Optical fiber article, its production and use

Patent metadata

Field	Value
Publication number	US-11406248-B2
Application number	US-202017038486-A
Country	US
Kind code	B2
Filing date	Sep 30, 2020
Priority date	Sep 30, 2019
Publication date	Aug 9, 2022
Grant date	Aug 9, 2022

Abstract

The present disclosure relates to an optical fiber article and a method for the production of the optical fiber article. The present disclosure in particular relates to the use of the optical fiber article in a fiber bundle as light guide and/or image guide, for example in an endoscope.

First claim

What is claimed is:

1. An optical fiber article, comprising:
an optical fiber; and
a functional layer on the surface of the optical fiber,
wherein the functional layer comprises at least one functional silane having the following structural formula:

wherein Z is a branched or unbranched alkyl group or aryl group with 1 to 18 carbon atoms,
wherein R1, R2 and R3 are independently selected from hydrogen, oxygen, alkyl, alkyloxy, hydroxyalkyl and hydroxyl, and wherein one, two or three of the groups R1, R2 or R3 is connected to the surface of the optical fiber directly or indirectly via a covalent bond,
wherein R4 is selected from —NH 2 , —NHR′, —NR′R″, glycidyloxy and —SH, wherein R′ and R″ are independently selected from alkyl, aminoalkyl, hydroxyalkyl and —(CH 2 ) m NH 2 , wherein m is 1 to 6, and
wherein the functional layer is a dry functional layer that comprises less than 35% by weight of a liquid component having a boiling point at 1013 hPa of higher than 100° C.

2. The optical fiber article according to claim 1 , wherein the photopolymerized polymers are present in an amount that is less than 1% by weight, based on the weight of the functional layer.

3. The optical fiber article according to claim 1 , wherein the polyacrylates, polymethacrylates, polyvinyl polymers, polystyrene and/or derivatives thereof in the functional layer are present in an amount that is less than 1% by weight, based on the weight of the functional layer.

4. The optical fiber article according to claim 1 , wherein the optical fiber article comprises less than 500 ppm (m/m) of a halide.

5. The optical fiber article according to claim 1 , wherein the functional layer comprises at least one fatty acid.

6. The optical fiber article according to claim 1 , wherein the optical fiber has a bending radius of less than 10 mm when measured in the breaking-loop test according to DIN 58141-6:2011.

7. The optical fiber article according to claim 1 , wherein the optical fiber article has a press force of at least 250 N.

8. The optical fiber article according to claim 1 , wherein the optical fiber article is biocompatible according to at least one of ISO10993-1:2018, USP Class VI, and ISO10993-5:2009.

9. The optical fiber article according to claim 1 , wherein the functional layer comprises at least one of an alkylsilane and a polyethylene glycol silane, covalently bound to the surface of the fiber.

10. The optical fiber article according to claim 1 , wherein R4 is —NHR′; wherein R′ is —(CH 2 ) m NH 2 , wherein m=2, and wherein Z is an unbranched alkyl group with 1 to 10 carbon atoms, preferably of 3 to 8 carbon atoms.

11. The optical fiber article according to claim 1 , wherein the functional layer comprises a polyalkylene oxide.

12. The optical fiber article according to claim 1 , wherein the optical fiber comprises a fiber core and a cladding and the functional layer is on a surface of the cladding.

13. The optical fiber article according to claim 1 , wherein the optical fiber comprises a fiber core and/or cladding made of a multicomponent glass.

14. The optical fiber article according to claim 1 , wherein the functional silane has formed a reaction product with one or more adhesives at least partially.

15. A light guide comprising the optical fiber article according to claim 1 .

16. A method for the production of an optical fiber article according to claim 1 , comprising the steps of:
a. providing at least one optical fiber;
b. coating at least a part of the optical fiber with a size; and
c. drying the size.

17. The method according to claim 16 , further comprising the step of treating the dried size with a liquid component to obtain a wet size, wherein the liquid component has a boiling point at 1013 hPa of higher than 100° C.

18. The method according to claim 17 , wherein the liquid component is selected from the group consisting of silicone oil, polyethylene glycol, alcohols, esters, ethers, ketones, acetates, and combinations thereof.

19. A method for the production of an optical fiber article, wherein the optical fiber article comprises:
an optical fiber; and
a functional layer on the surface of the optical fiber,
wherein the functional layer comprises at least one functional silane having the following structural formula:

wherein Z is a branched or unbranched alkyl group or aryl group with 1 to 18 carbon atoms,
wherein R1, R2 and R3 are independently selected from hydrogen, oxygen, alkyl, alkyloxy, hydroxyalkyl and hydroxyl, and wherein one, two or three of the groups R1, R2 or R3 is connected to the surface of the optical fiber directly or indirectly via a covalent bond, and
wherein R4 is selected from —NH 2 , —NHR′, —NR′R″, glycidyloxy and —SH, wherein R′ and R″ are independently selected from alkyl, aminoalkyl, hydroxyalkyl and —(CH 2 ) m NH 2 , wherein m is 1 to 6,
wherein the method comprises the steps of:
a. providing at least one optical fiber;
b. coating at least a part of the optical fiber with a size; and
c. drying the size; and
d. treating the dried size with a liquid component to obtain a wet size, wherein the liquid component has a boiling point at 1013 hPa of higher than 100° C.

20. The method according to claim 19 , wherein the liquid component is selected from the group consisting of silicone oil, polyethylene glycol, alcohols, esters, ethers, ketones, acetates, and combinations thereof.

Assignees

• Schott Ag

Inventors

• Mangold Stephanie
• Weingärtner Thomas
• Fratzer Oliver

Classifications

• G02B6/02395

  Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104) · CPC title

• C03C3/078

  containing an oxide of a divalent metal, e.g. an oxide of zinc · CPC title

• G02B6/06

  the relative position of the fibres being the same at both ends, e.g. for transporting images · CPC title

• C03C25/255

  Oils, waxes, fats or derivatives thereof · CPC title

• A61B1/0017 Primary

  Details of single optical fibres, e.g. material or cladding · CPC title