Transition-metal-supporting intermetallic compound, supported metallic catalyst, and ammonia producing method
US-10792645-B2 · Oct 6, 2020 · US
US11433378B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11433378-B2 |
| Application number | US-201816630269-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 12, 2018 |
| Priority date | Jul 12, 2017 |
| Publication date | Sep 6, 2022 |
| Grant date | Sep 6, 2022 |
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Provided are an intermetallic compound having high stability and high activity, and a catalyst using the same. A hydrogen storage/release material containing an intermetallic compound represented by formula (1): RTX . . . (1) wherein R represents a lanthanoid element, T represents a transition metal in period 4 or period 5 in the periodic table, and X represents Si, Al or Ge.
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The invention claimed is: 1. A transition metal-supported intermetallic compound comprising a transition metal M supported on an intermetallic compound represented by formula (1): RTX (1) wherein R represents a lanthanoid element, T represents a transition metal in period 4 or period 5 in the periodic table, and X represents Si, Al or Ge. 2. An activator for hydrogenation reaction, comprising the transition metal-supported intermetallic compound according to claim 1 . 3. A method for using the transition metal-supported intermetallic compound according to claim 1 , comprising contacting the intermetallic compound with hydrogen to activate a bond in a hydrogen molecule. 4. A catalyst comprising the transition metal-supported intermetallic compound according to claim 1 . 5. The catalyst according to claim 4 , wherein the catalyst is a catalyst for ammonia synthesis. 6. A transition metal-supported complex comprising a transition metal M supported on an intermetallic compound-hydrogen complex represented by formula (2), wherein the intermetallic compound is capable of storing and releasing hydrogen reversibly and the complex is capable of releasing hydrogen at 400° C. or less: RTX· a H (2) wherein R represents a lanthanoid element, T represents a transition metal in period 4 or period 5 in the periodic table, X represents Si, Al or Ge and a represents a number of 0.5 or more and 1.5 or less. 7. A catalyst comprising the transition metal-supported complex according to claim 6 . 8. The catalyst according to claim 7 , wherein the catalyst is a catalyst for ammonia synthesis. 9. A method for producing ammonia, comprising contacting nitrogen and hydrogen with a catalyst, wherein the catalyst comprises an intermetallic compound represented by formula (1): RTX (1) wherein R represents a lanthanoid element, T represents a transition metal in period 4 or period 5 in the periodic table, and X represents Si, Al or Ge.
with rare earths or actinides · CPC title
characterised by the catalyst · CPC title
Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title
by reactions not involving the formation of carboxamide groups · CPC title
by reduction with preservation of halogen-atoms in compounds containing nitro groups and halogen atoms bound to the same carbon skeleton · CPC title
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