Method of preparing laminated article

Patent metadata

Field	Value
Publication number	US-11401434-B2
Application number	US-201916551942-A
Country	US
Kind code	B2
Filing date	Aug 27, 2019
Priority date	Aug 27, 2019
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A flexible inkjet-printed article is prepared by: A′) providing an ink receptive medium having a substrate and an aqueous-based ink-receptive layer. This layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. At least one aqueous pigment-based ink is deposited directly on the aqueous-based ink-receptive layer, each having: a) an anionically-stabilized pigment colorant; and b) a water-miscible humectant at 1-20 weight %, each having a carbon to oxygen atom ratio of ≥1.0:1.0 and only two hydroxy groups. After drying, a functional layer with adhesive composition is formed on the inkjet-printed image and a flexible material is laminated to the functional layer, to form a flexible inkjet printed article.

First claim

The invention claimed is:

1. A method for making a flexible inkjet-printed article, the method comprising, in order:
A) providing an ink receptive medium comprising a substrate and an aqueous-based ink-receptive layer disposed thereon, which aqueous-based ink-receptive layer has an outer surface, and comprises:
(a) one or more water-soluble salts of a multivalent metal cation in an amount of at least 0.6 weight % and up to and including 49 weight %;
(b) one or both of a polyvinyl alcohol and a polyvinyl amine, or a copolymer derived from a vinyl alcohol and a vinyl amine, in a total amount of at least 0.5 weight % and up to and including 30 weight %;
optionally, (c) a crosslinking agent in an amount of at least 0.01 weight % and up to and including 5 weight %; and
optionally, (d) silica particles in an amount of up to and including 30 weight %,
all amounts being based on the total weight of the aqueous-based ink-receptive layer; and

B) depositing directly on the outer surface of the aqueous-based ink-receptive layer, one or more aqueous pigment-based inks,
each aqueous pigment-based ink having at least 75 weight % and up to and including 95 weight % of water, and comprising:
a) one or more anionically-stabilized pigment colorants;
b) one or more water-miscible humectants in a total amount of at least 1 weight % and up to and including 20 weight %, and consisting essentially of compounds, each of which has a carbon atom to oxygen atom ratio of at least 1.0:1.0 and only two hydroxy groups;
and optionally,
c) an acidic polymer that is an anionic polyurethane, an acidic acrylic polymer, an acidic styrene-acrylic polymer, or any combination of these materials, each acidic polymer having an acid number of at least 50 and up to and including 240, and each acidic polymer being neutralized with sufficient base to render it dispersible or soluble in each aqueous pigment-based ink,

C) drying the one or more aqueous pigment-based inks to remove substantially all water to form an inkjet-printed image;
D) forming a functional layer comprising an adhesive composition on the inkjet-printed image; and
E) adhering a flexible polymeric film or paper to the functional layer, to form the flexible inkjet printed article.

2. The method of claim 1 , wherein the adhesive composition comprises a water-based polyurethane resin.

3. The method of claim 1 , wherein the adhesive composition comprises a solvent-based polyurethane resin.

4. The method of claim 1 , wherein the adhesive composition comprises a solventless polyurethane resin.

5. The method of claim 1 , wherein the adhesive composition is provided on the flexible polymeric film or paper.

6. The method of claim 1 , wherein the flexible polymeric film is a water-impermeable film composed of a polyester, polyimide, polycarbonate, polystyrene, polyolefin, polyurethane, polyvinyl chloride, polyvinylidene chloride, or a mixture of two or more of these materials.

7. The method of claim 1 , wherein the flexible polymeric film or paper is adhered to the functional layer with a lamination bond strength greater than 1.0 N/cm.

8. The method of claim 1 , further comprising, before step A′, treating the substrate to increase its surface energy to at least 45 dyne/cm.

9. The method of claim 1 , wherein the flexible polymeric film is an opaque, transparent, or metallized flexible polymeric film.

10. The method of claim 1 , wherein the b) one or more water-miscible humectants consist essentially of compounds, each of which has a carbon atom to oxygen atom ratio of at least 1.0:1.0 and up to and including 2.7:1.0.

11. The method of claim 1 , wherein the b) one or more water-miscible humectants consists essentially of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 2,3-butanediol, 1,2-pentanediol, 2.3-pentanediol, 1,3-pentanediol, 2-(2-hydroxyethoxy)ethanol, 2-[2-(2-hydroxyethoxy)ethoxy]ethanol, or a combination of two or more of these compounds.

12. The method of claim 1 , wherein 50% of the volume of each of the a) one or more pigment colorants in each aqueous pigment-based ink is provided by pigment colorant particles having a diameter of less than 100 nm, and 95% of the volume of each of the a) one or more pigment colorants is provided by pigment colorant particles having a diameter of less than 150 nm, the particle size diameters being measured using a dynamic light scattering particle sizing instrument.

13. The method of claim 1 , wherein at least one of the one or more aqueous pigment-based inks is an aqueous cyan pigment-based ink that comprises one or more anionically-stabilized cyan pigment colorants, and the b) one or more water-miscible humectants consist essentially of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 2,3-butanediol, 1,2-pentanediol, 2.3-pentanediol, 1,3-pentanediol, 2-(2-hydroxyethoxy)ethanol, 2-[2-(2-hydroxyethoxy)ethoxy]ethanol, or a combination of two or more of these compounds, in a total amount of at least 4 weight % and up to and including 8 weight %, based on the total weight of the aqueous cyan pigment-based ink.

14. The method of claim 1 , wherein at least one of the one or more aqueous pigment-based inks is an aqueous magenta pigment-based ink that comprises one or more anionically-stabilized magenta pigment colorants, and the b) one or more water-miscible humectants consist essentially of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 2,3-butanediol, 1,2-pentanediol, 2.3-pentanedial, 1,3-pentanediol, 2-(2-hydroxyethoxy)ethanol, 2-[2-(2-hydroxyethoxy)ethoxy]ethanol, or a combination of two or more of these compounds, in a total amount of at least 4 weight % and up to and including 8 weight %, based on the total weight of the aqueous magenta pigment-based ink.

15. The method of claim 1 , wherein at least one of the one or more different aqueous pigment-based inks is an aqueous yellow pigment-based ink that comprises one or more anionically-stabilized yellow pigment colorants, and the b) one or more water-miscible humectants consist essentially of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 2,3-butanediol, 1,2-pentanediol, 2.3-pentanediol, 1,3-pentanediol, 2-(2-hydroxyethoxy)ethanol, 2-[2-(2-hydroxyethoxy)ethoxy]ethanol, or a combination of two or more of these compounds, in a total amount of at least 4 weight % and up to and including 8 weight %, based on the total weight of the aqueous yellow pigment-based ink.

16. The method of claim 1 , wherein at least one of the one or more aqueous pigment-based inks is an aqueous black pigment-based ink that comprises one or more anionically-stabilized yellow pigment colorants, and the b) one or more water-miscible humectants consist essentially of 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,2-butanediol, 1,3-butanediol, 2,3-butanediol, 1,2-pentanediol, 2.3-pentanediol, 1,3-pentanediol, 2-(2-hydroxyethoxy)ethanol, 2-[2-(2-hydroxyethoxy)ethoxy]ethanol, or a combination of two or more of these compounds, in a total amount of at least 5 weight % and up to and including 10 weight %, based on the total weight of the aqueous black pigment-based ink.

17. The method of claim 1 , wherein the (a) one or more water-soluble salts of a multivalent metal cation comprises a cation that is magnesium (+2), calcium (+2), barium (+2), zinc (+2), or aluminum (+3).

18. The method of claim 1 , wherein the weight ratio of the (a) one or more water-soluble salts of a multivalent metal cation to the (b) one or more of a polyvinyl alcohol and

Assignees

• Eastman Kodak Co

Inventors

• Putnam David D
• Irving Mark Edward
• Bugner Douglas Eugene
• Griffin Todd Russell
• Lussier Barbara Boland
• Sowinski Allan Francis

Classifications

• C09J7/29

  Laminated material (metallised plastics C09J7/22) · CPC title

• B32B2307/73

  Hydrophobic · CPC title

• B32B2255/205

  Metallic coating · CPC title

• B32B2451/00

  Decorative or ornamental articles · CPC title

• C09J7/22

  Plastics; Metallised plastics · CPC title