Synthesis of ammonia with internal cooling circuit

Patent metadata

Field	Value
Publication number	US-11434141-B2
Application number	US-201816218618-A
Country	US
Kind code	B2
Filing date	Dec 13, 2018
Priority date	Dec 14, 2017
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

The invention relates to a method for the synthesis of ammonia, in which a fresh gas consisting largely of hydrogen and nitrogen is compressed via a compressor and subsequently fed to an ammonia converter for conversion into a converter product containing ammonia and comprising hydrogen and nitrogen. Upstream of the compressor, ammonia is evaporated into the fresh gas in order to cool the fresh gas and to produce a cold substance mixture comprising ammonia and the fresh gas. The substance mixture is heated in a heat exchanger against at least one process stream to be cooled, and subsequently compressed via the compressor, to obtain a compressed substance mixture comprising ammonia and the fresh gas. Upstream of the circuit cooler, a gas mixture consisting largely of hydrogen and nitrogen is fed to a substance stream comprising the fresh gas. The constituents of the gas mixture are separated from the converter product and/or from the compressed substance mixture comprising ammonia and the fresh gas.

First claim

The invention claimed is:

1. A method for the synthesis of ammonia, comprising:
compressing a fresh gas containing hydrogen and nitrogen via a compressor and subsequently feeding the fresh gas to an ammonia converter for conversion into a converter product containing ammonia, hydrogen, and nitrogen,
upstream of the fresh-gas compressor, evaporating ammonia into the fresh gas in order to cool the fresh gas and to produce a substance mixture comprising ammonia and the fresh gas,
heating said substance mixture in a circuit cooler against at least one process stream to be cooled, and subsequently compressing the substance mixture via the compressor to obtain a compressed substance mixture comprising ammonia and the fresh gas, and
upstream of the circuit cooler, feeding a gas mixture containing hydrogen and nitrogen to the fresh gas or to the cold substance stream formed from admixing the fresh gas and the liquid ammonia, wherein the constituents of said gas mixture are separated from the converter product and/or separated from the compressed substance mixture comprising ammonia and the fresh gas.

2. The method according to claim 1 , wherein the gas mixture is fed to a substance stream formed from fresh gas through admixing of liquid ammonia.

3. The method according to claim 1 , wherein the quantity of the ammonia admixed with the fresh gas is controlled such that the substance mixture comprising the fresh gas exits the circuit cooler with an ammonia-saturated gas phase.

4. The method according to claim 1 , wherein said at least one process stream is the converter product and the substance mixture comprising ammonia and the fresh gas is heated in the circuit cooler against the converter product, wherein ammonia contained in the converter product condenses.

5. The method according to claim 1 , wherein, after being combined with the converter product cooled in the circuit cooler, the substance mixture compressed in the fresh-gas compressor and comprising the fresh gas undergoes ammonia separation in order to obtain the gas mixture containing hydrogen and nitrogen for admixing to the substance stream comprising the fresh gas upstream of the circuit cooler.

6. The method according to claim 5 , wherein the ammonia separation is realized in a separator from which a gas phase containing hydrogen and nitrogen, and a liquid ammonia phase are withdrawn.

7. The method according to claim 6 , wherein a part of the gas phase obtained in the separator is, in one step, expanded in a work-performing manner via an expander to the pressure of the substance stream comprising the fresh gas.

8. The method according to claim 6 , wherein a part of the gas phase obtained in the separator is, in one step, expanded in a work-performing manner via a throttle member to the pressure of the substance stream comprising the fresh gas.

9. The method according to claim 6 , wherein a part of the gas phase obtained in the separator is, in a first step via an expander and in a second step via a throttle member, expanded to the pressure of the substance stream comprising the fresh gas.

10. The method according to claim 7 , wherein the part of the gas phase to be expanded is heated before expansion.

11. The method according to claim 1 , wherein, prior to be being compressed in the compressor and after being heating against said at least one process stream to be cooled, the substance mixture is sent to a first separator where the substance mixture is separated into a first gaseous phase containing hydrogen and nitrogen and a first liquid ammonia phase.

12. The method according to claim 11 , wherein said first gaseous phase from the first separator is compressed in a first stage of the compressor and then sent to a second separator wherein the first gaseous phase is separated into a second gas phase and a second liquid ammonia phase.

13. The method according to claim 12 , wherein said second gaseous phase from the second separator is compressed in a second stage of the compressor to form the compressed substance mixture, and the second liquid ammonia phase from the second separator is sent to the first separator.

14. The method according to claim 13 , wherein said at least one process stream is the converter product which is cooled in the circuit cooler, and wherein the compressed substance mixture is combined with the converter product cooled in the circuit cooler and then subjected to ammonia separation in order to obtain the gas mixture containing hydrogen and nitrogen that is admixed to the substance stream upstream of the circuit cooler.

15. The method according to claim 14 , wherein the ammonia separation is realized in an ammonia separator from which a gas phase containing hydrogen and nitrogen, and a liquid ammonia phase are withdrawn.

16. The method according to claim 15 , wherein the liquid ammonia phase withdrawn the ammonia separator is combined with a portion of the fresh gas to a coolant stream which used to preheat the fresh gas in a preheater before said ammonia is evaporated into the fresh gas.

17. The method according to claim 16 , wherein said coolant stream is removed from the preheater and introduced into the first separator.

18. The method according to claim 15 , wherein gas phase containing hydrogen and nitrogen withdrawn from the ammonia separator is compressed and then sent to the ammonia converter.

19. The method according to claim 18 , wherein gas phase containing hydrogen and nitrogen withdrawn from the ammonia separator is compressed in a third stage of the compressor.

Assignees

• Linde Ag

Inventors

• Heinzel Albrecht
• Haselsteiner Thomas
• Ettner Florian

Classifications

• C01C1/047 Primary

  by condensation · CPC title

• F25J3/0276

  separation of H2/N2 mixtures, i.e. of ammonia synthesis gas (in general C01B3/00) · CPC title

• C01C1/0447

  Apparatus other than synthesis reactors · CPC title

• F25J3/0685

  separation of noble gases (from air F25J3/04642; in general C01B23/00) · CPC title