Method for sol-gel coating of textile materials

Patent metadata

Field	Value
Publication number	US-11408121-B2
Application number	US-201716341797-A
Country	US
Kind code	B2
Filing date	Oct 13, 2017
Priority date	Oct 14, 2016
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

The invention relates to a method for the coating of a textile material, said method comprising the following steps: d) providing a coating composition comprising an aqueous solvent and an organosilicon precursor; e) impregnating the textile material with the coating composition by means of pad finishing; f) drying the impregnated textile material; characterized in that the coating composition contains no polycarboxylic acid or catalyst.

First claim

The invention claimed is:

1. A method for coating a textile material with a sol-gel material, said method comprising the steps of:
a) providing a coating composition comprising an aqueous solvent and an organosilicon precursor,
b) impregnating the textile material with the coating composition by means of pad finishing,
c) drying the impregnated textile material,

characterized in that the coating composition contains no polycarboxylic acid or catalyst.

2. The method according to claim 1 , wherein the coating composition also contains no surfactant.

3. The method according to claim 1 , wherein the textile material is a woven fabric, a nonwoven fabric, or a knit, preferably a woven fabric.

4. The method according to claim 1 , wherein the textile material comprises fibers having hydrolysable functional groups, such as hydroxyl functional groups.

5. The method according to claim 1 , wherein the aqueous solvent is water or a mixture of water and an organic solvent.

6. The method according to claim 1 , wherein the organosilicon precursor is selected among tetramethoxysilane (TMOS), tetraethoxysilane (TEOS), methyl trimethoxysilane (MTM), methyl triethoxysilane (MTE), phenyltrimethoxysilane (PhTMOS), phenyltriethoxysilane (PhTEOS), a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane, a chloroalkylethoxysilane, an aminopropyltrimethoxysilane (APTES), aminopropyltriethoxysilane (APTMS), (3-glycidyloxypropyl)trimethoxysilane (GPTMOS), (3-glycidyloxypropyl) triethoxysilane (GPTEOS), and mixtures thereof preferably among tetramethoxysilane (TMOS), methyl trimethoxysilane (MTM), phenyltrimethoxysilane (PhTMOS), a fluoroalkyltrimethoxysilane, a chloroalkylmethoxysilane, an aminopropyltriethoxysilane (APTES), (3-glycidyloxypropyl) trimethoxysilane (GPTMOS), and mixtures thereof.

7. The method according to claim 6 , wherein the organosilicon precursor is tetramethoxysilane (TMOS).

8. The method according to claim 6 , wherein the organosilicon precursor is a mixture of tetramethoxysilane (TMOS) with one or more precursors selected among methyl trimethoxysilane (MTM), methyl triethoxysilane (MTE), phenyltrimethoxysilane (PhTMOS), phenyltriethoxysilane (PhTEOS), a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane (ClTMOS), a chloroalkylethoxysilane, an aminopropyltriethoxysilane (APTES), (3-glycidyloxypropyl) trimethoxysilane (GPTMOS), and mixtures thereof.

9. The method according to claim 8 , wherein the organosilicon precursor is a mixture of tetramethoxysilane (TMOS) with (3-glycidyloxypropyl) trimethoxysilane (GPTMOS).

10. The method according to claim 1 , wherein it comprises several successive cycles of impregnation by pad finishing.

11. The method according to claim 1 , wherein it comprises, before step b), a step of applying a precoating composition comprising an organic solvent and a zirconium alkoxide, said precoating composition containing no polycarboxylic acid or catalyst.

12. The method according to claim 1 , wherein it further comprises a step of immobilizing sol-gel pellets on at least one of the two sides of the impregnated textile material.

13. The method according to claim 12 , wherein the step of immobilizing the sol-gel pellets is carried out after the drying step c).

14. The method according to claim 12 , wherein it comprises, after the drying step c), the application of a second layer of textile material on the impregnated textile material.

15. The method according to claim 14 , wherein the second layer of textile material is secured to the impregnated textile material, in particular by stitching, welding, or gluing.

16. A coating composition, comprising an aqueous solvent and an organosilicon precursor, characterized in that it contains no polycarboxylic acid or catalyst.

17. The coating composition according to claim 16 , wherein the aqueous solvent is water or a mixture of water and an organic solvent.

18. The coating composition according to claim 16 , wherein the organosilicon precursor is selected among tetramethoxysilane (TMOS), tetraethoxysilane (TEOS), methyl trimethoxysilane (MTM), methyl triethoxysilane (MTE), phenyltrimethoxysilane (PhTMOS), phenyltriethoxysilane (PhTEOS), a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane, a chloroalkyltriethoxysilane, an aminopropyltriethoxysilane, (3-glycidyloxypropyl)trimethoxysilane (GPTMOS), and mixtures thereof; preferably among tetramethoxysilane (TMOS), methyl trimethoxysilane (MTM), phenyltrimethoxysilane (PhTMOS), a fluoroalkyltrimethoxysilane, a fluoroalkyltriethoxysilane, a chloroalkylmethoxysilane, an aminopropyltriethoxysilane, (3-glycidyloxypropyl) trimethoxysilane (GPTMOS), and mixtures thereof.

19. The coating composition according to claim 18 , wherein the organosilicon precursor is tetramethoxysilane (TMOS).

20. The coating composition according to claim 18 , wherein the organosilicon precursor is a mixture of tetramethoxysilane (TMOS) with a precursor selected among methyl trimethoxysilane (MTM), methyl triethoxysilane (MTE), phenyltrimethoxysilane (PhTMOS), phenyltriethoxysilane (PhTEOS), fluoroalkyltrimethoxysilane, fluoroalkyltriethoxysilane, chloroalkylmethoxysilane, chloroalkyltriethoxysilane, aminopropyltriethoxysilane, (3-glycidyloxypropyl)trimethoxysilane (GPTMOS), and mixtures thereof.

21. The coating composition according to claim 20 , wherein the organosilicon precursor is a mixture of tetramethoxysilane (TMOS) with (3-glycidyloxypropyl) trimethoxysilane (GPTMOS).

22. The coating composition according to claim 20 , wherein the organosilicon precursor is a mixture of tetramethoxysilane (TMOS) with phenyltrimethoxysilane (PhTMOS).

23. An impregnated textile material obtained using the coating method according to claim 1 .

24. The impregnated textile material according to claim 23 , wherein the sol-gel material forms a sheathing around the fibers of the textile material.

25. The impregnated textile material according to claim 23 , wherein it has a specific surface area S BET , determined from adsorption isotherms using the Brunauer, Emmet and Teller (BET) model, between 330±30 and 880±30 m 2 ·g −1 , in particular between 540±30 and 880±30 m 2 ·g −1 .

26. The impregnated textile material according to claim 23 , wherein it has a micropore proportion greater than 0%, preferably greater than 30%, and even more preferably greater than 50%.

27. The impregnated textile material according to claim 23 , wherein it has a mesopore proportion of less than 100%, preferably less than 70%, and even more preferably less than 50%.

28. The impregnated textile material according to claim 23 , wherein it has a mass per unit area of 1 to 500 g/m 2 , preferably from 5 to 400 g/m 2 , more preferably from 10 to 300 g/m 2 .

29. The impregnated textile material according to claim 23 , wherein it further comprises sol-gel pellets immobilized on at least one of its sides.

30. The impregnated textile material according to claim 29 , wherein it has a mass per unit area of 60 to 500 g/m 2 , preferably 80 to 400 g/m 2 , and more preferably from 100 to 300 g/m 2 .

31. A gas filter, comprising the impregnated textile material according to claim 23 .

32. A personal protective equipment, comprising the impregnated textile material acco

Assignees

• Commissariat Energie Atomique
• Centre Nat Rech Scient
• Safran Electronics & Defense
• Europrotect France Sa
• Centre National De La Rech Scientifique—Cnrs—

Inventors

• Tran-Thi Thu-Hoa
• Grinenval Eva
• Charton Philippe
• Tirard Franck
• Chatard Sebastien

Classifications

• D06M2200/11

  Oleophobic properties · CPC title

• D06M2101/06

  cellulosic · CPC title

• A41D13/00

  Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches (helmets A42B3/00; clothing affording protection against chemical agents or for use at high altitudes A62B17/00; life-saving garments for use at sea, diving suits B63C; bulletproof or armoured clothing F41H; clothing affording protection against radiation G21F3/02) · CPC title

• C09D183/06

  containing silicon bound to oxygen-containing groups (C09D183/12 takes precedence) · CPC title

• D06M13/507 Primary

  Organic silicon compounds without carbon-silicon bond · CPC title