Infrared-transparent polymer optics and methods of making and using the same

Patent metadata

Field	Value
Publication number	US-11397282-B1
Application number	US-201916427290-A
Country	US
Kind code	B1
Filing date	May 30, 2019
Priority date	Jun 29, 2018
Publication date	Jul 26, 2022
Grant date	Jul 26, 2022

Abstract

Infrared-transparent and damage-resistant polymer optics with LWIR and/or MWIR transparency are provided. Some variations provide an optic containing at least 50 wt % of an infrared-transparent polymer, wherein the infrared-transparent polymer has a carbon-free polymer backbone, wherein the optic is characterized by at least 80% average transmission of radiation over a wavenumber band with cumulative wavenumber width of at least 1000 cm−1 contained within wavelengths from 3.1 μm to 5 μm and/or from 8.1 μm to 12 μm, and wherein the average transmission is defined as the percentage ratio of radiation intensity through an optic thickness of 25 microns divided by incident radiation intensity. Many polymer compositions and pendant groups are disclosed for use in the polymer optics.

First claim

What is claimed is:

1. An optic containing at least 50 wt % of an infrared-transparent polymer, wherein said infrared-transparent polymer has a carbon-free polymer backbone, wherein said optic is characterized by at least 80% average transmission of radiation over a wavenumber band with cumulative wavenumber width of at least 1000 cm −1 contained within wavelengths from 3.1 μm to 5 μm and/or from 8.1 μm to 12 μm, and wherein said average transmission is defined as the ratio (expressed as a percentage) of radiation intensity through an optic thickness of 25 microns divided by incident radiation intensity.

2. The optic of claim 1 , wherein said optic is a single lens, a compound lens, a window, or an array of lenses.

3. The optic of claim 2 , wherein said optic is a lens or window that is flat, is curved on one axis, is biaxially curved, is curved in three dimensions, or is a combination thereof.

4. The optic of claim 1 , wherein said cumulative wavenumber width is at least 1500 cm −1 contained within wavelengths from 3.1 μm to 5 μm and/or from 8.1 μm to 12 μm.

5. The optic of claim 1 , wherein said cumulative wavenumber width is at least 2000 cm −1 contained within wavelengths from 3.1 μm to 5 μm and/or from 8.1 μm to 12 μm.

6. The optic of claim 1 , wherein said carbon-free polymer backbone contains a plurality of polymer repeat units of the form

wherein R 1 is selected from the group consisting of halogens, alkyls, hydroxyl, amino, urea, thiol, thioether, amino alkyls, carboxylates, metals, metal-containing groups, and derivatives, deuterated forms, or combinations thereof;
wherein R 2 is selected from the group consisting of halogens, alkyls, hydroxyl, amino, urea, thiol, thioether, amino alkyls, carboxylates, metals, metal-containing groups, and derivatives, deuterated forms, or combinations thereof;
wherein n is selected from 2 to about 10,000; and
wherein said carbon-free polymer backbone is linear, cyclic, branched, or a combination thereof.

7. The optic of claim 6 , wherein R 1 and R 2 are independently selected from the group consisting of Cl, CH 3 , NH 2 , NH(CH 2 ) 3 CH 3 , NH(CO)NH 2 , COOH, O(CO)OH, OTi(OH) 3 , SH, and derivatives, deuterated forms, or combinations thereof.

8. The optic of claim 1 , wherein said carbon-free polymer backbone contains at least one polymer repeat unit of the form

wherein R 1 is selected from the group consisting of halogens, alkyls, hydroxyl, amino, urea, thiol, thioether, amino alkyls, carboxylates, metals, metal-containing groups, and derivatives, deuterated forms, or combinations thereof;
wherein R 2 is selected from the group consisting of halogens, alkyls, hydroxyl, amino, urea, thiol, thioether, amino alkyls, carboxylates, metals, metal-containing groups, and derivatives, deuterated forms, or combinations thereof; and
wherein X is a crosslinking group, and optionally wherein X is R 1 or R 2 .

9. The optic of claim 1 , wherein said carbon-free polymer backbone is crosslinked with sulfur and/or with disulfide (S—S) bonds.

10. The optic of claim 1 , wherein said carbon-free polymer backbone is crosslinked with dithiols, CH 2 , NH, NH(CO)NH, COO-M 2+ -OOC, O(CO)O, or a combination thereof.

11. The optic of claim 1 , wherein said carbon-free polymer backbone is crosslinked with O—Ti(OH) 2 —O.

12. The optic of claim 1 , wherein said polymer is a thermoset polymer.

13. The optic of claim 1 , wherein said polymer is characterized by a density from about 1.2 g/cm 3 to about 1.9 g/cm 3 .

14. The optic of claim 1 , wherein said polymer is characterized by an index of refraction from about 1.3 to about 1.9.

15. The optic of claim 1 , wherein said optic includes, or is disposed in physical contact with, an anti-scratch layer, an anti-abrasion layer, an anti-reflection layer, or a combination thereof.

16. The optic of claim 15 , wherein said optic includes an anti-scratch layer that contains diamond, diamond-like carbon, sapphire, silicon, ZnS, or a combination thereof.

17. The optic of claim 15 , wherein said optic includes an anti-reflection layer in the form of a stack of films that provides anti-reflection properties.

18. The optic of claim 1 , wherein said optic includes an anti-rain erosion layer.

19. The optic of claim 18 , wherein said anti-rain erosion layer contains an elastomeric material.

20. The optic of claim 19 , wherein said elastomeric material is covalently or physically bonded to said optic.

21. The optic of claim 19 , wherein said elastomeric material has a storage modulus from about 1 MPa to about 500 MPa, and wherein said elastomeric material has a minimum elongation of 100%.

22. The optic of claim 19 , wherein said elastomeric material contains a polyphosphazene-based polymer, a polyphospazene-based copolymer, or a combination thereof.

23. The optic of claim 1 , wherein said optic contains toughening filler particles.

24. The optic of claim 23 , wherein said toughening filler particles are selected from the group consisting of Ge, CaF 2 , NaCl, KCl, KBr, diamond, Si, CsI, MgO, MgF 2 , LiF, NaF, BaF 2 , ZnS, ZnSe, PbS, Pb Se, PbF 2 , LiYF 4 , NaYF 4 , ThBrI, ThBrCl, and combinations thereof.

25. The optic of claim 23 , wherein said toughening filler particles are in the form of spheres, rods, whiskers, platelets, or a combination thereof.

26. The optic of claim 23 , wherein said toughening filler particles have an average dimension selected from about 100 nm to about 400 μm.

27. The optic of claim 23 , wherein said toughening filler particles have an average dimension that is less than one-half of thickness of said optic.

28. The optic of claim 23 , wherein said toughening filler particles have an average volumetric loading from about 1 vol % to about 65 vol % based on volume of said polymer plus volume of said toughening filler particles.

29. The optic of claim 1 , wherein said optic includes an anti-fouling layer on an exterior surface of said optic.

30. The optic of claim 29 , wherein said anti-fouling layer contains a polyphosphazene-based polymer, a polyphospazene-based copolymer, or a combination thereof.

Assignees

• Hrl Lab Llc

Inventors

• Gross Adam F
• Dustin Ashley M
• Nowak Andrew P
• Rodriguez April R
• Rajavel Rajesh D
• Hundley Jacob M

Classifications

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08K7/18

  inorganic · CPC title

• C08K7/04

  inorganic · CPC title

• C08K2201/011

  Nanostructured additives · CPC title

• G02B13/14

  for use with infrared or ultraviolet radiation ({G02B13/008, } G02B13/16 take precedence) · CPC title