Resin composition and multilayered structure using same

Patent metadata

Field	Value
Publication number	US-11401407-B2
Application number	US-201916400467-A
Country	US
Kind code	B2
Filing date	May 1, 2019
Priority date	Nov 9, 2016
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

Provided is a resin composition comprising an ethylene-vinyl alcohol copolymer (A), a hydrate-forming metal salt (B), and a polyamide-based resin (C) that inhibits elution of a resin composition layer during hot water sterilization treatment of a multilayered structure including the resin composition layer, while suppressing odor during melt molding of the resin composition. An aromatic polyamide (C1) and an aliphatic polyamide (C2) are used for the polyamide-based resin (C) at a proportion of (C1)/(C2)=55/45-99/1.

First claim

What is claimed is:

1. A resin composition comprising an ethylene-vinyl alcohol copolymer (A), a hydrate-forming metal salt (B), and a polyamide-based resin (C), in which (A), (B), and (C) are mixed together,
wherein a weight ratio of the ethylene-vinyl alcohol copolymer (A) to the polyamide-based resin (C), (A)/(C), is from 99/1 to 70/30,
wherein the polyamide-based resin (C) includes
an aromatic polyamide-based resin (C1) whose main chain includes a structural unit containing an aromatic ring and aliphatic polyamide-based resin (C2) whose main chain includes an aliphatic hydrocarbon containing 5 or more carbon atoms,
wherein a weight ratio of the aromatic polyamide-based resin (C1) to the aliphatic polyamide-based resin (C2), (C1)/(C2), is from 55/45 to 99/1, and
wherein the aromatic-polyamide-based resin (C1) is a copolymer of meta-xylylenediamine and adipic acid, and the aliphatic polyamide-based resin (C2) is nylon 6.

2. The resin composition according to claim 1 , wherein a content of the structural unit having an aromatic ring in the aromatic-polyamide resin (C1) is from 30 to 60 mol %.

3. The resin composition according to claim 1 , wherein the hydrate-forming metal salt (B) satisfies at least one of water absorption properties (I), (II), or (III):
water absorption property (I): a ratio (X 5 /Y) is 0.2 or more wherein Y is an amount of water of crystallization in hydrated hydrate-forming metal salt (B) in a state of maximum hydration, and X 5 is an amount of water absorption when the hydrate-forming metal salt (B) is placed for 5 days under the condition of 40° C. and 90% relative humidity;
water absorption property (II): an amount (Z) of water absorbed per 100 g of the hydrate-forming metal salt (B) while the hydrate-forming metal salt (B) is placed for 24 hours under the condition of 40° C. and 90% relative humidity, is 10 g or more;
water absorption property (III): a local maximum point exists in an amount of water absorption when the hydrate-forming metal salt (B) is placed under the condition of 40° C. and 90% relative humidity.

4. The resin composition according to claim 3 , wherein the hydrate-forming metal salt (B) satisfies the water absorption properties (I), (II), and (III).

5. The resin composition according to claim 2 , wherein the hydrate-forming metal salt (B) satisfies the water absorption properties (I), (II), and (III):
water absorption property (I): a ratio (X 5 /Y) is 0.2 or more wherein Y is an amount of water of crystallization in hydrated hydrate-forming metal salt (B) in a state of maximum hydration, and X 5 is an amount of water absorption when the hydrate-forming metal salt (B) is placed for 5 days under the condition of 40° C. and 90% relative humidity;
water absorption property (II): an amount (Z) of water absorbed per 100 g of the hydrate-forming metal salt (B) while the hydrate-forming metal salt (B) is placed for 24 hours under the condition of 40° C. and 90% relative humidity, is 10 g or more;
water absorption property (III): a local maximum point exists in an amount of water absorption when the hydrate-forming metal salt (B) is placed under the condition of 40° C. and 90% relative humidity.

6. The resin composition according to claim 1 , further comprising a dispersant (D).

7. A multilayered structure comprising at least one layer comprising the resin composition according to claim 1 .

8. A method for suppressing an occurrence of offensive odor of a multilayered structure on exposure to heating, the method comprising:
providing a multilayered structure containing a gas barrier layer made of a resin composition comprising an ethylene-vinyl alcohol copolymer (A), a hydrate-forming metal salt (B), and a polyamide-based resin (C), mixed together, wherein a content ratio of the ethylene-vinyl alcohol copolymer (A) to the polyamide-based resin (C), (A)/(C), is from 99/1 to 70/30,
wherein the polyamide-based resin (C) employs a combination of an aromatic polyamide-based resin (C1) whose main chain includes a structural unit containing an aromatic ring, and an aliphatic polyamide-based resin (C2) whose main chain includes an aliphatic hydrocarbon containing 5 or more carbon atoms, and
wherein a weight ratio of the aromatic polyamide-based resin (C1) to the aliphatic polyamide-based resin (C2), (C1)/(C2), is from 55/45 to 99/1
wherein the aromatic-polyamide-based resin (C1) is a copolymer of meta-xylylenediamine and adipic acid, and
wherein the aliphatic polyamide-based resin (C2) is nylon 6; and
heating the multilayered structure.

Assignees

• Mitsubishi Chem Corp

Inventors

• HASHIMOTO Honoka
• Nakanishi Shinji
• Furukawa Kazuya

Classifications

• B29B7/46

  with more than one shaft · CPC title

• B29B2009/163

  Coating, i.e. applying a layer of liquid or solid material on the granule · CPC title

• B32B2439/60

  Bottles · CPC title

• C08L2205/02

  containing two or more polymers of the same C08L -group · CPC title

• B32B27/304

  comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF · CPC title