Transparent fluoropolymer films

Patent metadata

Field	Value
Publication number	US-11401389-B2
Application number	US-201916407800-A
Country	US
Kind code	B2
Filing date	May 9, 2019
Priority date	May 24, 2018
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

In a first aspect, a transparent fluoropolymer film includes, a vinyl fluoride polymer, 2 to 8 wt % of an acrylate polymer, and 0.1 to 4 wt % of a triazine UV absorber. After heating at 100° C. for 96 hours, the transparent fluoropolymer film has a 340 nm absorbance of at least 1.5. In a second aspect, a transparent multilayer film includes a polymeric substrate film and a fluoropolymer film. The fluoropolymer film includes a vinyl fluoride polymer, 2 to 8 wt % of an acrylate polymer and 0.1 to 4 wt % of a triazine UV absorber. After heating at 100° C. for 96 hours, the transparent fluoropolymer film has a 340 nm absorbance of at least 1.5.

First claim

What is claimed is:

1. A transparent fluoropolymer film comprising:
a vinyl fluoride polymer;
2 to 8 wt % of an acrylate polymer; and
0.1 to 4 wt % of a triazine UV absorber, wherein after heating at 100° C. for 96 hours, the transparent fluoropolymer film has a 340 nm absorbance of at least 1.5.

2. The transparent fluoropolymer film of claim 1 , further comprising a hindered amine light stabilizer.

3. The transparent fluoropolymer film of claim 2 , wherein the hindered amine light stabilizer comprises bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate, bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, poly(4-hydroxy-2,2,6,6-tetramethyl-1-piperidine ethanol-alt-1,4-butanedioic acid), or a mixture thereof.

4. The transparent fluoropolymer film of claim 1 , wherein the triazine UV absorber comprises 2-hydroxyphenyl-s-triazine.

5. The transparent fluoropolymer film of claim 1 , wherein after soaking in methyl ethyl ketone solvent for 29 hours at room temperature, the transparent fluoropolymer film has a haze of less than 50%.

6. The transparent fluoropolymer film of claim 1 , wherein after soaking in methyl ethyl ketone solvent for 29 hours at room temperature, the transparent fluoropolymer film has a transmission of at least 80%.

7. The transparent fluoropolymer film of claim 1 , wherein the acrylate polymer comprises a methacrylate polymer.

8. The transparent fluoropolymer film of claim 7 , wherein the methacrylate polymer comprises polymethyl methacrylate.

9. The transparent fluoropolymer film of claim 1 , wherein the acrylate polymer is a copolymer comprising a methacrylate monomer and one or more comonomers.

10. The transparent fluoropolymer film of claim 9 , wherein the one or more comonomers comprise an ethyl acrylate, a butyl acrylate, a 2-ethylhexyl acrylate, an acrylic acid, a methacrylic acid or a mixture thereof.

11. The transparent fluoropolymer film of claim 1 , wherein a ratio of acrylate polymer to triazine UV absorber is in a range of from about 2.5:1 to about 8:1.

12. The transparent fluoropolymer film of claim 11 , wherein the ratio of acrylate polymer to triazine UV absorber is about 4:1.

13. The transparent fluoropolymer film of claim 2 , wherein a ratio of UV absorber to hindered amine light stabilizer is in a range of from about 1:1 to about 3:1.

14. The transparent fluoropolymer film of claim 13 , wherein the ratio of UV absorber to hindered amine light stabilizer is in a range of from about 1.5:1 to about 2:1.

15. The transparent fluoropolymer film of claim 1 , wherein the fluoropolymer film has a thickness of from about 10 to about 200 μm.

16. The transparent fluoropolymer film of claim 15 , wherein the fluoropolymer film has a thickness of from about 20 to about 75 μm.

17. A transparent multilayer film comprising a polymeric substrate film and a fluoropolymer film, wherein the fluoropolymer film comprises:
a vinyl fluoride polymer;
2 to 8 wt % of an acrylate polymer; and
0.1 to 4 wt % of a triazine UV absorber, wherein after heating at 100° C. for 96 hours, the transparent fluoropolymer film has a 340 nm absorbance of at least 1.5.

18. The transparent multilayer film of claim 17 , further comprising an adhesive layer.

19. A photovoltaic module comprising a frontsheet, a solar cell layer and a backsheet, wherein the frontsheet, the backsheet, or both the frontsheet and the backsheet comprise the transparent multilayer film of claim 17 .

20. An article comprising a substrate and a transparent fluoropolymer film, wherein the substrate comprises a material selected from the group consisting of plastics, metals and woods, and the transparent fluoropolymer film comprises:
a vinyl fluoride polymer;
2 to 8 wt % of an acrylate polymer; and
0.1 to 4 wt % of a triazine UV absorber, wherein after heating at 100° C. for 96 hours, the transparent fluoropolymer film has a 340 nm absorbance of at least 1.5.

21. The article of claim 20 , wherein plastics comprise a polymeric substrate and a graphic image.

Assignees

• Du Pont

Inventors

• Demko Michael T

Classifications

• H10F19/804

  Materials of encapsulations · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• B32B27/08

  of synthetic resin · CPC title

• C09D127/14

  Homopolymers or copolymers of vinyl fluoride · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title