Fluidized-bed reactor having multiple recycle gas inlet nozzles

Patent metadata

Field	Value
Publication number	US-11400428-B2
Application number	US-201816613626-A
Country	US
Kind code	B2
Filing date	May 15, 2018
Priority date	May 17, 2017
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

Fluidized-bed reactor for the gas-phase polymerization of olefins including a gas distribution grid installed in a lower part of the fluidized-bed reactor and a gas recycle line, which is equipped with a compressor and a heat exchanger and which is connected at the upper end with the top of the fluidized-bed reactor, wherein the gas recycle line splits at the lower end in at least two horizontal branches which are connected tangentially with the fluidized-bed reactor below the gas distribution grid and a process for preparing an olefin polymer carried out in the fluidized-bed reactor.

First claim

What is claimed is:

1. A process for preparing an olefin polymer comprising the step of:
homopolymerizing an olefin or copolymerizing an olefin and one or more other olefins at temperatures of from 20 to 200° C. and pressures of from 0.5 to 10 MPa in the presence of a polymerization catalyst, wherein the polymerization is carried out in a fluidized-bed reactor
wherein the fluidized-bed reactor comprises a gas distribution grid installed in a lower part of the fluidized-bed reactor and
a gas recycle line, which is equipped with a compressor and a heat exchanger and which is connected at the upper end with the top of the fluidized-bed reactor, wherein the gas recycle line splits at the lower end in at least two horizontal branches which are connected tangentially with the fluidized-bed reactor below the gas distribution grid, and
wherein the volume of the fluidized-bed reactor below the gas distribution grid is divided by a non-pressure-resistant divider plate in an upper part and a lower part.

2. The process of claim 1 , wherein the fluidized-bed reactor comprises a polymer discharge pipe, which contains a bed of polyolefin particles which moves from top to bottom of the discharge pipe, and wherein a fluid is introduced into the discharge pipe in an amount that an upward stream of the fluid is induced in the bed of polyolefin particles above the fluid introduction point.

3. The process of claim 1 , wherein the gas recycle line splits in two branches which are attached to the fluidized-bed reactor on opposite sides.

4. The process of claim 1 , wherein the gas distribution grid has the form of an inverted cone.

5. The process of claim 4 , wherein the cone angle is from 100° to 160°.

6. The process of claim 1 , wherein the gas distribution grid comprises a plurality of trays being attached to each other to form slots in the overlapping area of adjacent trays and being successively overlapped, thereby forming annular modules of trays.

7. The process of claim 1 , wherein the gas distribution grid comprises slots through which recycled gas enters the fluidized-bed reactor and the slots are formed such that the flow of gas after having passed the slots is parallel to the plane of the gas distribution grid and tangential with respect to a horizontal cross-section of the fluidized-bed reactor.

8. The process of claim 1 , wherein the fluidized-bed reactor further comprises a polymer discharge pipe, which is integrated with the upper opening into the gas distribution grid.

9. The process of claim 8 , wherein the upper opening of the polymer discharge pipe is arranged in the center of the gas distribution grid.

10. The process of claim 8 , wherein the polymer discharge pipe is part of a polymer circulation loop which is connected at the upper end with the upper region of the fluidized-bed reactor.

11. The process of claim 1 , wherein the divider plate is horizontal.

12. The process of claim 1 , wherein the equalization between the pressure in the volume above the divider plate and the pressure in the volume below the divider plate occurs by a pressure equilibration line which connects the volume below the divider plate and the gas recycle line.

13. The process of claim 1 , wherein the fluidized-bed reactor is part of a reactor cascade.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Azzarello Emanuele
• Mei Gabriele
• Mei Giulia
• Penzo Giuseppe
• Pesare Rosario

Classifications

• B01J8/44 Primary

  Fluidisation grids · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J8/1827 Primary

  the fluidising gas being a reactant · CPC title

• B01J2208/00761

  Discharging · CPC title

• B01J2208/00938

  Flow distribution elements · CPC title