Hydrogen isotope separation methods and systems

Patent metadata

Field	Value
Publication number	US-11433353-B2
Application number	US-201916433500-A
Country	US
Kind code	B2
Filing date	Jun 6, 2019
Priority date	Jun 6, 2019
Publication date	Sep 6, 2022
Grant date	Sep 6, 2022

Abstract

Methods and systems for the separation of hydrogen isotopes from one another are described. Methods include utilization of a hydrogen isotope selective separation membrane that includes a hydrogen isotope selective layer (e.g., graphene) and a hydrogen ion conductive supporting layer. An electronic driving force encourages passage of isotopes selectively across the membrane at an elevated separation temperature to enrich the product in a selected hydrogen isotope.

First claim

What is claimed is:

1. A method for separating hydrogen isotopes from one another comprising:
contacting a first side of a separation membrane with a sample, the sample comprising water in an amount of about 0.03 kg/m 3 or less, the sample including a first hydrogen isotope and a second hydrogen isotope, the separation membrane comprising a first layer and a second layer, the first layer comprising a crystalline material of from one to about 5 atomic or molecular layers and a metal selected from Groups 8 to 10 of the periodic table, wherein the metal reduces a thermal conduction barrier of the separation membrane, wherein the metal is present in a discontinuous fashion on a surface of the first layer, the second layer comprising a hydrogen ion conductive ceramic;
heating the separation membrane to a separation temperature of about 200° C. or greater; and
applying a voltage across the heated separation membrane from the first side of the separation membrane to the second side of the separation membrane, the voltage providing a driving force to selectively conduct the first hydrogen isotope across the separation membrane from the first side to the second side, thereby forming a product on the second side of the separation membrane that is enriched in the first hydrogen isotope, a remaining sample on the first side of the separation membrane being enriched in the second hydrogen isotope.

2. The method of claim 1 , the sample further comprising a third hydrogen isotope, wherein the remaining sample on the first side of the separation membrane is enriched in the second hydrogen isotope and the third hydrogen isotope.

3. The method of claim 1 , wherein the first hydrogen isotope comprises protium and the second hydrogen isotope comprises deuterium.

4. The method of claim 1 , wherein the first hydrogen isotope comprises protium and the second hydrogen isotope comprises tritium.

5. The method of claim 1 , wherein the voltage is about 20 Volts or less.

6. The method of claim 1 , wherein the separation temperature is from about 200° C. to about 800° C.

7. The method of claim 1 , further comprising contacting a first side of a second separation membrane with the product and applying a voltage across the second separation membrane.

8. The method of claim 7 , further comprising repeating the process with one or more additional separation membranes.

9. The method of claim 1 , the crystalline material comprising graphene, hexagonal boron nitride, or a transition metal chalcogenide.

10. The method of claim 1 , the hydrogen ion conductive ceramic comprising a perovskite type ceramic.

11. The method of claim 1 , wherein the sample comprises water in an amount of about 0.02 kg/m 3 or less.

12. The method of claim 1 , wherein the sample is a dry sample.

13. The method of claim 1 , wherein at least one layer of the crystalline material includes atoms in a hexagonal pattern.

14. The method of claim 10 , wherein the perovskite type ceramic comprises BaZrO 3 , BaCeO 3 , SrCeO 3 , CaZrO 3 , SrZRO 3 , or BaCe 0.7 Zr 0.1 Y 0.1 Yb 0.1 O 3-δ .

15. The method of claim 3 , wherein the method separates the protium from the deuterium with a single step separation factor of about 3.3 or greater.

16. The method of claim 4 , wherein the method separates the protium form the tritium with a single step separation factor of from about 10 to about 30.

17. The method of claim 1 , wherein the voltage is about 5 Volts or less.

18. The method of claim 1 , the crystalline material comprising graphene, wherein the graphene further functions as an electrode in application of the voltage across the heated separation membrane.

Assignees

• Savannah River Nuclear Solutions Llc
• Univ Clemson
• Georgia Tech Res Inst
• Univ Clemson Res Foundation

Inventors

• Hitchcock Dale A
• Serkiz Steven M
• Krentz Timothy M
• Velten Josef A
• Brinkman Kyle S
• Vogel Eric M
• Young Katherine T

Classifications

• C25B15/021

  of heating or cooling · CPC title

• C25B13/07

  based on ceramics · CPC title

• C25B11/067

  Inorganic compound e.g. ITO, silica or titania · CPC title

• C25B9/23

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• B01D71/025

  Aluminium oxide · CPC title