Methods for carbon dioxide hydrogenation

Patent metadata

Field	Value
Publication number	US-11421330-B2
Application number	US-201816493077-A
Country	US
Kind code	B2
Filing date	Mar 15, 2018
Priority date	Mar 16, 2017
Publication date	Aug 23, 2022
Grant date	Aug 23, 2022

Abstract

A method of carbon dioxide hydrogenation comprises introducing gaseous water to a positive electrode of an electrolysis cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10-2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. Carbon dioxide is introduced to the negative electrode of the electrolysis cell. A potential difference is applied between the positive electrode and the negative electrode of the electrolysis cell to generate hydrogen ions from the gaseous water that diffuses through the proton-conducting membrane and hydrogenates the carbon dioxide at the negative electrode. A carbon dioxide hydrogenation system is also described.

First claim

What is claimed is:

1. A method of carbon dioxide hydrogenation, comprising:
introducing gaseous water to a positive electrode of an electrolysis cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode,
the proton-conducting membrane comprising at least one perovskite material having an ionic conductivity greater than or equal to about 10 −2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. and selected to comprise one or more of yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb), yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb), and Ba 2 (YSn)O 5.5 , and
the positive electrode selected to comprise one or more of MBa 1-x Sr x Co 2-y Fe y O 5+δ and A 2 NiO 4−δ , where:
M is Pr, Nd, or Sm,
A is La, Pr, Gd, or Sm,
x and y are dopant levels, and
δ is oxygen deficit

introducing carbon dioxide to the negative electrode of the electrolysis cell; and
applying a potential difference between the positive electrode and the negative electrode of the electrolysis cell to generate hydrogen ions from the gaseous water that diffuse through the proton-conducting membrane and hydrogenate the carbon dioxide at the negative electrode.

2. The method of claim 1 , further comprising selecting the at least one perovskite material to have a H + conductivity greater than or equal to about 10 −2 S/cm at one or more temperatures within a range of from about 350° C. to about 650° C.

3. The method of claim 2 , further comprising selecting the at least one perovskite material to comprise a stack of at least two different perovskite materials each individually having the H + conductivity greater than or equal to about 10 −2 S/cm at the one or more temperatures within the range of from about 350° C. to about 650° C., at least one of the at least two different perovskite materials comprising the one or more of yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb), the yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb), and the Ba 2 (YSn)O 5.5 .

4. The method of claim 2 , further comprising selecting the negative electrode to comprise a cermet material comprising at least one metal and at least one perovskite.

5. The method of claim 1 , wherein introducing gaseous water to a positive electrode of an electrolysis cell comprises exposing the positive electrode of the electrolysis cell to the gaseous water without exposing the negative electrode of the electrolysis cell to the gaseous water.

6. The method of claim 1 , further comprising heating the gaseous water to a temperature within the range of from about 150° C. to about 650° C. effectuating the ionic conductivity greater than about 10 −2 S/cm within the proton-conducting membrane prior to applying a potential difference between the positive electrode and the negative electrode of the electrolysis cell.

7. The method of claim 1 , further comprising selecting the at least one perovskite material to comprise the yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb).

8. The method of claim 1 , further comprising selecting the at least one perovskite material to comprise the Ba 2 (YSn)O 5.5 .

9. The method of claim 1 , further comprising selecting the proton-conducting membrane to have a thickness within a range of from about 5 μm to about 1000 μm.

10. The method of claim 1 , further comprising selecting the proton-conducting membrane to be substantially homogeneous.

11. The method of claim 1 , further comprising selecting the positive electrode to comprise the MBa 1-x Sr x Co 2-y Fe y O 5+δ .

12. The method of claim 11 , further comprising selecting the positive electrode to comprise the MBa 1-x Sr x Co 2-y Fe y O 5+δ , wherein the MBa 1-x Sr x Co 2-y Fe y O 5+δ is selected from the group comprising PrBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ , NdBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ , and SmBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ .

13. The method of claim 1 , further comprising selecting the positive electrode to comprise the A 2 NiO 4−δ .

14. The method of claim 1 , further comprising selecting the negative electrode to comprise a cermet material comprising nickel and one of yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb), yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb), and Ba 2 (YSn)O 5.5 .

15. A method of carbon dioxide hydrogenation, comprising:
introducing gaseous water to a positive electrode of an electrolysis cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode, the proton-conducting membrane comprising at least one perovskite material having an ionic conductivity greater than or equal to about 10 −2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. and selected to comprise yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb);
introducing carbon dioxide to the negative electrode of the electrolysis cell; and
applying a potential difference between the positive electrode and the negative electrode of the electrolysis cell to generate hydrogen ions from the gaseous water that diffuse through the proton-conducting membrane and hydrogenate the carbon dioxide at the negative electrode.

Assignees

• Battelle Energy Alliance Llc

Inventors

• He Ting
• Ding Dong
• Li Chenlin

Classifications

• C25B11/0773

  of the perovskite type · CPC title

• C25B11/047

  Ceramics · CPC title

• C25B15/08

  Supplying or removing reactants or electrolytes; Regeneration of electrolytes · CPC title

• C25B13/07

  based on ceramics · CPC title

• C25B13/04

  characterised by the material · CPC title