Metal oxide nanofibers including functionalized catalyst using chitosan-metal complexes, and member for gas sensor, and gas sensor using the metal oxide nanofibers, and method of fabricating the same

Patent metadata

Field	Value
Publication number	US-11428660-B2
Application number	US-201916448546-A
Country	US
Kind code	B2
Filing date	Jun 21, 2019
Priority date	Jun 22, 2018
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

Disclosed are a member for a gas sensor, a gas sensor using the member, and a method of fabricating the same. Specifically, disclosed are a member for a gas sensor using a metal oxide nanofiber material in which nanocatalysts have been uniformly bound and functionalized using chitosans with which nanoparticle catalysts have been combined, a gas sensor using the member, and a method of fabricating the same.

First claim

What is claimed is:

1. A metal oxide nanofiber comprising functionalized catalysts, wherein metal is bound to an inside and a surface in nano size and functions as a catalyst through high-temperature thermal treatment of a complex nanofiber comprising chitosan-metal complexes, a metal oxide precursor, and polymers, wherein the chitosan of the chitosan-metal complex naturally contains an inorganic component in a process of extracting the chitosan from a shell of a crustacean and synthesizing the chitosan.

2. The metal oxide nanofibers of claim 1 , wherein metal particles of the chitosans-metal complex are configured with one or two or more metals included in a range of 1 to 100 nm in diameter through bonding with a chitosan.

3. The metal oxide nanofibers of claim 1 , wherein metal particles of the chitosans-metal complex are uniformly bound to a nanofiber and functionalized through dispersibility according to a repulsive force between chitosans.

4. The metal oxide nanofibers of claim 1 , wherein the chitosan is thermally decomposed through high-temperature thermal treatment of the complex nanofiber and forms pores having a size range of 1 to 50 nm in the nanofiber.

5. The metal oxide nanofibers of claim 1 , wherein in the high-temperature thermal treatment process of the complex nanofiber, a thermal decomposition temperature of the chitosan is higher than the crystallization temperature of the metal oxide precursor, the chitosans uniformly distributed in the complex nanofiber suppress a growth of metal oxide particles, and components remaining as residues after the chitosan is decomposed continue to suppress a growth of metal oxide particles.

6. The metal oxide nanofibers of claim 1 , wherein in the high-temperature thermal treatment process of the complex nanofiber, inorganic components included in the chitosan form heterojunctions with metal oxide.

7. The metal oxide nanofibers of claim 1 , wherein wt % of the metal included in the chitosans-metal complex is included in a range of 0.001 to 50 wt % with respect to the metal oxide.

8. The metal oxide nanofibers of claim 1 , wherein the chitosans-metal complex is formed by combining the chitosan with metal ions by adding one or two or more metal salts selected from acetate, nitrate, chloride, acetylacetonate, methoxide, ethoxide, butoxide, isopropoxide, and sulfide to a solution in which the chitosan has been dissolved and reducing the metal ions to one or two or more metal particles through reduction treatment.

9. The metal oxide nanofibers of claim 1 , wherein the metal oxide nanofiber is configured with one or two or more complex metal oxide materials selected from ZnO, SnO 2 , WO 3 , Fe 2 O 3 , Fe 3 O 4 , NiO, TiO 2 , CuO, In 2 O 3 , Zn 2 SnO 4 , Co 3 O 4 , PdO, LaCoO 3 , NiCo 2 O 4 , Ca 2 Mn 3 O 8 , ZrO 2 , Al 2 O 3 , B 2 O 3 , V 2 O 5 , Cr 3 O 4 , CeO 2 , Pr 6 O 11 , Nd 2 O 3 , Sm 2 O 3 , Eu 2 O 3 , Gd 2 O 3 , Tb 4 O 7 , Dy 2 O 3 , Ho 2 O 3 , Er 2 O 3 , Yb 2 O 3 , Lu 2 O 3 , Ag 2 V 4 O 11 , Ag 2 O, Li 0.3 La 0.57 TiO 3 , LiV 3 O 8 , RuO 2 , IrO 2 , MnO 2 , InTaO 4 , ITO, IZO, InTaO 4 , MgO, Ga 2 O 3 , CaCu 3 Ti 4 O 12 , Ag 3 PO 4 , BaTiO 3 , NiTiO 3 , SrTiO 3 , Sr 2 Nb 2 O 7 , Sr 2 Ta 2 O 7 , and Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3-7 .

10. A gas sensor comprising a sensor electrode on which metal oxide nanofibers comprising functionalized catalysts have been coated and capable of measuring a change in resistance, wherein metal is bound to an inside and a surface in nano size and functions as a catalyst through high-temperature thermal treatment of a complex nanofiber comprising chitosan-metal complexes, a metal oxide precursor, and polymers.

Assignees

• Korea Advanced Inst Sci & Tech

Inventors

• Kim Il-Doo
• Jeong Yong Jin
• Koo Won-Tae
• Jang Ji-Soo

Classifications

• D01F9/00 Primary

  Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments · CPC title

• G01N33/497

  of gaseous biological material, e.g. breath · CPC title

• C04B2235/3272

  Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite · CPC title

• C04B2235/95

  Products characterised by their size, e.g. microceramics · CPC title

• C04B35/62231

  based on oxide ceramics · CPC title