Method for producing a stream of propylene and associated facility

Patent metadata

Field	Value
Publication number	US-11401221-B2
Application number	US-201917057660-A
Country	US
Kind code	B2
Filing date	May 23, 2019
Priority date	May 23, 2018
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A method for producing a stream of propylene and associated facility are described. The method includes: an introduction of a feed cut rich in C4 and/or C5 hydrocarbons, and at least one cut rich in ethylene into a metathesis reactor; an introduction of a metathesis product in a deethylenizer; a production of an overhead stream rich in ethylene and a feed stream; an introduction of the feed stream into a depropylenizer and recovery of a bottom stream containing C4+ hydrocarbons; a recovery, from an overhead stream of the depropylenizer, of the propylene stream; a lateral withdrawal of a recycle stream and return of the recycle stream to the metathesis reactor; a lateral draw-off, in the depropylenizer, of a purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene.

First claim

The invention claimed is:

1. A method for producing a stream of propylene, comprising:
introducing a feed cut rich in C4 and/or C5 hydrocarbons, and at least one cut rich in ethylene into a metathesis reactor;
recovering a metathesis product at an outlet of the metathesis reactor;
introducing the metathesis product into a deethylenizer;
producing, an overhead stream rich in ethylene at a head of the deethylenizer and producing a feed stream at a bottom of the deethylenizer;
introducing the feed stream in a depropylenizer and recovering a bottom stream containing C4+ hydrocarbons from a bottom of the depropylenizer;
recovering a propylene stream from an overhead stream of the depropylenizer;
withdrawing a recycle stream rich in C4 and/or C5 hydrocarbons laterally in the depropylenizer;
returning the recycle stream to the metathesis reactor;
drawing-off a purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene, laterally in the depropylenizer,
wherein the withdrawing the recycle stream is carried out at a level N4 of the depropylenizer, the drawing-off of the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene being carried out at a level N2 of the depropylenizer, the level N4 being located below the level N2.

2. The method according to claim 1 , comprising recycling the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene to a steam cracking furnace.

3. The method according to claim 1 , comprising at least partially condensing the overhead stream from the depropylenizer to form a liquid fraction, separating the liquid fraction in a reflux introduced at a level N1 of the depropylenizer and in the propylene stream, the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene being drawn off from the depropylenizer laterally at a level N2 located below the level Ni.

4. The method according to claim 1 , wherein the withdrawing of the recycle stream is carried out in gas phase.

5. The method according to claim 1 , wherein the drawing-off of the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene is carried out in gas phase.

6. The method according to claim 1 , comprising:
cooling and/or condensing the recycle stream to form a cooled and/or condensed recycle stream,
introducing the cooled and/or condensed recycle stream into the feed cut.

7. The method according to claim 1 , comprising forming the feed cut from a C4 steam cracking cut, and/or a C4 refinery cut.

8. A propylene production installation, comprising:
a metathesis reactor configured to be supplied with at least one feed cut rich in C4 and/or C5 hydrocarbons, and by at least one cut rich in ethylene, the metathesis reactor being configured to produce a metathesis product;
a deethylenizer, fed with the metathesis product from the metathesis reactor, the deethylenizer having a deethylenizer top and a deethylenizer bottom, the deethylenizer being configured to produce an overhead stream rich in ethylene at the deethylenizer top, and to produce a feed stream at the deethylenizer bottom;
a depropylenizer having a depropylenizer top and a depropylenizer bottom, the depropylenizer being configured to receive the feed stream and to produce a bottom stream containing C4+ hydrocarbons at the depropylenizer bottom and to produce an overhead stream rich in propylene at the depropylenizer top;
a collector configured to collect a propylene stream from the overhead stream of the depropylenizer;
a lateral withdrawer configured to withdraw a recycle stream rich in C4 and/or C5 hydrocarbons in the depropylenizer and a recycler configured to return the recycle stream to the metathesis reactor;
a lateral off-drawer configured to draw off a purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene in the depropylenizer,
wherein the depropylenizer has a level N4 at which the recycle stream is withdrawn, and a level N2 at which the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene is withdrawn, the level N4 being located below the level N2.

9. The installation according to claim 8 , comprising a steam cracking furnace, the recycler being configured to return the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene to the steam cracking furnace.

10. The installation according to claim 8 , comprising a condenser configured to at least partially condense the overhead stream from the depropylenizer to form a liquid fraction, and a separator configured to fractionate the liquid fraction into a reflux introduced at a level N1 of the depropylenizer and into the propylene stream, the lateral off-drawer being disposed laterally at a level N2 located below the level Ni.

11. The installation according to claim 8 , wherein the lateral withdrawer is configured to withdraw the recycle stream rich in C4 hydrocarbons in gas phase.

12. The installation according to claim 8 , wherein the lateral off-drawer is configured to draw off the purge rich in C4 paraffinic hydrocarbons and/or rich in isobutene in gas phase.

13. The installation according to claim 8 , comprising:
a cooler and/or condenser configured to cool and/or condense the recycle stream to form a cooled and/or condensed recycle stream,
an introducer configured to introduce the cooled and/or condensed recycle stream in the feed cut.

14. The installation according to claim 8 , wherein the depropylenizer comprises an internal partition wall defining a first region located on one side of the partition wall facing a feed inlet of the feed stream and an second opposite region located on the other side of the partition wall from the feed inlet of the feed stream, the lateral off-drawer opening into the second region.

15. The installation according to claim 8 , wherein the depropylenizer comprises two fractionation columns in series.

16. The method according to claim 7 , comprising obtaining the C4 steam cracking cut, and/or the C4 refinery cut by catalytic cracking.

17. A method for producing a stream of propylene, comprising:
introducing a feed cut rich in C4 and/or C5 hydrocarbons, and at least one cut rich in ethylene into a metathesis reactor;
recovering a metathesis product at an outlet of the metathesis reactor;
introducing the metathesis product into a deethylenizer;
producing an overhead stream rich in ethylene at a head of the deethylenizer and producing a feed stream at a bottom of the deethylenizer;
introducing the feed stream in a depropylenizer and recovering a bottom stream containing C4+ hydrocarbons from a bottom of the depropylenizer;
recovering a propylene stream from an overhead stream of the depropylenizer;
withdrawing a recycle stream rich in C4 and/or C5 hydrocarbons laterally in the depropylenizer;
returning the recycle stream to the metathesis reactor;

the lateral withdrawing of the recycling stream being carried out in gas phase.

18. A method for producing a stream of propylene, comprising:
introducing a feed cut rich in C4 and/or C5 hydrocarbons, and at least one cut rich in ethylene into a metathesis reactor;
recovering a metathesis product at an outlet of the metathesis reactor;
introducing the metathesis product into a deethylenizer;
producing, an overhead stream rich in ethylene at a head of the deethylenizer and producing a feed stream at a bottom of the deethylenizer;
introducing the feed stream in a depropylenizer and recovering a bottom stream containing C4+ hydrocarbons from a bottom of the depropylenizer;
recovering a propylene stream from an overhead stream of the depropylenizer;
withdrawing a recycle strea

Assignees

• Technip France

Inventors

• Reich Véronique
• Destour Bruno

Classifications

• C07C4/04

  Thermal processes {(C07C4/025 takes precedence)} · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title

• B01J19/245

  placed in series · CPC title

• C07C7/005

  Processes comprising at least two steps in series · CPC title

• B01J2219/0004

  Processes in series · CPC title