim 1 , wherein the gas is an oxygen-containing gas.

9. The process of claim 1 , wherein a metal component of the metal compound is selected from the group consisting of Ag, Al, Au, B, Ba, Ca, Cd, Ce, Co, Cr, Cu, Dy, Fe, Ga, Ge, Hf, In, La, Li, Mg, Mn, Mo, Nb, Ni, Pd, Rh, Ru, Sc, Si, Sm, Sn, Sr, Ta, Ti, V, Y, Yb and Zn.

10. The process of claim 1 , wherein the solution contains zinc, titanium or calcium as the metal of the metal compound.

11. The process of claim 1 , wherein the solution contains Li, La and Zr as the metal of the metal compound.

12. The process of claim 1 , wherein the solution contains Li and Ni as the metal of the metal compound.

13. The process of claim 1 , wherein a gas supplied via a slot in an internal lengthens average residence time of the mixture of fuel gas and air in the reaction space by at least a factor of 1.2 compared to a reaction space comprising none of these internals.

14. The process of claim 1 , wherein gas entry velocity from a slot of an internal into the reaction space is at least 10 Nm/s.

15. The process of claim 1 , wherein the internal comprises four slots.

16. The process of claim 1 , wherein angle β is 40°≤β≤50°.

17. The process of claim 2 , wherein slot length/slot width is 10:1-200:1.

18. The process of claim 2 , wherein reaction space diameter/total slot area is 15:1-200:1.

19. The process of claim 2 , wherein the solution contains zinc, titanium or calcium as the metal of the metal compound.

20. The process of claim 2 , wherein the solution contains Li, La and Zr as the metal of the metal compound.

Assignees

• Evonik Operations Gmbh

Inventors

• Kress Peter
• Katusic Stipan
• Wiegand Armin
• Alff Harald
• Hagemann Michael

Classifications

• C01G9/03

  Processes of production using dry methods, e.g. vapour phase processes · CPC title

• B01J4/002

  Nozzle-type elements (nozzle-type reactors B01J19/26) · CPC title

• C01G25/006 Primary

  Compounds containing zirconium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• C01G53/42

  containing alkali metals, e.g. LiNiO2 · CPC title