Filtering membrane cleaning method

Patent metadata

Field	Value
Publication number	US-11413583-B2
Application number	US-202016888488-A
Country	US
Kind code	B2
Filing date	May 29, 2020
Priority date	Dec 11, 2017
Publication date	Aug 16, 2022
Grant date	Aug 16, 2022

Abstract

Provided is a method for cleaning a filtration membrane provided in a membrane filtration device that is immersed in a liquid to be treated and performs solid-liquid separation on the liquid to be treated. When a transmembrane pressure difference exceeds a first predetermined pressure difference P1, a first cleaning step W1 for cleaning a filtration membrane is performed using a first chemical solution; when the transmembrane pressure difference immediately after performing the first cleaning step W1 exceeds a second predetermined pressure difference P2 that is lower than the first predetermined pressure difference, a second cleaning step W2 for cleaning the filtration membrane is performed using a second chemical solution having a concentration higher than the first chemical solution; and when the second cleaning step W2 is performed, the concentration of the second chemical solution and/or the cleaning time is changed according to the temperature of the liquid to be treated.

First claim

What is claimed is:

1. A method for cleaning a filtration membrane which is provided in a membrane filtration device immersed in a liquid to be treated and performs solid-liquid separation of the liquid to be treated, the method comprising:
monitoring a transmembrane pressure difference of the filtration membrane while performing a filtration operation by the membrane filtration device;
performing, repeatedly, a first cleaning step for cleaning the filtration membrane using a first chemical solution, if a current transmembrane pressure difference exceeds a first predetermined pressure difference, followed by returning to the filtration operation;
performing, repeatedly, a second cleaning step for cleaning the filtration membrane using a second chemical solution having a concentration higher than that of the first chemical solution and/or for a cleaning time longer than that of the first cleaning step, instead of performing the first cleaning step, if an initial transmembrane pressure difference measured immediately after the first cleaning step most recently performed exceeds a second predetermined pressure difference which is lower than the first predetermined pressure difference, and if the current transmembrane pressure difference exceeds the first predetermined pressure difference, followed by returning to the filtration operation;
performing a determining step including:
obtaining and comparing a previous initial transmembrane pressure difference measured immediately after the second cleaning step performed previously and most recently, and a current initial transmembrane pressure difference measured immediately after the second cleaning step performed this time; and
determining if a quotient obtained by dividing the current initial transmembrane pressure difference by the previous initial transmembrane pressure difference exceeds a predetermined ratio;

performing a third cleaning step for cleaning the filtration membrane using a third chemical solution different from the first and second chemical solutions, if the quotient obtained in the determining step exceeds the predetermined ratio, followed by returning to the filtration operation; and
returning to the filtration operation without performing the third cleaning step, if the quotient obtained in the determining step does not exceed the predetermined ratio.

2. The method for cleaning the filtration membrane according to claim 1 , wherein the second cleaning step includes changing the concentration of the second chemical solution and/or the cleaning time of the second cleaning step in accordance with a temperature of the liquid to be treated.

3. The method for cleaning the filtration membrane according to claim 2 , wherein in performing the second cleaning step, the concentration of the second chemical solution is decreased as the temperature of the liquid to be treated increases, and the concentration of the second chemical solution is increased as the temperature of the liquid to be treated decreases.

4. The method for cleaning the filtration membrane according to claim 2 , wherein in performing the second cleaning step, the cleaning time is decreased as the temperature of the liquid to be treated increases, and the cleaning time is increased as the temperature of the liquid to be treated decreases.

5. The method for cleaning the filtration membrane according to claim 1 , wherein the first chemical solution and the second chemical solution remove organic substance adhered to the filtration membrane.

6. The method for cleaning the filtration membrane according to claim 1 , wherein in performing the third cleaning step, a concentration of the third chemical solution is decreased as a temperature of the liquid to be treated increases, and the concentration of the third chemical solution is increased as the temperature of the liquid to be treated decreases.

7. The method for cleaning the filtration membrane according to claim 1 , wherein in performing the third cleaning step, a cleaning time is decreased as temperature of the liquid to be treated increases, and the cleaning time is increased as the temperature of the liquid to be treated decreases.

8. The method for cleaning the filtration membrane according to claim 1 , wherein the third chemical solution removes inorganic substance adhered to the filtration membrane.

9. A method for cleaning a filtration membrane provided in a membrane filtration device which is immersed in a liquid to be treated and performs solid-liquid separation of the liquid to be treated, the method comprising:
monitoring a permeability of the filtration membrane while performing a filtration operation by the membrane filtration device;
performing, repeatedly, a first cleaning step for cleaning the filtration membrane using a first chemical solution, if a current permeability of the filtration membrane is lower than a first predetermined permeability, followed by returning to the filtration operation;
performing, repeatedly, a second cleaning step for cleaning the filtration membrane using a second chemical solution having a concentration higher than that of the first chemical solution and/or for a cleaning time longer than that of the first cleaning step, instead of performing the first cleaning step, if an initial permeability of the filtration membrane measured immediately after the first cleaning step most recently performed is lower than a second permeability which is higher than the first predetermined permeability, and if the current permeability is lower than the first predetermined permeability, followed by returning to the filtration operation; followed by resuming the filtration operation;
performing a determination step including:
obtaining and comparing a previous initial permeability measured immediately after the second cleaning step performed previously and most recently, and a current initial permeability measured immediately after the second cleaning step performed this time; and
determining if a quotient obtained by dividing the current initial permeability by the previous initial permeability is lower than a predetermined ratio;

performing a third cleaning step for cleaning the filtration membrane using a third chemical solution different from the first and second chemical solutions, if the quotient obtained in the determination step is lower than the predetermined ratio, followed by returning to the filtration operation; and
returning to the filtration operation without performing the third cleaning step, if the quotient obtained in the determination step is not lower than the predetermined ratio.

10. The method for cleaning the filtration membrane according to claim 9 , wherein the second cleaning step includes changing the concentration of the second chemical solution and/or the cleaning time of the second cleaning step in accordance with a temperature of the liquid to be treated.

11. The method for cleaning the filtration membrane according to claim 10 , wherein in performing the second cleaning step, the concentration of the second chemical solution is decreased as the temperature of the liquid to be treated increases, and the concentration of the second chemical solution is increased as the temperature of the liquid to be treated decreases.

12. The method for cleaning the filtration membrane according to claim 10 , wherein in performing the second cleaning step, the cleaning time is decreased as the temperature of the liquid to be treated increases, and the cleaning time is increased as the temperature of the liquid to be treated decreases.

13. The method for cleaning the filtration membrane according to claim 9 , wherein the first chemical soluti

Assignees

• Kubota Kk

Inventors

• Okajima Yasunobu
• Kawashima Yuki
• Otsuka Yuji
• Morita Yukako
• Tanaka Ken

Classifications

• B01D2315/06

  Submerged-type; Immersion type · CPC title

• C02F2303/16

  Regeneration of sorbents, filters · CPC title

• B01D65/02 Primary

  Membrane cleaning or sterilisation {; Membrane regeneration} · CPC title

• B01D2311/14

  Pressure control · CPC title

• B01D65/06 Primary

  with special washing compositions · CPC title