Method for manufacturing low molecular weight acrylic resin

Patent metadata

Field	Value
Publication number	US-11427658-B2
Application number	US-201916961055-A
Country	US
Kind code	B2
Filing date	Jan 11, 2019
Priority date	Jan 11, 2018
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

A method for manufacturing a low molecular weight acrylic resin, and more particularly, to a method for manufacturing a low molecular weight acrylic resin having a high conversion rate and a low poly dispersion index includes maintaining the temperature of a reacting part with a screw stirrer at a specific temperature during a continuous polymerization of a solvent-free acrylic composition in a continuous flow reactor having the reacting part.

First claim

The invention claimed is:

1. A method for manufacturing a low molecular weight acrylic resin by continuously polymerizing a solvent-free acrylic composition comprising one or more (meth)acrylate-based monomers and a thermal initiator in a continuous flow reactor, wherein the continuous flow reactor comprises a reacting part with a screw stirrer, a feeding part, and a discharging part, the method comprising:
feeding the solvent-free acrylic composition to the reacting part through the feeding part;
maintaining a temperature of the reacting part at 70° C. or more and 150° C. or less and continuously polymerizing the solvent-free acrylic composition to form forming a low molecular weight acrylic resin having a weight average molecular weight of 20,000 g/mol or more and 150,000 g/mol or less; and
discharging the low molecular weight acrylic resin through the discharging part,
wherein a separation distance adjacent stirring blades of the screw stirrer to 10 mm or more and 20 mm or less.

2. The method of claim 1 , wherein the solvent-free acrylic composition is fed to the reacting part at a feeding flow rate of 30 mL/min or more and 200 mL/min or less.

3. The method of claim 1 , wherein the thermal initiator is comprised in a content of 0.1 part by weight or more and 1 part by weight or less with respect to 100 parts by weight of the (meth)acrylate-based monomer.

4. The method of claim 1 , wherein the solvent-free acrylic composition does not comprise a molecular weight regulator.

5. The method of claim 1 , wherein a ratio of a length to a diameter of the reacting part is 14:1 to 28:1.

6. The method of claim 1 , wherein a shortest distance from a distal end of a stirring blade to a stirring axis in the screw stirrer is 5 mm or more and 10 mm or less.

7. The method of claim 1 , wherein in the maintaining the temperature of the reacting part, the reacting part is composed of a front end part and a rear end part, and
the temperature of the front end part is maintained at 100° C. or more and 150° C. or less, and the temperature of the rear end part is maintained at 70° C. or more and 110° C. or less.

8. The method of claim 1 , wherein the continuous polymerizing is performed for 1 hour or more and 2 hours or less.

9. The method of claim 1 , further comprising maintaining an internal pressure of the reacting part at 5 bar or less during the continuous polymerization.

10. The method of claim 1 , wherein a conversion rate of the low molecular weight acrylic resin measured according to the following General Equation 1 is 70% or more and 99% or less:
C=B/A× 100%  [General Equation 1]

wherein, A means a weight (g) of the low molecular weight acrylic resin, B means a weight (g) of a dried low molecular weight acrylic resin, and C means a conversion rate (%).

11. The method of claim 9 , wherein the internal pressure of the reacting part is 1 bar to 5 bar.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Woo Yeon
• Choi Jun Man
• Kim Jang Soon
• Seo Kwang Su

Classifications

• C08F20/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F2/02

  Polymerisation in bulk · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F2500/02

  Low molecular weight, e.g. <100,000 Da. · CPC title

• C08F220/1808 Primary

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title