Synthesis gas production process for the implementation of a natural gas liquefaction

Patent metadata

Field	Value
Publication number	US-11408672-B2
Application number	US-201716349691-A
Country	US
Kind code	B2
Filing date	Nov 14, 2017
Priority date	Nov 14, 2016
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

Natural gas liquefaction process in combination with a synthesis gas production process, where the steam derived from the synthesis gas production process is used as a heating source for the implementation of the pre-treatment step for eliminating the impurities liable to freeze during the natural gas liquefaction process.

First claim

The invention claimed is:

1. A process for the liquefaction of natural gas in combination with a process for the production of synthesis gas, the liquefaction process comprising the following stages:
Stage a): pretreatment of a feed natural gas in order to remove the impurities liable to freeze during the liquefaction process;
Stage b): extraction, from the gas stream resulting from stage a), of a stream enriched in hydrocarbons having more than two carbon atoms;
Stage c): liquefaction of the gas stream depleted in hydrocarbons having more than two carbon atoms resulting from stage b);
the process for the production of synthesis gas comprising the following stages:
Stage a′): desulfurization at a temperature of greater than 350° C. of a natural gas feed stream;
Stage b′): optional prereforming, at a temperature of greater than 500° C., in order to convert the hydrocarbon chains containing at least two carbon atoms of the gas stream resulting from stage a′) into methane;
Stage c′): reforming consisting in reacting, at a temperature of greater than 800° C., the gas stream resulting from stage a′) or b′) with steam in order to produce hydrogen, carbon dioxide and carbon monoxide;

wherein the steam resulting from the process for the production of synthesis gas is used as source of heating for the implementation of stage a); and wherein stage a) comprises a pretreatment by adsorption by means of an adsorption system comprising between two and five containers of at least one bed of adsorbent and at least one device for heating and/or cooling an adsorption and/or regeneration stream circulating in said adsorption system and wherein the steam resulting from the process for the production of synthesis gas is employed to reheat said regeneration stream.

2. The process as claimed in claim 1 , wherein the steam resulting from the process for the production of synthesis gas is employed to reheat the regeneration stream which has already passed through said adsorption system and to distance it from the dew point.

3. The process as claimed in claim 1 , wherein, during stage a′), all the sulfur-comprising derivatives present in the feed gas are converted into H 2 S by catalysis in a reactor.

4. The process as claimed in claim 3 , wherein the product H 2 S is extracted by catalysis.

5. The process as claimed in claim 1 , wherein the impurities liable to freeze during the liquefaction process which are removed during stage a) comprise the water, the carbon dioxide and the sulfur-comprising derivatives present in the feed gas.

6. The process as claimed in claim 1 , wherein, during stage c), the stream of natural gas depleted in hydrocarbons having more than two carbon atoms resulting from stage b) is liquefied at a temperature of less than −140° C. by means of a unit for the liquefaction of natural gas comprising at least one main heat exchanger and a system for producing cold.

7. The process as claimed in claim 1 , wherein the natural gas feed stream employed in stage a) and the natural gas feed stream employed in stage a′) originate from one and the same natural gas feed stream.

8. The process as claimed in claim 1 , wherein the unit for the production of synthesis gas is a unit for the production of hydrogen by steam reforming having a hydrogen production capacity of at least 20 000 Sm 3 /h.

Assignees

• Air Liquide

Inventors

• Costa De Beauregard Pierre
• Marty Pascal
• Morel Thomas

Classifications

• F25J2220/64

  Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general · CPC title

• F25J1/0229

  Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock · CPC title

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• B01D53/1493

  Selection of liquid materials for use as absorbents · CPC title

• C01B2203/80

  Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695 · CPC title