Fuel cell interconnect assembly

Patent metadata

Field	Value
Publication number	US-11430998-B2
Application number	US-202016735464-A
Country	US
Kind code	B2
Filing date	Jan 6, 2020
Priority date	Jan 6, 2020
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

A fuel cell stack is described. The fuel cell stack comprises an interconnect assembly comprising a cathode-side interface coupled to an interconnect via a first joint, and an anode-side interface coupled to the interconnect via a second joint, the interconnect assembly having a first coefficient of thermal expansion (CTE) at an interface side of the interconnect assembly. The fuel cell stack further comprises a fuel cell element coupled to the interconnect assembly at the interface side via a hermetic seal, the fuel cell element having a second CTE at the interface side, the first CTE and the second CTE satisfying a predetermined CTE matching condition.

First claim

The invention claimed is:

1. A fuel cell stack, comprising:
an interconnect assembly comprising:
a cathode-side interface coupled to an interconnect via a first joint; and
an anode-side interface coupled to the interconnect via a second joint,

the interconnect assembly comprising a metal interface side, the metal interface side having a first coefficient of thermal expansion (CTE); and
a fuel cell element comprising a ceramic interface side, the ceramic interface side being coupled to the metal interface side of the interconnect assembly via a hermetic seal, the ceramic interface side having a second CTE, the first CTE and the second CTE satisfying a CTE matching condition comprising the first CTE of the metal interface side and the second CTE of the ceramic interface side being within 10% of each other.

2. The fuel cell stack of claim 1 , where the first joint and the second joint form respective hermetic seals.

3. The fuel cell stack of claim 1 , where the interconnect assembly is unitary.

4. The fuel cell stack of claim 1 , where the fuel cell element comprises one or more ceramic materials.

5. The fuel cell stack of claim 1 , wherein the fuel cell element comprises an electrolyte, a cathode, and an anode, the cathode and the anode arranged on opposing sides of the electrolyte.

6. The fuel cell stack of claim 5 , wherein the fuel cell element is a first fuel cell element, further comprising a plurality of cathode-side interface sections coupled to the cathode, and a plurality of anode-side interface sections coupled to an anode of a second fuel cell element.

7. The fuel cell stack of claim 1 , where the first joint, the second joint, and the hermetic seal extend along a perimeter of the fuel cell element.

8. The fuel cell stack of claim 1 , where the interconnect assembly is a first interconnect assembly and the metal interface side is a first metal interface side, and where the fuel cell stack further comprises a second interconnect assembly coupled to the fuel cell element at a second metal interface side opposite the first metal interface side.

9. The fuel cell stack of claim 1 , where a material composition of the cathode-side interface and a material composition of the anode-side interface each differ from a material composition of the interconnect.

10. The fuel cell stack of claim 1 , where the cathode-side interface and the anode-side interface comprise a metallurgy material.

11. The fuel cell stack of claim 1 , wherein the interconnect assembly comprises different interface materials at either side of the interconnect assembly.

12. The fuel cell stack of claim 1 , where a material composition of the cathode-side interface differs from a material composition of the anode-side interface.

13. A method of manufacturing a fuel cell stack, the method comprising:
forming an interconnect assembly by joining a cathode-side interface to an interconnect at a first side of the interconnect, and joining an anode-side interface to the interconnect at a second side of the interconnect, the interconnect assembly comprising a metal interface side having a first coefficient of thermal expansion (CTE); and
hermetically sealing the metal interface side of the interconnect assembly to a ceramic interface side of a fuel cell element, the ceramic interface side having a second CTE, the first CTE and the second CTE satisfying a CTE matching condition comprising the first CTE of the metal interface side and the second CTE of the ceramic interface side being within 10% of each other.

14. The method of claim 13 , further comprising reducing a thickness of the interconnect assembly.

15. The method of claim 13 , where joining the cathode-side interface to the interconnect includes forming a first hermetic braze joint, and wherein joining the anode-side interface to the interconnect includes forming a second hermetic braze joint.

16. The method of claim 13 , where the interconnect assembly is unitary.

17. The method of claim 13 , where the interconnect assembly is a first interconnect assembly and the metal interface side is a first metal interface side, the method further comprising forming a second interconnect assembly, and hermetically sealing the second interconnect assembly to the fuel cell element at a second metal interface side opposite the first metal interface side.

18. A solid oxide fuel cell stack, comprising:
a unitary interconnect assembly comprising:
a cathode-side interface coupled to an interconnect via a first braze joint; and
an anode-side interface coupled to the interconnect via a second braze joint, the interconnect assembly comprising a metal interface side, the metal interface side having a first coefficient of thermal expansion (CTE); and

a fuel cell element comprising a ceramic interface side, the ceramic interface side being coupled to the metal interface side of the interconnect assembly via a hermetic seal, the ceramic interface side having a second CTE, the first CTE and the second CTE satisfying a CTE matching condition comprising the first CTE of the metal interface side and the second CTE of the ceramic interface side being within 10% of each other.

19. The solid oxide fuel cell stack of claim 18 , where the unitary interconnect assembly is a first interconnect assembly and the metal interface side is a first metal interface side, the fuel cell stack further comprising a second interconnect assembly coupled to the fuel cell element at a second metal interface side opposite the first metal interface side.

20. The solid oxide fuel cell stack of claim 18 , where a material composition of the cathode-side interface and a material composition of the anode-side interface each differ from a material composition of the interconnect.

Assignees

• Boeing Co

Inventors

• Mata Marianne E
• Yousefiani Ali
• Lang Adam J
• Zamorano Senderos Bruno
• Balan Chellappa

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/0286 Primary

  Processes for forming seals · CPC title

• H01M2250/20

  Fuel cells in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M8/2432

  Grouping of unit cells of planar configuration · CPC title

• H01M8/0202 Primary

  Collectors; Separators, e.g. bipolar separators; Interconnectors · CPC title