Protein-based water insoluble and bendable polymer with ionic conductivity

Patent metadata

Field	Value
Publication number	US-11427709-B2
Application number	US-201917277974-A
Country	US
Kind code	B2
Filing date	Sep 20, 2019
Priority date	Sep 21, 2018
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

An ionic conductive, stretchable, and flexible transparent material includes silk fibroin, a nanomaterial, and an electrolyte. The material can be recycled. A flexible surface capacitive touch panel and a flexible motion sensor can both be based on the ionic conductive, stretchable, and flexible transparent material. The ionic conductive, stretchable, and flexible transparent material shows many desirable properties, such as a good crystallinity, transparency, mechanical strength, recyclability, optical transparency, and electrical sensitivity. The material shows chemical and thermal stability, in addition to excellent dimensional stability.

First claim

What is claimed is:

1. An ionic conductive, stretchable, and flexible transparent material comprising silk fibroin, a nanomaterial, and an electrolyte, wherein the nanomaterial is present in an amount of 3 to 24 parts by weight for every 100 parts by weight of the silk fibroin, wherein the nanomaterial is a nano clay, a Mxene or a combination hereof.

2. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein the electrolyte is present in an amount above 2 parts by weight for every 100 parts by weight of the silk fibroin.

3. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein the nanomaterial further comprises a carbon nanomaterial.

4. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein the nanomaterial is present in an amount of 6 to 20 parts.

5. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein an optical transmittance of light through the ionic conductive, stretchable, and flexible transparent material at a wavelength above 400 nm is at least 50%.

6. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein the ionic conductive, stretchable, and flexible transparent material is dissolvable in a dissolving solution, the dissolving solution comprising:
lithium bromide in a concentration of at least 8 molar, and
optionally sodium hydroxide in a concentration of at least 0.3 molar.

7. The ionic conductive, stretchable, and flexible transparent material according to claim 1 , wherein the ionic conductive, stretchable, and flexible transparent material has a tensile strength of at least 10 MPa, and
wherein the tensile strength is measured by pulling the material while measuring the stress applied and the distance moved.

8. A method of recycling an ionic conductive, stretchable, and flexible transparent material comprising silk fibroin, a nanomaterial, and an electrolyte, wherein the nanomaterial is present in an amount of 3 to 24 parts by weight for every 100 parts by weight of the silk fibroin wherein the nanomaterial is a nano clay, a Mxene or a combination hereof, and wherein the recycling method comprises the steps of:
mixing a dissolving solution comprising lithium bromide in a concentration of at least 8 molar;
adding the ionic conductive, stretchable, and flexible transparent material to the dissolving solution;
dissolving the ionic conductive, stretchable, and flexible transparent material in the dissolving solution hereby creating a solid phase and a liquid supernatant phase;
centrifuging the dissolving solution and collecting the supernatant phase wherein the silk fibroin is contained; and
purifying the supernatant phase comprising the silk fibroin by dialysis against deionized water for at least 10 hours.

9. A flexible surface capacitive touch panel comprising a touch panel material defining a touch panel surface area, wherein the touch panel material comprises:
silk fibroin;
a nanomaterial, wherein the nanomaterial is present in an amount of 3 to 24 parts by weight for every 100 parts by weight of the silk fibroin, and
an electrolyte, wherein the electrolyte is present in an amount above 2 parts by weight for every 100 parts by weight of the silk fibroin,
wherein the nanomaterial is a nano clay, a Mxene or a combination hereof.

10. The flexible surface capacitive touch panel according to claim 9 , wherein the touch panel surface area has a square shape and wherein the touch panel further comprises at least three electrodes connected to and positioned at opposite corners or edges of the touch panel.

11. The flexible surface capacitive touch panel according to claim 10 , further comprising a controller calculating the location of touch based on the change in current from the electrodes.

12. A flexible motion sensor comprising a flexible motion sensor material defining a flexible motion sensor surface area, wherein the flexible motion sensor material comprises:
silk fibroin,
a nanomaterial, wherein the nanomaterial is present in an amount of 3 to 24 parts by weight for every 100 parts by weight of the silk fibroin, and
an electrolyte, wherein the electrolyte is present in an amount above 2 parts by weight for every 100 parts by weight of the silk fibroin,
wherein the nanomaterial is a nano clay, a Mxene or a combination hereof.

13. The flexible motion sensor according to claim 12 , further comprising at least one selected from the group of a silver paste, a copper wire, a cloth adhesive tape, or combinations hereof.

14. A method for production of an ionic conductive, stretchable, and flexible transparent material comprising steps of:
dissolving silk fibroin in a solution comprising lithium bromide to obtain a silk fibroin solution, wherein the lithium bromide is in a concentration above 8 molar;
heating the silk fibroin solution to a temperature above 50° C. for at least 3 hours;
dialyzing the silk fibroin solution against deionized water for at least 24 hours;
centrifuging the silk fibroin solution to remove impurities and collecting the supernatant;
adjusting the pH of the supernatant of the silk fibroin solution to a pH above 10;
dissolving an electrolyte in the desired amount in the supernatant of the silk fibroin solution;
dissolving a nanomaterial in the desired amount in the supernatant of the silk fibroin solution; and
casting the silk fibroin solution at a required size at a temperature above 30° C. for at least 18 hours, hereby obtaining an ionic conductive, stretchable, and flexible transparent material comprising silk fibroin, the nanomaterial, and the electrolyte,
wherein the nanomaterial is a nano clay, a Mxene or a combination hereof.

15. The method for production of an ionic conductive, stretchable, and flexible transparent material according to claim 14 , further comprising a step of hydrating the obtained conductive, stretchable, and flexible transparent material with deionized water or a 2 molar lithium chloride solution.

16. A method for production of a flexible surface capacitive touch panel, the method comprising the step of:
affixing at least two platinum or copper plates on the ionic conductive, stretchable, and flexible transparent material obtained by the method according to claim 14 , using silver epoxy paste, hereby obtaining a flexible surface capacitive touch panel,
wherein the flexible surface capacitive touch panel is adapted for operating at an AC voltage of −0.5 to 0.5 V and within a frequency range of 10 to 40 kHZ, wherein an AC current or capacitance response from a finger-touch is measureable using an oscilloscope.

17. A method for production of a flexible motion sensor comprising the steps of:
connecting copper wires to both ends of the ionic conductive, stretchable, and flexible transparent material obtained by the method according to claim 14 using conductive silver epoxy paste, hereby obtaining a flexible motion sensor, wherein the flexible motion sensor is adapted for operating at 10 kHz by applying an AC voltage ranging from −0.5 to 0.5 V;
attaching the flexible motion sensor to various moving parts of a body such as a finger, a wrist, a shoulder, an ankle, an elbow, or a knee, by means of cloth adhesive tape or adhesive layers;
optionally attaching the flexible motion sensor to various wearable devices such as glove, sleeves, or jackets, made up of textiles or polymers; and
monitoring resistance changes in response to body movements.

Assignees

• Univ Danmarks Tekniske

Inventors

• Dolatshahi-Pirouz Alireza
• Kadumudi Firoz Babu
• Mehrali Mehdi

Classifications

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08K3/16

  Halogen-containing compounds · CPC title

• G06F2203/04102

  Flexible digitiser, i.e. constructional details for allowing the whole digitising part of a device to be flexed or rolled like a sheet of paper · CPC title

• A61B2562/0261

  Strain gauges · CPC title

• C08L2203/20

  use in electrical or conductive gadgets · CPC title