Determining fluid properties

Patent metadata

Field	Value
Publication number	US-11428557-B2
Application number	US-202017007399-A
Country	US
Kind code	B2
Filing date	Aug 31, 2020
Priority date	Aug 31, 2020
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

Techniques for measuring liquid properties include circulating a mixed oil-water liquid flow through a fluid flow circuit; polarizing the mixed oil-water liquid flow with a pre-polarizing magnet to an initial polarization; circulating the polarized mixed oil-water liquid flow to an EFNMR detector that includes a radio-frequency (RF) coil and a surrounding electromagnet; further polarizing the polarized mixed oil-water liquid flow with the surrounding electromagnet; measuring fluid induction decay (FID) values of the additionally polarized mixed oil-water liquid flow with the EFNMR detector; transforming the measured FID values to an effective adiabatic transition from the Earth's field to the polarizing field; determining a velocity of the oil in the mixed oil-water liquid flow and a velocity of the water in the mixed oil-water liquid flow based on differences in NMR signal relaxation properties of the transformed FID values; and determining an oil content and a water content of the mixed oil-water liquid flow from the transformed FID values.

First claim

What is claimed is:

1. A fluid measurement system, comprising:
a fluid flow circuit that comprises an oil source, a water source, and a fluid mixer that mixes oil from the oil source and water from the water source into a mixed oil-water liquid flow;
a pre-polarizing magnet positioned to receive the mixed oil-water liquid flow from the fluid mixer;
an Earth's field nuclear magnetic resonance (EFNMR) detector that comprises a radio-frequency (RF) coil and surrounding electromagnet positioned to receive the mixed oil-water liquid flow from the pre-polarizing magnet; and
a control system communicably coupled to the pre-polarizing magnet and the EFNMR detector and configured to perform operations comprising:
controlling the pre-polarizing magnet position to polarize the mixed oil-water liquid flow to an initial polarization;
controlling the electromagnet to additionally polarize the polarized mixed oil-water liquid flow at the initial polarization to an additional polarization;
controlling the EFNMR detector to measure a plurality of fluid induction decay (FID) values of the additionally polarized mixed oil-water liquid flow;
transforming the measured plurality of FID values from a non-adiabatic transition from an Earth's field to a polarizing field to an effective adiabatic transition from the Earth's field to the polarizing field, the transforming comprising selecting a portion of the plurality of FID values that correspond to a particular portion of the polarized mixed oil-water liquid flow that is external to the detection zone of the EFNMR detector at a start time of the additional polarization of the polarized mixed oil-water liquid flow;
determining a velocity of the oil in the mixed oil-water liquid flow and a velocity of the water in the mixed oil-water liquid flow from the transformed plurality of FID values based on differences in NMR signal relaxation properties of the transformed plurality of FID values; and
determining an oil content and a water content of the mixed oil-water liquid flow from the transformed plurality of FID values based on differences in NMR signal relaxation properties of the transformed plurality of FID values, wherein the operations of determining the velocity and content of the oil in the mixed oil-water liquid flow and the velocity and content of the water in the mixed oil-water liquid flow comprise:
applying a pseudo-1D inversion to a selected portion of the plurality of FID values, and
determining a 2D probability distribution of the velocity of the oil in the mixed oil-water liquid flow and the velocity of the water in the mixed oil-water liquid flow based on the applied 1D inversion of the selected portion of the plurality of FID values and a model kernel matrix.

2. The fluid measurement system of claim 1 , wherein the operation of transforming the measured plurality of FID values from a non-adiabatic transition from an Earth's field to a polarizing field to an effective adiabatic transition from the Earth's field to the polarizing field further comprises:
determining the particular portion of the polarized mixed oil-water liquid flow flowing through the detection zone of the EFNMR detector based on the start time of the additional polarization of the polarized mixed oil-water liquid flow; and
determining that the particular portion of the polarized mixed oil-water liquid flow is independent of the non-adiabatic transition from the Earth's field to the polarizing field.

3. The fluid measurement system of claim 1 , wherein the portion of the polarized mixed oil-water liquid flow that is external to the detection zone of the EFNMR detector at the start time of the additional polarization of the polarized mixed oil-water liquid flow is fully within the detection zone of the EFNMR detector at a time subsequent to the start time of the additional polarization of the polarized mixed oil-water liquid flow with an upper bound that comprises a ratio of a length of the detection zone to a velocity of the mixed oil-liquid flow.

4. The fluid measurement system of claim 1 , wherein the model kernel matrix is a function of a polarization pulse time of the electromagnet, a distance between the pre-polarizing magnet and the EFNMR detector, a start time of a radio-frequency signal acquisition, and the NMR signal relaxation properties of the transformed plurality of FID values.

5. The fluid measurement system of claim 1 , wherein the pseudo-1D inversion comprises a Tikhonov inversion.

6. The fluid measurement system of claim 1 , wherein the fluid flow circuit further comprises an oil-water separator fluidly coupled to the oil source and the water source and configured to separate the mixed oil-water liquid flow into an oil flow and a water flow.

7. The fluid measurement system of claim 6 , wherein the fluid flow circuit comprises a recirculating, closed loop flow circuit that includes at least one pump to circulate the mixed oil-water liquid flow, the oil flow, and the water flow through the recirculating, closed loop flow circuit.

8. The fluid measurement system of claim 1 , wherein the plurality of FID values are a function of velocity values and T 1 values.

9. A method for measuring liquid properties, comprising:
circulating a mixed oil-water liquid flow through a fluid flow circuit that comprises an oil source, a water source, and a fluid mixer that mixes oil from the oil source and water from the water source into the mixed oil-water liquid flow;
circulating the mixed oil-water liquid flow through a pre-polarizing magnet;
polarizing the mixed oil-water liquid flow with the pre-polarizing magnet to an initial polarization;
circulating the polarized mixed oil-water liquid flow at the initial polarization to an Earth's field nuclear magnetic resonance (EFNMR) detector that comprises a radio-frequency (RF) coil and a surrounding electromagnet;
further polarizing the polarized mixed oil-water liquid flow with the surrounding electromagnet;
measuring a plurality of fluid induction decay (FID) values of the additionally polarized mixed oil-water liquid flow with the EFNMR detector;
transforming the measured plurality of FID values from a non-adiabatic transition from an Earth's field to a polarizing field to an effective adiabatic transition from the Earth's field to the polarizing field, the transforming comprising selecting a portion of the plurality of FID values that correspond to a particular portion of the polarized mixed oil-water liquid flow that is external to the detection zone of the EFNMR detector at a start time of the additional polarization of the polarized mixed oil-water liquid flow;
determining a velocity of the oil in the mixed oil-water liquid flow and a velocity of the water in the mixed oil-water liquid flow based on differences in NMR signal relaxation properties of the transformed plurality of FID values; and
determining an oil content and a water content of the mixed oil-water liquid flow from the transformed plurality of FID values based on differences in the NMR signal relaxation properties of the transformed plurality of FID values, wherein determining the velocity and content of the oil in the mixed oil-water liquid flow and the velocity and content of the water in the mixed oil-water liquid flow comprises:
applying a pseudo-1D inversion to a selected portion of the plurality of FID values, and
determining a 2D probability distribution of the velocity of the oil in the mixed oil-water liquid flow and the velocity of the water in the mixed oil-water liquid flow based on the applied 1D inversion of the selected portion of the plurality of FID values and a model kernel matrix.

10. The method of claim 9 , wherein transforming the measured plurality of FI

Assignees

• Saudi Arabian Oil Co

Inventors

• O'Neill Keelan Thomas
• Johns Michael Leslie
• Fridjonsson Einar Orn
• Stanwix Paul Louis
• Al-Jindan Jana M
• Noui-Mehidi Mohamed Nabil

Classifications

• G01F1/716 Primary

  using electron paramagnetic resonance [EPR] or nuclear magnetic resonance [NMR] · CPC title

• G01R33/448

  Relaxometry, i.e. quantification of relaxation times or spin density (G01R33/50 takes precedence) · CPC title

• G01F1/74

  Devices for measuring flow of a fluid or flow of a fluent solid material in suspension in another fluid · CPC title

• G01R33/445

  MR involving a non-standard magnetic field B0, e.g. of low magnitude as in the earth's magnetic field or in nanoTesla spectroscopy, comprising a polarizing magnetic field for pre-polarisation, B0 with a temporal variation of its magnitude or direction such as field cycling of B0 or rotation of the direction of B0, or spatially inhomogeneous B0 like in fringe-field MR or in stray-field imaging · CPC title

• G01R33/307

  specially adapted for moving the sample relative to the MR system, e.g. spinning mechanisms, flow cells or means for positioning the sample inside a spectrometer · CPC title