Method to produce a dental structure and dental structure

Patent metadata

Field	Value
Publication number	US-11427504-B2
Application number	US-201615159427-A
Country	US
Kind code	B2
Filing date	May 19, 2016
Priority date	May 22, 2015
Publication date	Aug 30, 2022
Grant date	Aug 30, 2022

Abstract

The invention relates to a method to produce a dental structure with a cavity having a negative form of the structure, which is formed in an investment material, wherein flowable lithium silicate glass ceramic is pressed into the cavity. Thereby a compressive surface stress is created in the ceramic structure through the replacement of lithium ions by alkali ions, in that the model is enriched with alkali compounds and/or the model is covered with a layer of a material containing alkali ions.

First claim

The invention claimed is:

1. A method to produce a dental structure comprising the steps of:
providing an investment mold having a cavity that has a negative shape of the dental structure, wherein the shape of the cavity is defined from a positive model formed in an investment material within the investment mold, wherein the positive model is covered with a layer of material that includes the alkali ions;
heating the investment mold so that at least a portion of the alkali ions in the layer of material covering the positive model is diffused into a wall of the cavity;
pressing lithium silicate glass ceramic into the cavity to form a ceramic structure; and
creating a surface compressive stress in the ceramic structure through replacement of lithium ions by alkali ions of a greater diameter between an exterior surface of the ceramic structure and the alkali ions diffused into the wall of the cavity;
wherein the layer is applied with a thickness D where 10 μm≤D≤100 μm; and
wherein the lithium silicate glass ceramic is derived from a glass melt that includes the following starting components in percentages by weight:

SiO 2
  52-70,

at least one nucleating agent
  3-8,

Al 2 O 3
0.5-5,

Li 2 O
  13-22,

K 2 O
0.5-8,

Na 2 O
   0-0.5,

ZrO 2
  4-16,

CeO 2
0.5-8,

Tb 4 O 7
0.5-6,

greater than 0 but less than or equal to 20 of an oxide or a number of oxides of an earth alkali metal or a number of earth alkali metals from the group magnesium, calcium, strontium, barium,
greater than 0 but less than or equal to 6 of one or more additives selected from the group consisting of B 2 O 3 , MnO 2 , Fe 2 O 3 , V 2 O 5 , TiO 2 , Sb 2 O 3 , ZnO, SnO 2 and fluorides, and
greater than 0 but less than or equal to 5 of one or more oxides of the rare earth metals with the atomic numbers 57, 59-64, 66-71,
wherein the total sum is 100% by weight.

2. The method according to claim 1 , wherein the percentage by weight of the alkali ions in the layer covering the positive model is in the range 0.5-10% by weight.

3. The method of claim 1 , wherein the at least one nucleating agent is P 2 O 5 .

4. The method according to claim 1 , further comprising the step of forming one or more lithium silicate glass ceramic pellets from the glass melt and subjecting the lithium silicate glass ceramic pellet to at least a first heat treatment W1 at a temperature Twi for a period of time T w1 , wherein 620° C.≤T w1 ≤800° C., and/or 1 minute≤t w1 ≤200 minutes.

5. The method according to claim 4 , wherein the first heat treatment W1 is carried out in two stages, including a first holding stage having a temperature T st1 wherein 630° C.≤T st1 ≤690° C. and a heating rate A st1 up to the temperature T st1 , wherein 1.5 K/minute≤A st1 ≤2.5 K/minute; and a second holding stage having a temperature T st2 wherein 720° C.≤T st2 ≤780° C. and a heating rate A st2 up to the temperature T st2 , wherein 8 K/minute≤T st2 ≤12 K/minute.

6. The method according to claim 4 , wherein the one or more lithium silicate glass ceramic pellets after the first heat treatment W1 is subject to a second heat treatment W2 at a temperature T w2 for a period of time t w2 , wherein 800° C.≤T w2 ≤1040° C., and/or 5 minutes≤t w2 200 minutes.

7. The method of claim 1 , wherein the layer of material with which the positive model is covered includes potassium ions and at least one salt selected from the group consisting of one or more inorganic acids and one or more organic acids.

8. The method of claim 7 , wherein the layer of material with which the positive model is covered further alkali compounds in the form of one or more salts of inorganic acids and/or organic acids that are selected from the group consisting of nitrates carbonates, acetates and chlorides.

Assignees

• Dentsply Sirona Inc

Inventors

• Vollmann Markus
• Schusser Udo

Classifications

• A61K6/853

  Silicates · CPC title

• A61C13/081

  Making teeth by casting or moulding · CPC title

• A61K6/818

  comprising zirconium oxide · CPC title

• A61K6/822 Primary

  comprising rare earth metal oxides · CPC title

• C03C4/0021

  for dental use · CPC title