Method for producing methanol in a reactor with bypass

Patent metadata

Field	Value
Publication number	US-11407702-B2
Application number	US-201917261235-A
Country	US
Kind code	B2
Filing date	Jul 11, 2019
Priority date	Aug 17, 2018
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

A method for producing methanol comprises the steps of passing a feed stream of methanol synthesis pas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol, cooling the mixed gas containing methanol, separating methanol from the mixed pas and heating the mixed gas. The stream of heated mixed gas is passed through an additional methanol reactor containing a methanol synthesis catalyst, and the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor.

First claim

The invention claimed is:

1. A method for producing methanol, comprising the steps of
(a) passing a feed stream of methanol synthesis gas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol,
(b) cooling the mixed gas containing methanol,
(c) separating methanol from the mixed gas and
(d) heating the mixed gas, wherein
the stream of heated mixed gas from step (d) is passed through an additional methanol reactor containing a methanol synthesis catalyst,
the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor,
either the main methanol reactor or the additional methanol reactor comprises a tube sheet.

2. The method according to claim 1 , wherein the main methanol reactor is a boiling water reactor (BWR).

3. The method according to claim 2 , wherein an adiabatic catalyst layer is placed on top of the tube sheet.

4. The method according to claim 3 , wherein the main methanol reactor comprises the tube sheet.

5. The method according to claim 3 , wherein the additional methanol reactor comprises the tube sheet.

6. The method according to claim 1 , wherein each of the main methanol reactor and the additional methanol reactor comprises a tube sheet.

7. The method according to claim 3 , wherein each of the main methanol reactor and the additional methanol reactor comprises a tube sheet.

8. The method according to claim 1 , wherein the feed stream of methanol synthesis gas is split into a first stream and a second stream before reaching the main methanol reactor.

9. The method according to claim 8 , wherein the first stream is sent to the main methanol reactor via a throttle valve, and the second stream is sent to the additional methanol reactor after passing a feed/effluent heat exchanger.

10. The method according to claim 1 , wherein effluent from the main methanol reactor is cooled in a loop air cooler and a loop water cooler before being fed to a separator in which liquid methanol product is separated from the gas phase.

11. The method according to claim 10 , wherein, the gas phase leaving the separator is mixed with fresh feed gas and then passed to the additional methanol reactor.

12. The method according to claim 1 , wherein the feed stream of methanol synthesis gas is split into a first stream and a second stream before reaching the main methanol reactor,
wherein the first stream is sent to the main methanol reactor via a throttle valve, and the second stream is sent to the additional methanol reactor after passing a feed/effluent heat exchanger,
wherein effluent from the main methanol reactor is cooled in a loop air cooler and a loop water cooler before being fed to a separator in which liquid methanol product is separated from the gas phase, and
wherein, the gas phase leaving the separator is mixed with fresh feed gas and then passed to the additional methanol reactor.

Assignees

• Haldor Topsoe As

Inventors

• Tjärnehov Emil Andreas
• Dahl Per Juul

Classifications

• C07C31/04

  Methanol · CPC title

• C07C29/152 Primary

  characterised by the reactor used · CPC title

• C07C29/151 Primary

  with hydrogen or hydrogen-containing gases · CPC title

• C07C29/1518

  one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title