High melt strength polypropylene and extrusion process for preserving melt strength

Patent metadata

Field	Value
Publication number	US-11414526-B2
Application number	US-201515321594-A
Country	US
Kind code	B2
Filing date	Jun 25, 2015
Priority date	Jun 25, 2014
Publication date	Aug 16, 2022
Grant date	Aug 16, 2022

Abstract

A method of melt blending a polypropylene and the melt blended polypropylene therefrom, comprising providing a base-polypropylene having a MFR of less than 15 g/10 min and a molecular weight distribution (Mw/Mn) within the range from 5 to 16, and comprising hindered phenol and phosphorous-type antioxidants, and within the range from 5 ppm to 4000 ppm of an alkyl radical scavenger relative to the total weight of the components to form a melt blended polypropylene; melt blending the melt blended polypropylene at a temperature of at least 210° C.; and isolating a melt blended, melt blended polypropylene.

First claim

The invention claimed is:

1. A method of melt blending a polypropylene composition, comprising:
providing (A) a base-polypropylene having a melt flow rate according to ASTM D1238, condition L, of less than 15 g/10 min, a molecular weight distribution (Mw/Mn) of 6 to 16, and a ratio of a z-average molecular weight and a weight average molecular weight (Mz/Mw) within a range of 2.8 and 5.0, (B) at least one hindered phenol antioxidant and at least one phosphorous-type antioxidant, and (C) within the range from 5 ppm to 4000 ppm of an alkyl radical scavenger and within the range from 1000 ppm to 2000 ppm of an acid scavenger relative to the total weight of the components, wherein the acid scavenger is formulated as a solid, and wherein the at least one hindered phenol antioxidant, the at least one phosphorous-type antioxidant, and the alkyl radical scavenger are mixed and formed into one or more solid pellets,
wherein the alkyl radical scavenger comprises one or more 6-chromanol-containing compounds selected from the group consisting of compounds of formula:

wherein each of R 1 , R 2 , R 3 , R 6 ′ and R 6 are independently selected from hydrogen and C 1 to C 10 linear alkyls or branched alkyls, and
wherein each of R 4 , R 5 , R 4 ′, and R 5 ′ are independently selected from hydrogen and C 1 to C 30 linear or branched alkyls;
melt blending the base-polypropylene, the acid scavenger, and the one or more solid pellets in an extruder having a temperature controlled length from the feed zone to the die zone, wherein the initial melt temperature at the feed zone is less than 180° C., wherein the final melt temperature at the die zone of at least 210° C., and wherein oxygen is excluded from at least the feed zone during the melt blending; and
isolating a melt blended polypropylene, wherein the melt blended polypropylene has a Tensile at Yield within a range of 45 MPa to 80 MPa.

2. The method of claim 1 , wherein the alkyl radical scavenger is present within the range from 20 ppm to 3000 ppm relative to the total weight of the components.

3. The method of claim 1 , wherein a screen pack is absent from the extruder, or if present, is at least as course as 80 mesh.

4. The method of claim 1 , wherein the base-polypropylene has a melt strength of at least 15 cN at 190° C.

5. The method of claim 1 , wherein at 260° C. there is less than a 20% drop in the melt strength of the melt blended polypropylene relative to the base-polypropylene.

6. The method of claim 1 , wherein the properties of the melt blended polypropylene are within ±20% of that measured property's original value prior to melt blending for the base-polypropylene.

7. The method of claim 1 , wherein the hindered phenol and phosphorous-type antioxidants are independently present within a range from 500 ppm to 3000 ppm.

8. The method of claim 1 , wherein at least the base-polypropylene used to form the melt blended polypropylene is melt blended through an apparatus having a length, wherein there is a temperature change along such length from the entrance of the extruder to the exit of the extruder of at least 80° C.

9. The method of claim 1 , wherein the melt blended polypropylene is foamed, thermoformed, injection molded, blow molded, extrusion coated, or melt/spun bonded to form articles.

10. The method of claim 1 , wherein the Tensile at Yield of the melt blended polypropylene is within a range of 50 MPa to 80 MPa.

11. The method of claim 1 , wherein the hindered phenol and phosphorous-type antioxidants are independently present within a range from 800 ppm to 3000 ppm.

Assignees

• Exxonmobil Chemical Patents Inc
• Basf Se

Inventors

• Pehlert George J
• Zhao Mosha H
• King Roswell E

Classifications

• B29K2023/12

  PP, i.e. polypropylene · CPC title

• B29C48/875

  for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08J3/203 Primary

  Solid polymers with solid and/or liquid additives · CPC title

• B29C48/76

  Venting {, drying} means; Degassing means · CPC title