Aluminium or copper-carbon nanotube composite material and method for preparing same

Patent metadata

Field	Value
Publication number	US-11401583-B2
Application number	US-201716470474-A
Country	US
Kind code	B2
Filing date	Dec 14, 2017
Priority date	Dec 22, 2016
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

The present invention relates to a composite material based on aluminium or copper and tin oxide-functionalized carbon nanotubes, to the method for producing same and to a cable comprising said composite material as the electrically conductive element.

First claim

The invention claimed is:

1. A composite material comprising:
a metal matrix of aluminium, copper, aluminium alloy or copper alloy, and tin oxide-functionalized carbon nanotubes dispersed in said metal matrix.

2. The composite material according to claim 1 , wherein said composite material comprises from 0.1 to 10% by mass of tin oxide-functionalized carbon nanotubes, relative to the total mass of the composite material.

3. The composite material according to claim 1 , wherein said composite material has an electrical conductivity of at least 50% IACS.

4. The composite material according to claim 1 , wherein said composite material has a tensile strength of between 100 and 1000 MPa.

5. A method for preparing the composite material as claimed in claim 1 , wherein said method comprises at least the following steps:
i) bringing the tin oxide-functionalized carbon nanotubes into contact with a metal chosen from among aluminium, copper, an aluminium alloy and a copper alloy,
ii) mixing the tin oxide-functionalized carbon nanotubes with the metal in order to disperse them homogeneously in the molten metal, and
iii) forming a solid mass.

6. The method according to claim 5 , wherein said metal is in the molten state.

7. The method according to claim 6 , wherein step i) is carried out by bringing at least one metal container made of aluminium, copper, aluminium alloy or copper alloy comprising tin oxide-functionalized carbon nanotubes into contact with said molten metal, said metal container comprising at least one opening intended to receive the tin oxide-functionalized carbon nanotubes and said opening being closed by a closure element that is able to melt, dissolve or detach from the metal container when said metal container is brought into contact with the molten metal.

8. The method according to claim 7 , wherein step i) is carried out by introducing or injecting at least one metal container as defined in claim 7 into a liquid metal bath, said bath being at a sufficiently high temperature to cause the closure element of said container to melt, dissolve or detach, and to melt said metal container.

9. The method according to claim 8 , wherein the sufficiently high temperature of step i) is between 550 and 1200° C.

10. The method according to claim 7 , wherein the closure element is one or more nanometric filters made of paper.

11. The method according to claim 6 , wherein step iii) is carried out by casting the mixture of the preceding step ii) to form said composite material.

12. The method according to claim 5 , wherein said method further comprises a step i 0 ) of preparing the tin oxide-functionalized carbon nanotubes, comprising the following sub-steps:
possibly a sub-step i 01 ) of functionalizing carbon nanotubes with appropriate chemical groups which may represent sites of attachment between the carbon nanotubes and the tin oxide,
a sub-step i 02 ) of bringing the commercial functionalized carbon nanotubes, or the functionalized carbon nanotubes as prepared in the preceding sub-step if such a sub-step exists, into contact with a tin precursor, and
a sub-step i 03 ) of heating.

13. The method according to claim 12 , wherein sub-step i 01 ) is carried out by acid treatment of the carbon nanotubes with sulfuric acid.

14. The method according to claim 12 , wherein the tin precursor is tin sulfate.

15. A composite material, wherein said composite material comprises a metal matrix of aluminium, copper, aluminium alloy or copper alloy, and tin oxide-functionalized carbon nanotubes dispersed in said metal matrix, and wherein said composite material is obtained according to the method as defined in claim 5 .

16. An electrical cable, wherein said electrical cable comprises at least one composite material as defined in claim 1 .

17. The cable according to claim 16 , wherein said cable is an OHL cable comprising an elongate reinforcing element and an assembly of composite strands positioned around the elongate reinforcing element.

18. The cable according to claim 16 , wherein said cable comprises at least one electrically insulating layer surrounding said composite material or the plurality of composite materials, said electrically insulating layer comprising at least one polymer material.

19. The cable according to claim 16 , wherein each one of the composite strands is a composite material comprising a metal matrix of aluminium, copper, aluminium alloy or copper alloy, and tin oxide-functionalized carbon nanotubes dispersed in said metal matrix.

20. The composite material according to claim 1 , wherein said composite material comprises from 0.25 to 5% by mass of tin oxide-functionalized carbon nanotubes, relative to the total mass of the composite material.

21. The composite material according to claim 1 , wherein said composite material has a tensile strength of between 110 and 600 MPa.

22. The composite material according to claim 1 , wherein the tin oxide-functionalized carbon nanotubes are uniformly dispersed within the metal matrix of aluminium, copper, aluminium alloy or copper alloy.

Assignees

• Nexans

Inventors

• Hiouani Thomas
• Royes Paul
• Masquelier Nicolas

Classifications

• C22C1/1036 Primary

  starting from a melt · CPC title

• C22C1/1047

  by mixing and casting liquid metal matrix composites · CPC title

• C22C21/00 Primary

  Alloys based on aluminium · CPC title

• C01B32/174

  Derivatisation; Solubilisation; Dispersion in solvents · CPC title

• C01B2202/00

  Structure or properties of carbon nanotubes · CPC title