Liquid silicone rubber composition

Patent metadata

Field	Value
Publication number	US-11401422-B2
Application number	US-201816629939-A
Country	US
Kind code	B2
Filing date	Jul 12, 2018
Priority date	Jul 12, 2017
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A liquid silicone rubber (LSR) composition, and articles and coatings made therewith are disclosed. Also disclosed is a process to provide for the composition, and a process to coat on textile.

First claim

The invention claimed is:

1. A liquid silicone rubber composition comprising:
(i) a liquid silicone rubber base comprising a reinforcing filler;
(ii) a hydrophobic silica aerogel in an amount of from 3 to 8 weight percent (wt %) of the composition, where the hydrophobic silica aerogel is different from the reinforcing filler of the liquid silicone rubber base (i);
(iii) an elastomeric powder in an amount of from 3 to 8 wt % of the composition; and
(iv) a volatile solvent;
wherein the weight ratio of the hydrophobic silica aerogel (ii) to the elastomeric powder (iii) is from 0.8:1 to 2:1.

2. The liquid silicone rubber composition according to claim 1 , wherein the liquid silicone rubber base (i) comprises at least one liquid alkenyl-containing polydiorganosiloxane (A), at least one organohydrogenpolysiloxane (B), at least one reinforcing filler (C), and at least one hydrosilylation catalyst (D).

3. The liquid silicone rubber composition according to claim 1 , wherein the hydrophobic silica aerogel (ii) has a surface area of from 500 to 1200 m 2 /g using the BET method.

4. The liquid silicone rubber composition according to claim 1 , wherein the hydrophobic silica aerogel (ii) has a particle size of from 5 to 1000 μm as measured by of laser light scattering.

5. The liquid silicone rubber composition according to claim 1 , wherein the elastomeric powder (iii) has a particle size of from 0.1 to 1000 μm as measured by a laser diffraction type particle size distribution analyzer.

6. The liquid silicone rubber composition according to claim 1 , wherein the weight ratio of the hydrophobic silica aerogel (ii) to the elastomeric powder (iii) is from 0.8:1 to 1.5:1.

7. The liquid silicone rubber composition according to claim 1 , wherein the volatile solvent (iv) is selected from the group consisting of silicone based volatile solvents, hydrocarbon based volatile solvents, and mixtures thereof.

8. The liquid silicone rubber composition according to claim 1 , wherein the liquid silicone rubber base (i) is a silicone textile printing ink.

9. A method for preparing the liquid silicone rubber composition according to claim 1 , the method comprising mixing ingredients (i) to (iv) at ambient temperature.

10. A method for coating a textile, the method comprising:
coating the textile with a liquid silicone rubber composition; and
curing the composition to form a coating;
wherein the liquid silicone rubber composition comprises:
(i) a liquid silicone rubber base comprising a reinforcing filler;
(ii) a hydrophobic silica aerogel in an amount of from 3 to 8 weight percent (wt %) of the composition, where the hydrophobic silica aerogel is different from the reinforcing filler of the liquid silicone rubber base (i);
(iii) an elastomeric powder in an amount of from 3 to 8 wt % of the composition; and
(iv) a volatile solvent; and
wherein the weight ratio of the hydrophobic silica aerogel (ii) to the elastomeric powder (iii) is from 0.8:1 to 2:1.

11. The method according to claim 10 , wherein the textile is selected from the group of leather or natural fibers and/or synthetic fibers.

12. The method according to claim 11 , wherein the textile comprises natural fibers selected from the group consisting of cellulosic fibers, wool, and/or silk.

13. The method according to claim 10 , wherein the composition is applied by screen printing.

14. A textile coated with the liquid silicone rubber composition in accordance with claim 1 or a cured coating thereof.

15. An article cured from the liquid silicone rubber composition in accordance with claim 1 .

16. A composite part comprising a silicone elastomer cured from the liquid curable silicone rubber composition in accordance with claim 1 on a substrate.

17. A method to impart a mattifying effect to a silicone elastomer article or composite part, wherein the silicone elastomer article or composite part is obtained from curing a liquid silicone rubber composition comprising a combination of hydrophobic silica aerogel and elastomeric powder where the ratio of hydrophobic silica aerogel to elastomeric powder is from 0.8:1 to 2:1 to 2:1.

Assignees

• Dow Silicones Corp
• Dow Global Technologies Llc

Inventors

• Phukan Humen
• Sawant Parag
• Shinde Tushar
• Nair Padmadas
• Pillay Shamit

Classifications

• D06P1/44

  using insoluble pigments or auxiliary substances, e.g. binders · CPC title

• D06P1/67383

  containing silicon · CPC title

• C08L83/04 Primary

  Polysiloxanes · CPC title

• D06N2201/06

  Animal fibres, e.g. hair, wool, silk · CPC title

• D06N2209/0846

  Matt, dull surface · CPC title