High-strength A356 alloy and preparation method thereof

Patent metadata

Field	Value
Publication number	US-11401586-B2
Application number	US-201916693896-A
Country	US
Kind code	B2
Filing date	Nov 25, 2019
Priority date	Mar 22, 2019
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A high-strength A356 alloy and a preparation method thereof are disclosed. Modifiers Ba and Zr are added to improve the as-cast structure of the alloy. The high-pressure solidified A356 alloy prepared by a high-pressure solidification technology has finer grains, and the elements such as Mg and Si have higher supersaturated solubility in a matrix.

First claim

The invention claimed is:

1. A preparation method of an A356 alloy, the A356 alloy being prepared from the following components in percentage by mass: 6.5 to 7.5 percent of Si, 0.3 to 0.5 percent of Mg, 0.05 to 0.1 percent of Cu, 0.05 to 0.2 percent of Ti, 0.1 to 0.5 percent of Ba, 0.5 to 1.5 percent of Zr, less than or equal to 0.15 percent of impurity elements and a balance Al, wherein the preparation method comprises the following steps:
(1) taking an A356 aluminum ingot, a pure Mg ingot, an Al-Ba intermediate alloy and an Al-Zr intermediate alloy as raw materials, and calculating desired mass of each of the raw materials according to components of a target alloy;
(2) preheating the raw materials in Step (1) at 300 DEG C;
(3) setting heating temperature of a crucible resistance furnace as 720 to 780 DEG C; adding the A356 aluminum ingot when a temperature of a crucible reaches 300 to 350 DEG C; adding the Al-Ba intermediate alloy and the Al-Zr intermediate alloy in sequence when the A356 aluminum ingot is completely melted and the temperature of the crucible reaches 600 to 650 DEG C; adding a C 2 Cl 6 refining agent after the raw materials are completely melted, and slightly stirring the mixture; removing dross from a surface of a metal melt when the temperature of the crucible resistance furnace reaches 720 to 780 DEG C, preserving the heat for 15 to 30 min, and then pouring the metal melt into a preheated metal mold to obtain a desired A356 as-cast alloy;
(4) performing high-pressure solidification on the A356 as-cast alloy obtained in Step (3): setting solidification pressure as 2 to 5 GPa, at the same time, heating the A356 as-cast alloy to 750 to 850 DEG C, preserving the heat and the pressure at this temperature for 15 to 20 min, turning off a power supply to stop heating, performing pressure relief after the A356 as-cast alloy is cooled to room temperature, and taking out the A356 as-cast alloy to obtain a further refined high-pressure solidified A356 alloy; and
(5) aging the high-pressure solidified A356 alloy obtained in Step (4) at 150 to 200 DEG C for 2 to 100 h to finally obtain the A356 alloy,
wherein the A356 alloy has a maximum compressive strength of 371 Mpa.

2. A preparation method of an A356 alloy, the A356 alloy being prepared from the following components in percentage by mass: 7 percent of Si, 0.35 percent of Mg, 0.05 percent of Cu, 0.08 percent of Ti, 0.3 percent of Ba, 0.6 percent of Zr, less than or equal to 0.15 percent of impurity elements and a balance Al, wherein the preparation method comprises-the following steps:
(1) taking an A356 aluminum ingot, a pure Mg ingot, an Al-Ba intermediate alloy and an Al-Zr intermediate alloy as raw materials, and calculating desired mass of each of the raw materials according to components of a target alloy;
(2) preheating the raw materials in Step (1) at 300 DEG C;
(3) setting heating temperature of a crucible resistance furnace as 720 to 780 DEG C; adding the A356 aluminum ingot when a temperature of a crucible reaches 300 to 350 DEG C; adding the Al-Ba intermediate alloy and the Al-Zr intermediate alloy in sequence when the A356 aluminum ingot is completely melted and the temperature of the crucible reaches 600 to 650 DEG C; adding a C 2 Cl 6 refining agent after the raw materials are completely melted, and slightly stirring the mixture; removing dross from a surface of a metal melt when the temperature of the crucible resistance furnace reaches 720 to 780 DEG C, preserving the heat for 15 to 30 min, and then pouring the metal melt into a preheated metal mold to obtain a desired A356 as-cast alloy;
(4) performing high-pressure solidification on the A356 as-cast alloy obtained in Step (3): setting solidification pressure as 2 to 5 GPa, at the same time, heating the A356 as-cast alloy to 750 to 850 DEG C, preserving the heat and the pressure at this temperature for 15 to 20 min, turning off a power supply to stop heating, performing pressure relief after the A356 as-cast alloy is cooled to room temperature, and taking out the A356 as-cast alloy to obtain a further refined high-pressure solidified A356 alloy; and
(5) aging the high-pressure solidified A356 alloy obtained in Step (4) at 150 to 200 DEG C for 2 to 100 h to finally obtain the high strength A356 alloy,
wherein the A356 alloy has a maximum compressive strength of 371 Mpa.

Assignees

• Citic Dicastal Co Ltd

Inventors

• Fu Shoujun
• Liu Jinwei
• Wang Chunwei
• Sun Haichao
• Liu Huiying

Classifications

• C22F1/043

  of alloys with silicon as the next major constituent · CPC title

• C22C21/04 Primary

  Modified aluminium-silicon alloys · CPC title