Method for decomposing byproducts in phenol production process

Patent metadata

Field	Value
Publication number	US-11407694-B2
Application number	US-201816478802-A
Country	US
Kind code	B2
Filing date	Aug 17, 2018
Priority date	Nov 20, 2017
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

In a process of decomposing byproducts of a phenol production process using a reactive distillation column in which a reactor and a distillation column are integrated, since acetophenone is mixed with tar recovered to a lower part of the reactive distillation column and transferred, viscosity of the tar may be lowered so that the tar may be transferred at room temperature, and since the reactive distillation column may be operated at 0.5 to 3 bar, an operating temperature of the reactive distillation column is low as compared with a method of separating acetophenone by pressurization with high pressure, significantly reducing an operation cost of a heater required for a reaction. Also, since acetophenone is separately recovered at a position of 25 to 90% of a total number of stages in the reactive distillation column, recovery of an active ingredient may be enhanced.

First claim

The invention claimed is:

1. A method for decomposing phenol byproducts produced in a phenol production process, the method comprising:
supplying the phenol byproducts to a reactive distillation column to perform a decomposition reaction;
recovering tar from a lower part of the reactive distillation column;
recovering acetophenone from a middle portion of a side part of the reactive distillation column;
mixing the recovered acetophenone with the recovered tar at room temperature at a mixing ratio of 1:0.3 to 1:0.9 to form a mixed stream of the recovered tar and the recovered acetophenone; and
recovering an active ingredient from an upper part of the reactive distillation column.

2. The method of claim 1 , wherein the reactive distillation column is operated at 0.5 to 3 bar.

3. The method of claim 1 , further comprising:
exchanging heat between the phenol byproducts supplied to the reactive distillation column and the mixed stream of the recovered tar and the recovered acetophenone to heat the phenol byproducts.

4. The method of claim 1 , wherein the active ingredient comprises phenol, alpha-methylstyrene, and cumene.

5. An apparatus for decomposing phenol byproducts, the apparatus comprising:
a phenol byproduct supply part for supplying phenol byproducts of a phenol production process to a reactive distillation column;
a tar recovery part provided at a lower part of the reactive distillation column to recover tar;
a tar transfer line to transfer tar recovered from the tar recovery part;
an acetophenone recovery line provided at a middle part of a side of the reactive distillation column;
an acetophenone transfer line connected to the tar transfer line to mix the acetophenone recovered from the acetophenone recovery line with the recovered tar; and
an active ingredient recovery part provided at an upper part of the reactive distillation column.

6. The apparatus of claim 5 , wherein the acetophenone recovery line is positioned at 25 to 90% of a total number of stages of the reactive distillation column.

7. The apparatus of claim 5 , further comprising:
a heat exchanger for exchanging heat between a mixed stream of the recovered tar and acetophenone and the phenol byproducts.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Min Suk
• Lee Sang Beom
• Lee Sung Ho
• Shin Joon Ho
• Park Chul Han

Classifications

• C07C1/20 Primary

  starting from organic compounds containing only oxygen atoms as heteroatoms · CPC title

• C07C37/52

  by splitting polyaromatic compounds, e.g. polyphenolalkanes · CPC title

• C07C45/82

  by distillation · CPC title

• C07C15/44

  the hydrocarbon substituent containing a carbon-to-carbon double bond · CPC title

• C07C39/04

  Phenol · CPC title