Reforming system and reforming method using off gas as cooling medium

Patent metadata

Field	Value
Publication number	US-11434133-B2
Application number	US-202016904538-A
Country	US
Kind code	B2
Filing date	Jun 17, 2020
Priority date	Dec 3, 2019
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Disclosed is a reforming system using an off gas as a cooling medium, which includes: a compressor configured to compress a feed gas; a cooling system a heat exchanger connected to the compressor and configured to cool the feed gas, the temperature of which has been raised in a compression process, by a cooling medium including cooling water; a reformer configured to generate a synthesis gas including hydrogen by reacting the feed gas, which passed through the heat exchanger, with water; a pressure swing adsorption (PSA) unit configured to separate hydrogen from the synthesis gas generated by the reformer and discharge the off gas; and an off gas line configured to feed the off gas discharged from the PSA unit to the heat exchanger such that the heat exchanger utilizes the off gas as the cooling medium.

First claim

What is claimed is:

1. A reforming system using an off gas as a cooling medium, the reforming system comprising:
a compressor configured to compress a feed gas;
a cooling system comprising a heat exchanger connected to the compressor and configured to cool the feed gas, the temperature of which has been raised in a compression process by a cooling medium comprising cooling water;
a reformer configured to generate a synthesis gas comprising hydrogen by reacting the feed gas, which passed through the heat exchanger, with water;
a pressure swing adsorption (PSA) unit configured to separate hydrogen from the synthesis gas generated by the reformer and discharge the off gas; and
an off gas line configured to feed the off gas discharged from the pressure swing adsorption (PSA) unit to the heat exchanger such that the heat exchanger utilizes the off gas as the cooling medium.

2. The reforming system of claim 1 , wherein the cooling system further comprises:
a cooling tower configured to cool the cooling water, which passed through the heat exchanger;
a cooling water circulating line connected to a cooling tower and the heat exchanger and through which the cooling water circulates; and
a first valve provided on the cooling water circulating line and discharged from the cooling tower to control the flow rate of the cooling water introduced into the heat exchanger.

3. The reforming system of claim 2 , wherein a temperature sensor configured to measure temperature information of the feed gas is provided between the heat exchanger and the reformer, and the first valve feeds back the temperature information of the feed gas measured by the temperature sensor to control the flow rate of the cooling water.

4. The reforming system of claim 1 , wherein the off gas line comprises:
an off gas introducing line that is a passage, through which the off gas discharged from the PSA unit is introduced into the heat exchanger; and
an off gas discharge line that is a passage, through which the off gas, the temperature of which has been raised through heat exchange with the feed gas, is charged, and
wherein a second valve configured to control the flow rate of the off gas is provided in the off gas introducing line.

5. The reforming system of claim 4 , wherein if the flow rate of the off gas becomes a reference value for a preset rated flow rate for the off gas, the second valve is opened such that, after the heat exchanger uses the cooling water as the cooling medium at an initial stage of the reforming system, the flow rate of the cooling water gradually decreases and the flow rate of the off gas gradually increases and the cooling medium is finally replaced by the off gas.

6. The reforming system of claim 1 , wherein the off gas line is connected to the heat exchanger in a condition in which the purity of hydrogen produced by the reformer is 99.99% or more.

7. The reforming system of claim 1 , further comprising:
a burner configured to supply heat to the reformer by burning the fuel gas and the off gas discharged from the off gas line.

8. The reforming system of claim 1 , further comprising:
a reactor connected to the reformer and configured to produce hydrogen by reacting CO of the synthesis gas generated by the reformer.

9. A reforming method using the reforming system of claim 1 , the reforming method comprising:
a first operation mode step of operating the reformer by using the cooling medium of the heat exchanger as the cooling water;
a bypass condition detecting step of detecting whether a condition for the flow rates, the temperatures, and the pressures of the synthesis gas produced by the reformer and the off gas corresponds to a bypass condition;
a second operation mode step of burning the off gas discharged from the heat exchanger while using the off gas produced by the reformer as the cooling medium together with the cooling water;
a hydrogen purity detecting step of detecting whether the purity of the produced hydrogen is a target purity or more; and
a third operation mode step of operating the reforming system while using the off gas as the cooling medium.

10. The reforming method of claim 9 , wherein in the bypass condition in the bypass condition detecting step, the flow rates of the synthesis gas and the off gas are 40% or less of the rated flow rate.

11. The reforming method of claim 9 , wherein in the hydrogen purity detecting step, the detected purity of hydrogen is 99.99% or more.

12. The reforming method of claim 9 , wherein the first operation mode step comprises:
a reformer starting step of starting the reformer;
a first valve opening step of opening the first valve provided in the cooling system and configured to control the flow rate of the cooling water;
a cooling water system operating step of starting circulation of the cooling water through the heat exchanger;
a compressor operating step of starting the compressor;
a feed gas introducing step of introducing the feed gas into the compressor; and
a burner and reformer operating step of starting the burner and the reformer.

13. The reforming method of claim 9 , wherein the second operation mode step comprises:
a PSA unit operating step of starting the PSA unit;
a second valve opening step of opening the first valve provided in the off gas line and configured to control the flow rate of the off gas;
a first valve temperature control operation starting step of starting a temperature control operation by feeding back temperature information measured by the temperature sensor provided between the heat exchanger and the reformer and configured to measure temperature information of the feed gas such that the first valve provided in the cooling system and configured to control the flow rate of the cooling water maintains a predetermined temperature; and
a reformer load control operation step of increasing the flow rate of the off gas of the heat exchanger.

14. The reforming method of claim 9 , wherein the third operation mode step comprises:
a reformer load rated operation step of operating the cooling medium of the heat exchanger as the off gas; and
a first valve temperature control operation maintaining step of controlling temperature in preparation for stop of supply of the off gas by the first valve formed in a line, through which the cooling water is introduced into the heat exchanger, and configured to control the flow rate of the cooling water.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp

Inventors

• Song Han Eol
• Ko Dong Seok

Classifications

• C01B2203/0425

  In-situ adsorption process during hydrogen production · CPC title

• Y02C20/40

  of CO2 · CPC title

• C01B2203/043

  Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration · CPC title

• C01B3/14

  Handling of heat and steam · CPC title

• C01B2203/0827

  at least part of the fuel being a recycle stream · CPC title