Froth flotation with anisotropic particle collectors

Patent metadata

Field	Value
Publication number	US-11413629-B2
Application number	US-201916579363-A
Country	US
Kind code	B2
Filing date	Sep 23, 2019
Priority date	Dec 22, 2015
Publication date	Aug 16, 2022
Grant date	Aug 16, 2022

Abstract

In one example, a method includes providing a pulp composed of a combination of particulate materials including particles of a target material. The pulp is mixed with a collector composed of anisotropic particles having at least two separate spatial domains that have different physiochemical properties, and the mixture of pulp and collector is fed into an aqueous solution containing air bubbles.

First claim

What is claimed is:

1. A system, comprising:
a mixing chamber comprising:
a first feed line coupled to a source of a pulp; and
a second feed line coupled to a source of a collector;

the source of the collector, wherein the source of the collector comprises anisotropic particles having at least two separate spatial domains that have different physiochemical properties; and
a flotation chamber comprising:
a third feed line coupled to a source of air; and
a fourth feed line coupled to an output of the mixing chamber;

wherein:
the pulp comprises a combination of particulate materials including particles of a target material; and
at least some particles of the anisotropic particles comprise:
a plurality of hydrocarbon chains; and
functional groups borne on a first subset of the plurality of hydrocarbon chains;

the at least some particles of the anisotropic particles are arranged to provide a hierarchical surface structure comprising:
a micro-scale surface comprising bodies of the at least some particles of the aniostropic particles; and
a nano-scale surface extending from the micro-scale surface and comprising at least some of the plurality of hydrocarbon chains.

2. The system of claim 1 , wherein the mixing chamber further comprises:
an ultrasound sonicator positioned in the mixing chamber.

3. The system of claim 1 , wherein a first domain of the at least two separate spatial domains is hydrophobic, and a second domain of the at least two spatial domains is hydrophilic.

4. The system of claim 1 , wherein the functional groups selectively adsorb the at least some of the particles to the particles of the target material.

5. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises electrostatic interaction.

6. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises complexation.

7. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises chemical bond formation.

8. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises hydrogen bonding.

9. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises Van der Waals interaction.

10. The system of claim 4 , wherein a mechanism of adsorption that selectively adsorbs the at least some of the particles to the particles of the target material comprises hydrophobic interaction.

11. The system of claim 1 , wherein a second subset of the plurality of hydrocarbon chains not including the functional groups attaches the at least some of the particles to the air bubbles.

12. The system of claim 1 , wherein the second subset comprises non-polar hydrocarbons.

13. The system of claim 1 , wherein a diameter of the anisotropic particles is in the nanometer to micrometer range.

14. The system of claim 1 , wherein at least a portion of at least some of the anisotropic particles is treated with a hydrophobic coating.

15. The system of claim 1 , wherein the flotation cell comprises:
a hollow, elongate column;
a first collection point positioned at a first end of the column; and
a second collection point positioned at a second end of the column.

16. A system, comprising:
a source of a pulp, wherein the pulp comprises a combination of particulate materials including particles of a target material;
a source of the collector, wherein the source of the collector comprises anisotropic particles having at least two separate spatial domains that have different physiochemical properties;
a mixing chamber having a first feed line that is coupled to the source of the pulp and the source of the collector; and
a flotation chamber comprising:
a second feed line coupled to a source of air; and
a third feed line coupled to an output of the mixing chamber;

wherein:
at least some particles of the anisotropic particles comprise:
a plurality of hydrocarbon chains; and
functional groups borne on a first subset of the plurality of hydrocarbon chains;

the at least some particles of the anisotropic particles are arranged to provide a hierarchical surface structure comprising:
a micro-scale surface comprising bodies of the at least some particles of the aniostropic particles; and
a nano-scale surface extending from the micro-scale surface and comprising at least some of the plurality of hydrocarbon chains.

17. The system of claim 16 , wherein the mixing chamber further comprises:
an ultrasound sonicator positioned in the mixing chamber; and
a controller to control at least one of: a duration of an ultrasonic pulse emitted by the ultrasound sonicator, a location of an ultrasonic pulse emitted by the ultrasound sonicator, and a power of an ultrasonic pulse emitted by the ultrasound sonicator.

Assignees

• IBM

Inventors

• Baldauf Julia
• Bojovschi Alexe
• Mashford Benjamin S
• Schieber Christine
• Yiapanis George

Classifications

• B03D2201/02

  Collectors · CPC title

• B03D1/006 Primary

  Hydrocarbons · CPC title

• B03D1/12

  Agent recovery · CPC title

• B03D1/023

  Carrier flotation; Flotation of a carrier material to which the target material attaches · CPC title