Synthesis method for highly selective 2-methylallyl chloride and synthesis reactor thereof

Patent metadata

Field	Value
Publication number	US-11407698-B2
Application number	US-201816759931-A
Country	US
Kind code	B2
Filing date	Oct 10, 2018
Priority date	Jan 29, 2018
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

The present invention relates to a synthesis method and synthesis reactor of high-selectivity 2-methylallyl chloride by taking isobutylene and chlorine gas as raw materials and performing a gas-phase chlorination reaction in a microchannel reactor with a cooling surface. The isobutylene and the chlorine gas are reacted in a T-shaped microchannel reactor, and the mixing speed is extremely fast. Meanwhile, the huge heat exchange area per unit volume can ensure that the reaction proceeds stably at a substantially constant temperature and has good controllability. Therefore, side reactions caused by excessive local temperature can be effectively suppressed, the reaction selectivity is high, and no coking phenomenon occurs.

First claim

The invention claimed is:

1. A synthesis reactor assembly for producing high-selectivity 2-methyl-3-chloroallyl, comprising:
an isobutylene supply having isobutylene;
a chlorine gas supply having chlorine gas;
a plurality of synthesis reactors arranged side-by-side, each synthesis reactor comprising:
a synthesis reaction tube fluidly coupled with an isobutylene inlet tube configured to receive the isobutylene from the isobutylene supply and fluidly coupled with a chlorine gas inlet tube configured to receive chlorine gas from the chlorine gas supply;
wherein the isobutylene inlet tube, the chlorine gas inlet tube, and the synthesis reaction tube are connected in tee form;
wherein the isobutylene inlet tube and the chlorine gas inlet tube are in a U-shape, and an upper end of the synthesis reaction tube is connected to the U-shape to form the tee form; and
wherein the isobutylene inlet tube, the chlorine gas inlet tube, and the synthesis reaction tube have a diameter of 0.2-0.5 mm, respectively;

a cooling jacket wrapped around the plurality of synthesis reactors arranged side-by-side; and
a cooling surface of each synthesis reactor has a heat exchange area of 8000-20000 m 2 /m 3 based on an actual reaction volume of each synthesis reactor.

2. The synthesis reactor assembly for producing high-selectivity 2-methyl-3-chloroallyl of claim 1 , comprising:
isobutylene in each isobutylene inlet tube; and
chlorine gas in each chlorine gas inlet tube.

3. A method for synthesizing high-selectivity 2-methyl-3-chloroallyl, comprising:
providing the synthesis reactor assembly of claim 1 ;
feeding isobutylene from the isobutylene supply through each isobutylene inlet tube and chlorine gas from the chlorine gas supply through each chlorine gas inlet tube;
mixing the isobutylene and the chlorine gas at each tee form to produce a mixture of isobutylene and chlorine gas; and
performing a gas-phase chlorination reaction of the mixture of isobutylene and chlorine gas in each synthesis reaction tube to produce 2-methyl-3-chloroallyl.

4. The method according to claim 3 , wherein an excess amount of isobutylene is added in the chlorination reaction.

5. The method according to claim 4 , wherein a molar ratio of the isobutylene to the chlorine gas is 1.005˜1.02:1.

6. The method according to claim 3 , wherein the chlorination reaction temperature is 0˜30° C. and the chlorination reaction residence time is 0.1˜1 second.

Assignees

• Univ Zhejiang
• Zhejiang Huangma Tech Co Ltd

Inventors

• Yin Hong
• Chen Zhirong
• Wang Xinrong
• Wang Weisong
• Yu Yuanrong
• Wang Shengli
• Wang Yuefen
• Ma Zhenqiang
• Zhao Xingjun
• Qian Jianfang

Classifications

• B01J2219/00873

  Heat exchange · CPC title

• B01J19/2415

  Tubular reactors · CPC title

• B01J2219/00792

  One or more tube-shaped elements · CPC title

• C07C17/10 Primary

  of hydrogen atoms (combined with addition of halogens to unsaturated hydrocarbons C07C17/06) · CPC title

• B01J2219/00247

  Fouling of the reactor or the process equipment · CPC title