Heterocyclic compound and harmful arthropod controlling agent containing same

Patent metadata

Field	Value
Publication number	US-11399539-B2
Application number	US-201716314776-A
Country	US
Kind code	B2
Filing date	Jul 6, 2017
Priority date	Jul 7, 2016
Publication date	Aug 2, 2022
Grant date	Aug 2, 2022

Abstract

A heterocyclic compound that exhibits superior control effects against harmful arthropods is provided. In particular, a heterocyclic compound of formula (I) is provided, wherein the variable groups are as defined in the specification. Also provided is a composition containing the heterocyclic compound of formula (I) and one or more types of components selected from the components described in the specification.

First claim

The invention claimed is:

1. A compound represented by formula (I):

wherein
Q 1 represents an oxygen atom or a sulfur atom;
n is 1 or 2;
Q 2 represents an oxygen atom, a N—CN, a N—NO 2 , a NR 5 , a N—C(O)R 5 or a N—C(O)OR 15 , and when n is 2, said two Q 2 may be independently identical to or different from each other;
R 5 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom;
A 1 represents a nitrogen atom or a CR 6 ;
A 2 represents a nitrogen atom or a CR 4a ;
A 3 represents a nitrogen atom or a CR 4b ;
A 4 represents a nitrogen atom or a CR 4c ;
R 4a , R 4b and R 4c represent independently of each other a hydrogen atom, a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a nitro group, a OR 18 , a NR 18 R 19 , a cyano group, or a halogen atom;
R 6 represents a hydrogen atom or a halogen atom;
T represents a C1-C10 chain hydrocarbon group substituted with one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from Group G, a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G, a OR 1 , a S(O) v R 1 , a OS(O) 2 R 1 , a CH 2 OR 1 , a NR 1 R 29 , a C(O)R 1 , a C(O)NR 1 R 29 , a NR 29 C(O)R 1 , a N═CR 1 R 30 , a group represented by the following formula T-1, a group represented by the following formula T-2, a group represented by the following formula T-3, a group represented by the following formula T-4, a group represented by the following formula T-5, a group represented by the following formula T-6, a group represented by the following formula T-7, a group represented by the following formula T-8, a group represented by the following formula T-9, a group represented by the following formula T-10, a group represented by the following formula T-11, or a group represented by the following formula T-12,

X 1 represents a nitrogen atom or a CR 1a ;
X 2 represents a nitrogen atom or a CR 1b ;
X 3 represents a nitrogen atom or a CR 1c ;
X 4 represents a nitrogen atom or a CR 1d ;
X 5 represents a nitrogen atom or a CR 1e ;
R 1x represents a OR 7 , a OS(O) 2 R 7 , a S(O) m R 7 , a NR 8 S(O) 2 R 7 , a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, or a halogen atom;
q is 0, 1, 2, or 3;
R 1a , R 1b , R 1c , R 1d , and R 1e represent independently of each other a hydrogen atom, a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a halogen atom;
Y 1 represents a NR 25 , an oxygen atom or a sulfur atom;
Y 2 represents a nitrogen atom or a CR 26 ;
Y 3 represents a nitrogen atom or a CR 27 ;
Y 4 represents a nitrogen atom or a CR 28 ;
R 25 , R 26 , R 27 , and R 28 represent independently of each other a hydrogen atom, a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a halogen atom;
R 1y represents a OR 7 , a OS(O) 2 R 7 , a S(O) m R 7 , a NR 8 S(O) 2 R 7 , a cyano group, a C1-C5 chain hydrocarbon group substituted with one or more halogen atoms, or a halogen atom;
R 1ay and R 7 represent independently of each other a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms;
R 8 represents a hydrogen atom, or a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms;
m and v are independently of each other 0, 1 or 2,
R 1 represents a C1-C10 chain hydrocarbon group substituted with one or more halogen atoms, a (C1-C5 alkoxy)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfanyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfinyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C1-C5 alkylsulfonyl)C2-C5 alkyl group substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C3 alkyl group substituted with one or more substituents selected from Group G, or a C3-C7 cycloalkyl group substituted with one or more substituents selected from Group G;
R 2 represents a cyclopropyl group, a cyclopropylmethyl group, or a C1-C6 alkyl group optionally substituted with one or more halogen atoms;
R 3 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group B, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group J, a phenyl group optionally substituted with one or more substituents selected from Group H, a five or six membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, a OR 12 , a NR 11 R 12 , a NR 11a R 12a , a NR 29 NR 11 R 12 , a NR 29 OR 11 , a NR 11 C(O)R 13 , a NR 29 NR 11 C(O)R 13 , a NR 11 C(O)OR 14 , a NR 29 NR 11 C(O)OR 14 , a NR 11 C(O)NR 15x R 16x , a NR 24 NR 11 C(O)NR 15x R 16x , a N═CHNR 15x R 16x , a N═S(O)R 15 R 16 , a C(O)R 17 , a C(O)OR 17 , a C(O)NR 15x R 16x , a C(O)NR 11 S(O) 2 R 23 , a CR 24 ═NOR 17 , a NR 11 CR 24 ═NOR 7 , a cyano group, a nitro group, or a halogen atom, and when q is 2 or 3, a plurality of R 3 may represent independently identical to or different from each other;
when two R 3 are adjacent to each other, said two R 3 may combine together with a carbon atom to which they are attached to form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, a triazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, or a pyrazine ring, wherein the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the triazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the oxadiazole ring, the thiadiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, or the pyrazine ring may be optionally substituted with one or more substituents selected from Group H:
R 17 represent independently of each other a hydrogen atom, a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group F, or a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J;
R 11 , R 19 , R 24 , and R 29 represent independently of each other a hydrogen atom, or a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms;
R 30 represents a hydrogen atom, a halogen atom, a OR 35 , a NR 36 R 37 , or a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms;
R 18 and R 35 represent independently of each other a C1-C6 chain hydrocarbon group substituted with one or more halogen atoms;
R 36 and R

Assignees

• Sumitomo Chemical Co

Inventors

• Tanaka Ayaka
• Shimomura Masaru
• Nokura Yoshihiko
• Murakami Shinichiro

Classifications

• A01N43/40 Primary

  six-membered rings · CPC title

• A01N43/58

  1,2-Diazines; Hydrogenated 1,2-diazines · CPC title

• C07D213/71

  to which a second hetero atom is attached · CPC title

• C07D401/14

  containing three or more hetero rings · CPC title

• A01N43/56

  1,2-Diazoles; Hydrogenated 1,2-diazoles · CPC title