Method and facility for purifying a feed gas stream comprising at least 90% CO2

Patent metadata

Field	Value
Publication number	US-11400413-B2
Application number	US-201816637978-A
Country	US
Kind code	B2
Filing date	Jul 13, 2018
Priority date	Aug 10, 2017
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A process for purifying a feed gas stream containing at least 90% of CO2, at least 20% RH and at least one impurity chosen from chlorinated, sulfur-bearing, nitrated or fluorinated compounds is provided. The process includes a) subjecting the feed gas stream to catalytic oxidation producing a stream containing at least one of HCl, NOx, SOx or hydrofluoric acid; b) maintaining the temperature of the gas stream above the highest value between the dew points of water and the acid(s) contained in the gas; c) removing at least a part of the acid impurities by bringing the gas stream into contact with a corrosion-resistant heat exchanger to condense the acid compounds while regulating the temperature of the gas stream exiting below the dew point of water; and d) separating the acid condensates with a corrosion-resistant separator in such a way as to produce a CO2-enriched gas stream.

First claim

The invention claimed is:

1. A process for purifying a feed gas stream comprising at least 90% of CO 2 on a dry basis, at least 20% relative humidity and at least one impurity chosen from chlorinated, sulfur-bearing, nitrated or fluorinated compounds, comprising the following successive steps:
a) subjecting the feed gas stream to catalytic oxidation in such a way as to produce a gas stream comprising at least one acid impurity chosen from HCl, NOx, SOx or hydrofluoric acid;
b) maintaining the temperature of the gas stream from step a) above the highest value between the dew point of water and the dew point of the acid(s) contained in the gas downstream of the catalytic process;
c) removing at least a part of the acid impurities by bringing the gas stream from step b) into contact with at least one corrosion-resistant heat exchanger in such a way as to condense the acid compounds while regulating the temperature of the gas stream exiting below the dew point of water; and
d) separating the acid condensates from the gas stream from step c) by means of a corrosion-resistant separator in such a way as to produce a CO 2 -enriched gas stream.

2. The process as claimed in claim 1 , further comprising, after step d), the following successive steps:
e) liquefying the CO 2 -enriched gas stream,
f) drying the liquefied stream, and
g) sending the dried stream to a cryogenic unit.

3. The process as claimed in claim 1 , wherein the heat exchanger and the separator comprise materials chosen from austenitic steel, glass or a composite resistant to nitric, sulfuric or hydrochloric acid.

4. The process as claimed in claim 1 , wherein the catalytic oxidation is carried out by means of a catalytic oxidation unit resistant to sulfur and to chlorine.

5. The process as claimed in claim 1 , wherein the feed gas stream subjected to the catalytic oxidation is at a temperature of at least 300° C.

6. The process as claimed in claim 1 , wherein the feed gas stream subjected to the catalytic oxidation is at a pressure of at least 1 bar absolute.

7. The process as claimed in claim 1 , wherein the feed gas stream comes from a monoethylene glycol unit, from washing of CO 2 by absorption, from a monoethylene glycol synthesis unit, from a biofermentation or any other process generating a CO 2 -rich stream.

8. The process as claimed in claim 1 , wherein, in step c), water is used as refrigerant within the heat exchanger.

9. A facility for the purification of a feed gas stream comprising at least 95% of CO 2 , at least 20% relative humidity and at least one impurity chosen from chlorinated, sulfur-bearing, nitrated or fluorinated compounds, comprising, in the direction of circulation of the gas stream:
a) a catalytic oxidation unit configured to subject the gas stream to catalytic oxidation in such a way as to produce a gas stream comprising at least one acid impurity chosen from HCl, NOx and SOx;
b) a means for maintaining the temperature of the gas stream exiting the catalytic oxidation unit above the acid dew point;
c) a corrosion-resistant heat exchanger making it possible to condense the acid compounds of the gas stream; and
d) a corrosion-resistant separator making it possible to separate the acid compounds from the gas stream in such a way as to produce a CO 2 -enriched gas stream.

10. The facility as claimed in claim 9 , wherein said facility comprises, downstream of the separator and in the direction of circulation of the CO 2 -enriched gas stream:
e) a liquefier making it possible to liquefy the CO 2 -enriched gas stream;
f) a dryer making it possible to dry the liquefied gas; and
g) a cryogenic unit.

11. The facility as claimed in claim 9 , wherein the heat exchanger and the separator comprise materials chosen from austenitic steel, glass or a composite resistant to nitric, sulfuric or hydrochloric acid.

12. The facility as claimed in claim 9 , wherein the catalytic oxidation is carried out by means of a catalytic oxidation unit resistant to sulfur and to chlorine.

Assignees

• Air Liquide

Inventors

• Rodrigues Guillaume
• Arpentinier Philippe
• Franco Aurélien
• Jabes Rémi
• Lagoutte François
• Perru Laurent
• Werlen Etienne

Classifications

• B01D2255/1021

  Platinum · CPC title

• B01D53/8687 Primary

  Organic components · CPC title

• B01D2255/1023

  Palladium · CPC title

• B01D2257/2045

  Hydrochloric acid · CPC title

• Y02C20/30

  of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6] · CPC title